A robust zirconium amino acid metal-organic framework for proton conduction.

Abstract:

:Proton conductive materials are of significant importance and highly desired for clean energy-related applications. Discovery of practical metal-organic frameworks (MOFs) with high proton conduction remains a challenge due to the use of toxic chemicals, inconvenient ligand preparation and complication of production at scale for the state-of-the-art candidates. Herein, we report a zirconium-MOF, MIP-202(Zr), constructed from natural α-amino acid showing a high and steady proton conductivity of 0.011 S cm-1 at 363 K and under 95% relative humidity. This MOF features a cost-effective, green and scalable preparation with a very high space-time yield above 7000 kg m-3 day-1. It exhibits a good chemical stability under various conditions, including solutions of wide pH range and boiling water. Finally, a comprehensive molecular simulation was carried out to shed light on the proton conduction mechanism. All together these features make MIP-202(Zr) one of the most promising candidates to approach the commercial benchmark Nafion.

journal_name

Nat Commun

journal_title

Nature communications

authors

Wang S,Wahiduzzaman M,Davis L,Tissot A,Shepard W,Marrot J,Martineau-Corcos C,Hamdane D,Maurin G,Devautour-Vinot S,Serre C

doi

10.1038/s41467-018-07414-4

subject

Has Abstract

pub_date

2018-11-22 00:00:00

pages

4937

issue

1

issn

2041-1723

pii

10.1038/s41467-018-07414-4

journal_volume

9

pub_type

杂志文章
  • Ventral hippocampal afferents to the nucleus accumbens regulate susceptibility to depression.

    abstract::Enhanced glutamatergic transmission in the nucleus accumbens (NAc), a region critical for reward and motivation, has been implicated in the pathophysiology of depression; however, the afferent source of this increased glutamate tone is not known. The NAc receives glutamatergic inputs from the medial prefrontal cortex ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms8062

    authors: Bagot RC,Parise EM,Peña CJ,Zhang HX,Maze I,Chaudhury D,Persaud B,Cachope R,Bolaños-Guzmán CA,Cheer JF,Deisseroth K,Han MH,Nestler EJ

    更新日期:2015-05-08 00:00:00

  • Memory consolidation reconfigures neural pathways involved in the suppression of emotional memories.

    abstract::The ability to suppress unwanted emotional memories is crucial for human mental health. Through consolidation over time, emotional memories often become resistant to change. However, how consolidation impacts the effectiveness of emotional memory suppression is still unknown. Using event-related fMRI while concurrentl...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13375

    authors: Liu Y,Lin W,Liu C,Luo Y,Wu J,Bayley PJ,Qin S

    更新日期:2016-11-29 00:00:00

  • How ligand binds to the type 1 insulin-like growth factor receptor.

    abstract::Human type 1 insulin-like growth factor receptor is a homodimeric receptor tyrosine kinase that signals into pathways directing normal cellular growth, differentiation and proliferation, with aberrant signalling implicated in cancer. Insulin-like growth factor binding is understood to relax conformational restraints w...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-03219-7

    authors: Xu Y,Kong GK,Menting JG,Margetts MB,Delaine CA,Jenkin LM,Kiselyov VV,De Meyts P,Forbes BE,Lawrence MC

    更新日期:2018-02-26 00:00:00

  • The composition of British bird communities is associated with long-term garden bird feeding.

    abstract::There is a multi-billion dollar global industry dedicated to feeding wild birds in residential gardens. This extraordinary boost to food resources is almost certainly reshaping entire bird communities, yet the large-scale, long-term impacts on community ecology remain unknown. Here we reveal a 40-year transformation o...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10111-5

    authors: Plummer KE,Risely K,Toms MP,Siriwardena GM

    更新日期:2019-05-21 00:00:00

  • Network curvature as a hallmark of brain structural connectivity.

