Electrophoretic NMR studies of electrical transport in fluid-filled porous systems.

Abstract:

:An NMR technique is described which allows the observation of ionic charge carriers moving in the electric field within a porous system saturated with electrolyte solution. This method, which was recently developed in our laboratory, gives experimental access to the study of electric transport in disordered media on a microscopic level and offers new potential for morphology studies. We performed 1H NMR PFG self-diffusion measurements on ions combined with ionic drift velocity measurements by electrophoretic NMR (ENMR), each as a function of observation time Delta. In this way we obtained time-dependent self-diffusion coefficients D(+/-) (Delta) and time-dependent electric mobilities mu(+/-) (Delta) of polyatomic cations and anions in porous media. The porous media used were gels and glass bead packs. From the behaviour of D(+/-) (Delta) and mu(+/-) (Delta) at long observation times the tortuosities T(p) (D(+/-)) and T(p) (mu(+/-)) are derived, allowing a direct experimental check of the validity of the Einstein relation (D(+/-) is proportional to mu(+/-)) in a disordered medium. The tortuosities obtained via the diffusivity of ions are compared with those obtained via the diffusivity of water molecules. We also make a first attempt to derive the specific surface S/V(p) from the time-dependence of the ionic mobility at short observation times and discuss possible advantages of those measurements in morphology studies of porous media.

journal_name

Magn Reson Imaging

authors

Holz M,Heil SR,Schwab IA

doi

10.1016/s0730-725x(01)00267-3

subject

Has Abstract

pub_date

2001-04-01 00:00:00

pages

457-63

issue

3-4

eissn

0730-725X

issn

1873-5894

pii

S0730-725X(01)00267-3

journal_volume

19

pub_type

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