Thermoreversible (Ionic-Liquid-Based) Aqueous Biphasic Systems.

Abstract:

:The ability to induce reversible phase transitions between homogeneous solutions and biphasic liquid-liquid systems, at pre-defined and suitable operating temperatures, is of crucial relevance in the design of separation processes. Ionic-liquid-based aqueous biphasic systems (IL-based ABS) have demonstrated superior performance as alternative extraction platforms, and their thermoreversible behaviour is here disclosed by the use of protic ILs. The applicability of the temperature-induced phase switching is further demonstrated with the complete extraction of two value-added proteins, achieved in a single-step. It is shown that these temperature-induced mono(bi)phasic systems are significantly more versatile than classical liquid-liquid systems which are constrained by their critical temperatures. IL-based ABS allow to work in a wide range of temperatures and compositions which can be tailored to fit the requirements of a given separation process.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Passos H,Luís A,Coutinho JA,Freire MG

doi

10.1038/srep20276

subject

Has Abstract

pub_date

2016-02-04 00:00:00

pages

20276

issn

2045-2322

pii

srep20276

journal_volume

6

pub_type

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