Photochemical Immobilization of Polymers on a Surface: Controlling Film Thickness and Wettability.

Abstract:

:In this manuscript, we demonstrate the control of film thickness and surface wettability in the photochemical immobilization of poly (vinyl alcohol) (PVA) to a self-assembled monolayer (SAM) containing a phthalimide chromophore. Surface attachment is characterized by ellipsometry and contact angle measurements. The wettability of the resulting films is shown to depend on the chemical composition of the polymer. The film thickness is shown to depend on the irradiation time and molecular weight of the polymer. Using a photomask, micropatterns of polymers can be grafted to the SAM. The photopatterned surface can be "developed" by coating with a thin layer of a mixture containing poly (styrene) (PS) and triphenylsulfonium triflate.

journal_name

Photochem Photobiol

authors

Carroll GT,Turro NJ,Mammana A,Koberstein JT

doi

10.1111/php.12751

subject

Has Abstract

pub_date

2017-10-01 00:00:00

pages

1165-1169

issue

5

eissn

0031-8655

issn

1751-1097

journal_volume

93

pub_type

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