Cellulosic paper with high antioxidative and barrier properties obtained through incorporation of tannin into kraft pulp fibers.

Abstract:

:In this work, we prepared novel cellulosic paper by incorporating tannin into the kraft pulp for potential application in active food packaging. The kraft pulp fibers were firstly periodate oxidized to obtain the dialdehyde cellulosic fibers, and then reacted with varied dosages of tannin to incorporate them into the fibers by covalent bondings between aldehyde groups on cellulose and active hydrogen on tannin. Handsheets were prepared using the tannin incorporated fibers through papermaking process and the properties were characterized. The percentage of tannin in the paper increased with the increase of the tannin dosage. FT-IR spectra confirmed the successful incorporation of tannin into the cellulosic fibers. It was found that paper after incorporation of tannin turned to be surface hydrophobic with contact angles higher than 90°, which may probably due to the covalent bonds between tannin and cellulose. The handsheets show high antioxidative and UV-shielding properties, which both increased with the increase of the tannin percentage in the paper. Water vapor transmission rate (WVTR) decreased after the incorporation of tannin, and this could facilitate its application in food packaging. The breaking length of tannin incorporated paper decreased insignificantly, less than 10% with the tannin percentage as high as 45%.

journal_name

Int J Biol Macromol

authors

Ji Y,Xu Q,Jin L,Fu Y

doi

10.1016/j.ijbiomac.2020.06.101

subject

Has Abstract

pub_date

2020-11-01 00:00:00

pages

678-684

eissn

0141-8130

issn

1879-0003

pii

S0141-8130(20)33543-1

journal_volume

162

pub_type

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