    abstract::Although brain functionality is often remarkably robust to lesions and other insults, it may be fragile when these take place in specific locations. Previous attempts to quantify robustness and fragility sought to understand how the functional connectivity of brain networks is affected by structural changes, using eit...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12915-x

    authors: Farooq H,Chen Y,Georgiou TT,Tannenbaum A,Lenglet C

    更新日期:2019-10-30 00:00:00

  • Bio-inspired self-shaping ceramics.

    abstract::Shaping ceramics into complex and intricate geometries using cost-effective processes is desirable in many applications but still remains an open challenge. Inspired by plant seed dispersal units that self-fold on differential swelling, we demonstrate that self-shaping can be implemented in ceramics by programming the...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13912

    authors: Bargardi FL,Le Ferrand H,Libanori R,Studart AR

    更新日期:2016-12-23 00:00:00

  • Robust quantum valley Hall effect for vortices in an interacting bosonic quantum fluid.

    abstract::Topologically protected pseudospin transport, analogous to the quantum spin Hall effect, cannot be strictly implemented for photons and in general bosons because of the lack of symmetry-protected pseudospins. Here we show that the required protection can be provided by the real-space topological excitation of an inter...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-06520-7

    authors: Bleu O,Malpuech G,Solnyshkov DD

    更新日期:2018-09-28 00:00:00

  • MCM8IP activates the MCM8-9 helicase to promote DNA synthesis and homologous recombination upon DNA damage.

    abstract::Homologous recombination (HR) mediates the error-free repair of DNA double-strand breaks to maintain genomic stability. Here we characterize C17orf53/MCM8IP, an OB-fold containing protein that binds ssDNA, as a DNA repair factor involved in HR. MCM8IP-deficient cells exhibit HR defects, especially in long-tract gene c...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-16718-3

    authors: Huang JW,Acharya A,Taglialatela A,Nambiar TS,Cuella-Martin R,Leuzzi G,Hayward SB,Joseph SA,Brunette GJ,Anand R,Soni RK,Clark NL,Bernstein KA,Cejka P,Ciccia A

    更新日期:2020-06-11 00:00:00

  • Ultrafast cooling reveals microsecond-scale biomolecular dynamics.

    abstract::The temperature-jump technique, in which the sample is rapidly heated by a powerful laser pulse, has been widely used to probe the fast dynamics of folding of proteins and nucleic acids. However, the existing temperature-jump setups tend to involve sophisticated and expensive instrumentation, while providing only mode...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms6737

    authors: Polinkovsky ME,Gambin Y,Banerjee PR,Erickstad MJ,Groisman A,Deniz AA

    更新日期:2014-12-17 00:00:00

  • Observation of an unpaired photonic Dirac point.

    abstract::At photonic Dirac points, electromagnetic waves are governed by the same equations as two-component massless relativistic fermions. However, photonic Dirac points are known to occur in pairs in "photonic graphene" and other similar photonic crystals, which necessitates special precautions to excite only one valley sta...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-15801-z

    authors: Liu GG,Zhou P,Yang Y,Xue H,Ren X,Lin X,Sun HX,Bi L,Chong Y,Zhang B

    更新日期:2020-04-20 00:00:00

  • Quantifying cerebral contributions to pain beyond nociception.

    abstract::Cerebral processes contribute to pain beyond the level of nociceptive input and mediate psychological and behavioural influences. However, cerebral contributions beyond nociception are not yet well characterized, leading to a predominant focus on nociception when studying pain and developing interventions. Here we use...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14211

    authors: Woo CW,Schmidt L,Krishnan A,Jepma M,Roy M,Lindquist MA,Atlas LY,Wager TD

    更新日期:2017-02-14 00:00:00

  • Microscopic origins of the terahertz carrier relaxation and cooling dynamics in graphene.

    abstract::The ultrafast dynamics of hot carriers in graphene are key to both understanding of fundamental carrier-carrier interactions and carrier-phonon relaxation processes in two-dimensional materials, and understanding of the physics underlying novel high-speed electronic and optoelectronic devices. Many recent experiments ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11617

    authors: Mihnev MT,Kadi F,Divin CJ,Winzer T,Lee S,Liu CH,Zhong Z,Berger C,de Heer WA,Malic E,Knorr A,Norris TB

