Preparation and characterisation of polylactic acid modified polyurethane microcapsules for controlled-release of chlorpyrifos.

Abstract:

:Polyurethane modified with polylactic acid microcapsules were fabricated for controlled release of chlorpyrifos (one of the high usage solid phosphorous insecticides) via interfacial polymerisation with diphenylmethane diisocyanate, polyether triol, 1,4-butanediol and polylactic acid as modifier. The structure, morphology and release properties of synthesised microcapsules were characterised by Fourier transform infra-red spectroscopy, thermogravimetric analyser, scanning electron microscope, particle size analyser and high-performance liquid chromatography. More benign solvents, namely ethyl acetate and n-butyl acetate were used as replacement for toxic solvents commonly used in the preparation of polyurethane microcapsules, namely xylene. The spherical microcapsules prepared in this study were 1-20 μm in diameter. Fourier transform infra-red spectroscopy indicated that polylactic acid had successfully participated in the interfacial polymerisation of polyurethane. Encapsulation efficiency of microcapsules can amount up to 71.0% w/w with a loading efficiency of 26.2% w/w. The microcapsules exhibited a sustained release period above 60 days. Combining polylactic acid into the soft segment of polyurethane proves to effectively accelerate the release rate.

journal_name

J Microencapsul

authors

Zheng T,Chen K,Chen W,Wu B,Sheng Y,Xiao Y

doi

10.1080/02652048.2019.1599075

subject

Has Abstract

pub_date

2019-01-01 00:00:00

pages

62-71

issue

1

eissn

0265-2048

issn

1464-5246

journal_volume

36

pub_type

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