Structure and stereochemistry of dimeric proteracacinidins possessing the rare C-4(C) --> C-5(D) interflavanyl linkage.

abstract：:In addition to Z-coniferyl and Z-sinapyl alcohols, bark extracts of Fagus grandifolia also contain significant amounts of the glucosides, Z-coniferin, Z-isoconiferin (previously called faguside) and Z-syringin. The corresponding E-isomers of these glucosides do not accumulate to a detectable level. The accumulation ...

journal_title：Phytochemistry

authors： Lewis NG,Inciong EJ,Ohashi H,Towers GH,Yamamoto E

更新日期：1988-01-01 00:00:00

abstract：:A polynucleotide (or a fragment of RNA) was purified to apparent homogeneity by HPLC from mycelium of the wild strain 74A of the mould Neurospora crassa, after growth on sucrose and in the presence of saturating amounts of inorganic phosphate (Pi) for 72 hr at 30 degrees. The M(r) was ca 20,000 as determined by HPLC a...

journal_title：Phytochemistry

authors： Carmona EC,Han SW,Palma MS,Rossi A

更新日期：1996-02-01 00:00:00

abstract：:Human kidney-type glutaminase (KGA) is an important target that is often over expressed in many cancer cells but very few effective inhibitors of this enzyme have yet reached clinical trials. Caudatan A and caudatan B, two undescribed tetracyclic flavans with an unusual ether bond between the C-4 and C-2' were isolate...

journal_title：Phytochemistry

authors： Sun Y,Feng X,Liu X,Qian C,Che X,Cao F,Jin S,Meng D

更新日期：2018-08-01 00:00:00

abstract：:Cutinized and suberized cell walls form physiological important plant-environment interfaces as they act as barriers limiting water and nutrient loss and protect from radiation and invasion by pathogens. Due to the lack of protocols for the isolation and analysis of cutin and suberin in Arabidopsis, the model plant fo...

journal_title：Phytochemistry

authors： Franke R,Briesen I,Wojciechowski T,Faust A,Yephremov A,Nawrath C,Schreiber L

更新日期：2005-11-01 00:00:00

abstract：:Strychnos nux-vomica L. (Loganiaceae) is famous for its monomeric alkaloid content, such as strychnine, a convulsant poison. The stem bark of the tree is traditionally used to treat intermittent fever in South East Asia. In various studies, it appeared that dimeric indolo-monoterpenic alkaloids possess a promising act...

journal_title：Phytochemistry

authors： Jonville MC,Dive G,Angenot L,Bero J,Tits M,Ollivier E,Frédérich M

更新日期：2013-03-01 00:00:00

abstract：:Nine cycloartane triterpenoids, including two new derivatives 22,25-dihydroxy-cycloart-23E-en-3-one and 24-methylenecycloartane-3 beta,22-diol have been isolated from leaves of Guarea macrophylla. The structures were elucidated by interpretation of spectral data, mainly 1H and 13C NMR, including bidimensional analysis...

journal_title：Phytochemistry

authors： Lago JH,Roque NF

更新日期：2002-06-01 00:00:00

abstract：:Two new triterpenoid glycosides, quinovic acid-3 beta-O-beta-D- glucopyranosyl-(1-->4)-alpha-L-rhamnopyranoside and quinovic acid-3 beta-O-beta-D-glucopyranosyl-(1-->3)-beta-D-fucopyranoside (named rubelloside A and B, respectively), were isolated from roots of Adina rubella. Their structures were elucidated by spectr...

journal_title：Phytochemistry

authors： Fang SY,He ZS,Gao JH,Wang P

更新日期：1995-07-01 00:00:00

abstract：:The paper describes the amino acid sequence of a 26 kDa basic subunit of 13S globulin of common buckwheat (Fagopyrum esculentum Moench). The protein has 93 and 75% sequence homology with 11S globulin of Coffea arabica and beta subunit of 11S globulin of Cucurbita pepo respectively. The subunit has the "globally conser...

journal_title：Phytochemistry

authors： Bharali S,Chrungoo NK

更新日期：2003-05-01 00:00:00

abstract：:Five new compounds (three esters and two glycosides) and seven previously reported compounds were isolated as biotransformation products of digitoxigenin by ginseng hairy root cultures. The new esters and glycosides were elucidated as digitoxigenin stearate, digitoxigenin palmitate, digitoxigenin myristate, 3-epidigit...

journal_title：Phytochemistry

authors： Kawaguchi K,Hirotani M,Yoshikawa T,Furuya T

更新日期：1990-01-01 00:00:00

abstract：:The bark of Garcinia merguensis yielded 10 xanthones, merguenone, 1,5-dihydroxy-6'-methyl-6'-(4-methyl-3-pentenyl)-pyrano(2',3':3,2)-xanthone, subelliptenone H, 8-deoxygartanin, rheediaxanthone A, morusignin G, 6-deoxyjacareubin, 1,3,5-trihydroxy-4,8-di(3-methylbut-2-enyl)-xanthone, rheediachromenoxanthone and 6-deoxy...

