Abstract:
:The structure changes of hemoglobin (Hb) and glucose oxidase (GOx), as two typical proteins, upon interaction with MWCNTs and MWCNTs-[BMIM]BF₄(-) was studied. The ability of MWCNTs and MWCNTs-([BMIM]BF₄(-)) for the achievement of direct electrochemistry of GOx and Hb and enhancing the electron transfer rate between proteins and electrode surface was compared. Also the data obtained by various techniques including UV-vis, fluorescence and circular dichroism spectroscopy revealed that the structure of Hb or GOx conjugated with supramolecular network of the nano-composite could be preserved much better than those absorbed on MWCNTs. It seems that ionic liquid provides a favorable microenvironment to maintain the protein native structures.
journal_name
Int J Biol Macromoljournal_title
International journal of biological macromoleculesauthors
Karimi S,Ghourchian H,Banaei Adoi
10.1016/j.ijbiomac.2013.02.008subject
Has Abstractpub_date
2013-05-01 00:00:00pages
169-74eissn
0141-8130issn
1879-0003pii
S0141-8130(13)00060-3journal_volume
56pub_type
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