    更新日期:2016-05-25 00:00:00

  • Superplume mantle tracked isotopically the length of Africa from the Indian Ocean to the Red Sea.

    abstract::Seismological findings show a complex scenario of plume upwellings from a deep thermo-chemical anomaly (superplume) beneath the East African Rift System (EARS). It is unclear if these geophysical observations represent a true picture of the superplume and its influence on magmatism along the EARS. Thus, it is essentia...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-13181-7

    authors: O'Connor JM,Jokat W,Regelous M,Kuiper KF,Miggins DP,Koppers AAP

    更新日期:2019-12-02 00:00:00

  • Vapor-liquid-solid growth of large-area multilayer hexagonal boron nitride on dielectric substrates.

    abstract::Multilayer hexagonal boron nitride (h-BN) is highly desirable as a dielectric substrate for the fabrication of two-dimensional (2D) electronic and optoelectronic devices. However, the controllable synthesis of multilayer h-BN in large areas is still limited in terms of crystallinity, thickness and stacking order. Here...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-14596-3

    authors: Shi Z,Wang X,Li Q,Yang P,Lu G,Jiang R,Wang H,Zhang C,Cong C,Liu Z,Wu T,Wang H,Yu Q,Xie X

    更新日期:2020-02-12 00:00:00

  • Measurement of the first ionization potential of astatine by laser ionization spectroscopy.

    abstract::The radioactive element astatine exists only in trace amounts in nature. Its properties can therefore only be explored by study of the minute quantities of artificially produced isotopes or by performing theoretical calculations. One of the most important properties influencing the chemical behaviour is the energy req...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2819

    authors: Rothe S,Andreyev AN,Antalic S,Borschevsky A,Capponi L,Cocolios TE,De Witte H,Eliav E,Fedorov DV,Fedosseev VN,Fink DA,Fritzsche S,Ghys L,Huyse M,Imai N,Kaldor U,Kudryavtsev Y,Köster U,Lane JF,Lassen J,Liberati V,

    更新日期:2013-01-01 00:00:00

  • Dynamic urea bond for the design of reversible and self-healing polymers.

    abstract::Polymers bearing dynamic covalent bonds may exhibit dynamic properties, such as self-healing, shape memory and environmental adaptation. However, most dynamic covalent chemistries developed so far require either catalyst or change of environmental conditions to facilitate bond reversion and dynamic property change in ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4218

    authors: Ying H,Zhang Y,Cheng J

    更新日期:2014-01-01 00:00:00

  • Highly atroposelective synthesis of nonbiaryl naphthalene-1,2-diamine N-C atropisomers through direct enantioselective C-H amination.

    abstract::Nonbiaryl N-C atropisomer is an important structural scaffold, which is present in natural products, medicines and chiral ligands. However the direct enantioselective C-H amination to access optically pure N-C atropisomer is still difficult and rare. Here we report a π-π interaction and dual H-bond concerted control s...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10858-x

    authors: Bai HY,Tan FX,Liu TQ,Zhu GD,Tian JM,Ding TM,Chen ZM,Zhang SY

    更新日期:2019-07-11 00:00:00

  • Human hypocretin and melanin-concentrating hormone levels are linked to emotion and social interaction.

    abstract::The neurochemical changes underlying human emotions and social behaviour are largely unknown. Here we report on the changes in the levels of two hypothalamic neuropeptides, hypocretin-1 and melanin-concentrating hormone, measured in the human amygdala. We show that hypocretin-1 levels are maximal during positive emoti...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2461

    authors: Blouin AM,Fried I,Wilson CL,Staba RJ,Behnke EJ,Lam HA,Maidment NT,Karlsson KÆ,Lapierre JL,Siegel JM

    更新日期:2013-01-01 00:00:00

  • Tropomodulin3 is a novel Akt2 effector regulating insulin-stimulated GLUT4 exocytosis through cortical actin remodeling.