journal_title：Phytochemistry

authors： Nguyen LH,Vo HT,Pham HD,Connolly JD,Harrison LJ

更新日期：2003-06-01 00:00:00

abstract：:An approach, using well characterized procedures, is presented that should be of general applicability for the structural elucidation of complex sugar moieties of natural products. The methods used are exemplified by the structure elucidation of a new gitogenin-based steroidal saponin that has a strong leishmanicidal ...

journal_title：Phytochemistry

authors： Plock A,Beyer G,Hiller K,Gründemann E,Krause E,Nimtz M,Wray V

更新日期：2001-06-01 00:00:00

abstract：:Five tirucallane-type triterpenes were isolated along with nine known triterpenes from the bark of Juliania adstringens. The structures of the five triterpenes were determined by analysis of their 1H and 13C NMR and mass spectral data, and each compound exhibited growth inhibitory activity against leukemia cells (L-12...

journal_title：Phytochemistry

authors： Makino M,Motegi T,Fujimoto Y

更新日期：2004-04-01 00:00:00

abstract：:Santolina insularis (Genn ex Fiori) Arrig. is a medicinal plant whose essential oil shows antiviral and antibacterial activities and potent and selective cytotoxic activity against the human colon carcinoma cell line. The occurrence of several chemotypes makes the taxonomic identification of S. insularis hard to achie...

journal_title：Phytochemistry

authors： Gnavi G,Bertea CM,Usai M,Maffei ME

更新日期：2010-06-01 00:00:00

abstract：:The leaves of Cyclocarya paliurus with sweet taste are often used as herbal tea in People's Republic of China. In this study eight previously undescribed seco-dammarane type triterpenoids, cyclocariols A-H along with seven known compounds were isolated and characterized from its leaves. A possible biogenetic pathway f...

journal_title：Phytochemistry

authors： Chen YJ,Na L,Fan J,Zhao J,Hussain N,Jian YQ,Yuan H,Li B,Liu B,Choudhary MI,Khan I,Wang W

更新日期：2018-01-01 00:00:00

abstract：:Acylamidohydrolases from higher plants have not been characterized or cloned so far. AtAMI1 is the first member of this enzyme family from a higher plant and was identified in the genome of Arabidopsis thaliana based on sequence homology with the catalytic-domain sequence of bacterial acylamidohydrolases, particularly...

journal_title：Phytochemistry

authors： Pollmann S,Neu D,Weiler EW

更新日期：2003-02-01 00:00:00

abstract：:A pyrroloisoquinoline alkaloid, 2,3-dimethoxy-6-(3-oxo-butyl)-7,9,10,11,11a,12-hexahydrobenzo[f]pyrrolo[1,2-b]isoquinoline (1), whose structure was determined by spectroscopic methods, was isolated from the aerial parts of Cynanchum komarovii, together with two known alkaloids, 7-demethoxytylophorine (2) and 7-demetho...

journal_title：Phytochemistry

authors： An T,Huang RQ,Yang Z,Zhang DK,Li GR,Yao YC,Gao J

更新日期：2001-12-01 00:00:00

abstract：:Reinvestigation of the fermentation broth and mycelium of the coprophilous fungus Guanomyces polythrix, grown in static conditions, led to the isolation of several phytotoxic compounds, including two new naphthopyranone derivatives, namely (2S, 3R)-5-hydroxy-6,8-dimethoxy-2,3-dimethyl-2,3-dihydro-4H-naphtho[2,3-b]-pyr...

journal_title：Phytochemistry

authors： Macías M,Gamboa A,Ulloa M,Toscano RA,Mata R

更新日期：2001-11-01 00:00:00

abstract：:The accumulation of apocarotenoids in arbuscular mycorrhizal (AM) roots suggests a dramatic reorganization of the plastids responsible for the biosynthesis of these compounds. This review describes the cytological and biochemical characterization of this phenomenon. The results presented suggest that plastids are key ...

journal_title：Phytochemistry

authors： Fester T,Lohse S,Halfmann K

更新日期：2007-01-01 00:00:00

abstract：:The enzymatic glucose cleavage of palicoside revealed the biosynthetic pathway to akagerine, whereas the conversion of dolichantoside led to a new quaternary heteroyohimbine alkaloid named N(b)-methyl-21-beta-hydroxy-mayumbine. The hypothetical models of reactions occurring after the conversion of both substrates are ...

journal_title：Phytochemistry

authors： Brandt V,Tits M,Penelle J,Frédérich M,Angenot L

更新日期：2001-07-01 00:00:00

abstract：:A protein phosphatase (WbPP) has been purified from the soluble fraction of the winged bean (Psophocarpus tetragonolobus) shoot extract. The preparation is essentially homogenous as shown by the constant specific activity of the enzyme across the peak fractions, eluted from the thiophosphorylated histone-Sepharose aff...

journal_title：Phytochemistry

authors： Ganguly S,Singh M

更新日期：1999-09-01 00:00:00

abstract：:The secondary metabolites in the roots, leaves and flowers of the common dandelion (Taraxacum officinale agg.) have been studied in detail. However, little is known about the specific constituents of the plant's highly specialized laticifer cells. Using a combination of liquid and gas chromatography, mass spectrometry...

