Exchange dynamics of surfactants in adsorption layers investigated by PFG NMR diffusion.

Abstract:

:Surfactant adsorption layers on polystyrene latex particles are investigated concerning their equilibrium exchange dynamics with surfactant molecules in solution. Pulsed field gradient (PFG) nuclear magnetic resonance (NMR) self-diffusion measurements of the nonionic surfactant C12(EO)5 are performed, making use of the difference of the diffusion coefficients of adsorbed and free surfactant in solution. On variation of the gradient pulse spacing the echo decay data show a transition from fast to slow exchange, giving the possibility of a quantitative evaluation. A two-site model is applied to fit the data and obtain average residence times of the surfactant in both sites. The results are consistent with diffusion-controlled adsorption of surfactant monomers and additional micellar contributions to the exchange, whereas no evidence for kinetic barriers is found for these nonionic surfactants on the relevant timescale (10 ms).

journal_name

Magn Reson Imaging

authors

Schönhoff M,Söderman O

doi

10.1016/s0730-725x(98)00023-x

subject

Has Abstract

pub_date

1998-06-01 00:00:00

pages

683-5

issue

5-6

eissn

0730-725X

issn

1873-5894

pii

S0730-725X(98)00023-X

journal_volume

16

pub_type

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