Eutectic nano-droplet template injection into bulk silicon to construct porous frameworks with concomitant conformal coating as anodes for Li-ion batteries.

Abstract:

:Building porosity in monolithic materials is highly desired to design 3D electrodes, however ex-situ introduction or in-situ generation of nano-scale sacrificial template is still a great challenge. Here Al-Si eutectic droplet templates are uniformly injected into bulk Si through Al-induced solid-solid convection to construct a highly porous Si framework. This process is concomitant with process-inherent conformal coating of ion-conductive oxide. Such an all-in-one method has generated a (continuously processed) high-capacity Si anode integrating longevity and stable electrolyte-anode diaphragm for Li-ion batteries (e.g. a reversible capacity as large as ~1800 mAh/g or ~350 μAh/cm(2)-μm with a CE of ~99% at 0.1 C after long-term 400 cycles).

journal_name

Sci Rep

journal_title

Scientific reports

authors

Qu F,Li C,Wang Z,Wen Y,Richter G,Strunk HP

doi

10.1038/srep10381

subject

Has Abstract

pub_date

2015-05-19 00:00:00

pages

10381

issn

2045-2322

pii

srep10381

journal_volume

5

pub_type

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