Abstract：
:A metal-free three component cyclization reaction with amidation is devised for direct synthesis of DFT-designed amido-phenazine derivative bearing noncovalent gluing interactions to fabricate organic nanomaterials. Composition-dependent organic nanoelectronics for nonvolatile memory devices are discovered using mixed phenazine-stearic acid (SA) nanomaterials. We discovered simultaneous two different types of nonmagnetic and non-moisture sensitive switching resistance properties of fabricated devices utilizing mixed organic nanomaterials: (a) sample-1(8:SA = 1:3) is initially off, turning on at a threshold, but it does not turn off again with the application of any voltage, and (b) sample-2 (8:SA = 3:1) is initially off, turning on at a sharp threshold and off again by reversing the polarity. No negative differential resistance is observed in either type. These samples have different device implementations: sample-1 is attractive for write-once-read-many-times memory devices, such as novel non-editable database, archival memory, electronic voting, radio frequency identification, sample-2 is useful for resistive-switching random access memory application.
journal_name
Sci Repjournal_title
Scientific reportsauthors
Maiti DK,Debnath S,Nawaz SM,Dey B,Dinda E,Roy D,Ray S,Mallik A,Hussain SAdoi
10.1038/s41598-017-13754-wsubject
Has Abstractpub_date
2017-10-17 00:00:00pages
13308issue
1issn
2045-2322pii
10.1038/s41598-017-13754-wjournal_volume
7pub_type
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