journal_title：Phytochemistry

authors： Huber M,Triebwasser-Freese D,Reichelt M,Heiling S,Paetz C,Chandran JN,Bartram S,Schneider B,Gershenzon J,Erb M

更新日期：2015-07-01 00:00:00

abstract：:Bispecific O-methyltransferase (OMT, EC 2.1.1.68) which catalyses the meta-specific methylation of caffeic acid and 5-hydroxyferulic acid was purified to homogeneity from the developing secondary xylem of aspen (Populus tremuloides). The enzyme was purified by conventional techniques and affinity chromatography on S-a...

journal_title：Phytochemistry

authors： Bugos RC,Chiang VL,Campbell WH

更新日期：1992-05-01 00:00:00

abstract：:A new triterpenoid, 22,29xi-epoxy-30-norhopane-13beta-ol (1) was isolated together with six known compounds viz., fern-9(11)-en-6alpha-ol. fern-9(11)-ene, fern-9(11)-en-25-oic acid, fern-9(11)-en-28-ol, filicenol-B, adiantone and oxidation product of fern-9(11)-en-6alpha-ol obtained as 6-oxofern-9(11)-ene from the who...

journal_title：Phytochemistry

authors： Reddy VL,Ravikanth V,Rao TP,Diwan PV,Venkateswarlu Y

更新日期：2001-01-01 00:00:00

abstract：:Four lactone diterpenes and two related glucosides with a labdane skeleton have been isolated from the aquatic plant Potamogeton natans. The structures of three new compounds were determined as 19-acetoxy-20-oxo-8(17),13-ent-labdadien-15-->16 lactone, 8(17), 13-ent-labdadien-15-->16,19-->20 dilactone and 6'-acetyl-19-...

journal_title：Phytochemistry

authors： Cangiano T,DellaGreca M,Fiorentino A,Isidori M,Monaco P,Zarrelli A

更新日期：2001-03-01 00:00:00

abstract：:The secondary metabolite contents and genetic profiles of six Hypericum species (H. barbatum Jacq., H. hirsutum L., H. linarioides Bosse, H. maculatum Crantz, H. rumeliacum Boiss. and H. tetrapterum Fries), collected from different locations in Serbia, have been analyzed. Methanol extracts of the aerial parts of the p...

journal_title：Phytochemistry

authors： Smelcerovic A,Verma V,Spiteller M,Ahmad SM,Puri SC,Qazi GN

更新日期：2006-01-01 00:00:00

abstract：:In a screening for antimicrobial metabolites, amides of D-allo- and L-isoleucine derivatives were isolated from the culture of a marine strain of Acremonium furcatum. Structural elucidation of these compounds was performed by analysis of spectroscopic data and confirmed by synthesis. All of the compounds, natural and ...

journal_title：Phytochemistry

authors： Gallardo GL,Butler M,Gallo ML,Rodríguez MA,Eberlin MN,Cabrera GM

更新日期：2006-11-01 00:00:00

abstract：:The biosynthetic origin of 9-phenylphenalenones and the sequence according to which their oxygen functionalities are introduced were studied using nuclear magnetic resonance (NMR) spectroscopy and high-resolution electrospray ionization mass spectrometry (HRESIMS). (13)C-labelled precursors were administered to root c...

journal_title：Phytochemistry

authors： Munde T,Maddula RK,Svatos A,Schneider B

更新日期：2011-01-01 00:00:00

abstract：:From the branches of Microtropis japonica (Celastraceae), nine aliphatic glucosides, named microtropins A-I, were isolated. The 6-position of glucose was esterified with (2S,3R)-2-ethyl-2,3-dihydroxybutyric acid. Microtropins A-D contained a rare natured product nitrile functional group in their aglycones. The absolut...

journal_title：Phytochemistry

authors： Uemura Y,Sugimoto S,Matsunami K,Otsuka H,Takeda Y,Kawahata M,Yamaguchi K

更新日期：2013-03-01 00:00:00

abstract：:Five new oleanane-type saponins, polygalasaponins XLII-XLVI, along with two known saponins were isolated from the roots of Polygala glomerata Lour. The structures of polygalasaponins XLII-XLVI were elucidated as 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl- (1-->2)-{...

journal_title：Phytochemistry

authors： Zhang D,Miyase T,Kuroyanagi M,Umehara K,Noguchi H

更新日期：1998-02-01 00:00:00

abstract：:Vanadium-dependent peroxidase activity in extracts of Ascophyllum nodosum growing in the intertidal region close to Roscoff/France, and algal vanadium levels, followed approximately similar seasonal variation, as deduced from a study lasting from April 2005 to March 2006. High peroxidase (PO) activity was found in ext...

journal_title：Phytochemistry

authors： Hartung J,Brücher O,Hach D,Schulz H,Vilter H,Ruick G

更新日期：2008-11-01 00:00:00