    abstract::Akt2 and its downstream effectors mediate insulin-stimulated GLUT4-storage vesicle (GSV) translocation and fusion with the plasma membrane (PM). Using mass spectrometry, we identify actin-capping protein Tropomodulin 3 (Tmod3) as an Akt2-interacting partner in 3T3-L1 adipocytes. We demonstrate that Tmod3 is phosphoryl...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms6951

    authors: Lim CY,Bi X,Wu D,Kim JB,Gunning PW,Hong W,Han W

    更新日期:2015-01-09 00:00:00

  • Heat conduction measurements in ballistic 1D phonon waveguides indicate breakdown of the thermal conductance quantization.

    abstract::Emerging quantum technologies require mastering thermal management, especially at the nanoscale. It is now accepted that thermal metamaterial-based phonon manipulation is possible, especially at sub-kelvin temperatures. In these extreme limits of low temperatures and dimensions, heat conduction enters a quantum regime...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-06791-0

    authors: Tavakoli A,Lulla K,Crozes T,Mingo N,Collin E,Bourgeois O

    更新日期:2018-10-16 00:00:00

  • Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability.

    abstract::Interfacial reactions between electrode and electrolyte are critical, either beneficial or detrimental, for the performance of rechargeable batteries. The general approaches of controlling interfacial reactions are either applying a coating layer on cathode or modifying the electrolyte chemistry. Here we demonstrate a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11299-2

    authors: Zou L,Li J,Liu Z,Wang G,Manthiram A,Wang C

    更新日期:2019-08-01 00:00:00

  • GATA2 regulates mast cell identity and responsiveness to antigenic stimulation by promoting chromatin remodeling at super-enhancers.

    abstract::Mast cells are critical effectors of allergic inflammation and protection against parasitic infections. We previously demonstrated that transcription factors GATA2 and MITF are the mast cell lineage-determining factors. However, it is unclear whether these lineage-determining factors regulate chromatin accessibility a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20766-0

    authors: Li Y,Gao J,Kamran M,Harmacek L,Danhorn T,Leach SM,O'Connor BP,Hagman JR,Huang H

    更新日期:2021-01-21 00:00:00

  • The transcript cleavage factor paralogue TFS4 is a potent RNA polymerase inhibitor.

    abstract::TFIIS-like transcript cleavage factors enhance the processivity and fidelity of archaeal and eukaryotic RNA polymerases. Sulfolobus solfataricus TFS1 functions as a bona fide cleavage factor, while the paralogous TFS4 evolved into a potent RNA polymerase inhibitor. TFS4 destabilises the TBP-TFB-RNAP pre-initiation com...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02081-3

    authors: Fouqueau T,Blombach F,Hartman R,Cheung ACM,Young MJ,Werner F

    更新日期:2017-12-04 00:00:00

  • Chunking as the result of an efficiency computation trade-off.

    abstract::How to move efficiently is an optimal control problem, whose computational complexity grows exponentially with the horizon of the planned trajectory. Breaking a compound movement into a series of chunks, each planned over a shorter horizon can thus reduce the overall computational complexity and associated costs while...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms12176

    authors: Ramkumar P,Acuna DE,Berniker M,Grafton ST,Turner RS,Kording KP

    更新日期:2016-07-11 00:00:00

  • Heterologous biosynthesis and characterization of a glycocin from a thermophilic bacterium.

    abstract::The genome of the thermophilic bacterium, Aeribacillus pallidus 8, encodes the bacteriocin pallidocin. It belongs to the small class of glycocins and is posttranslationally modified, containing an S-linked glucose on a specific Cys residue. In this study, the pallidocin biosynthetic machinery is cloned and expressed i...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09065-5

    authors: Kaunietis A,Buivydas A,Čitavičius DJ,Kuipers OP

    更新日期:2019-03-07 00:00:00

  • Transcription factor YcjW controls the emergency H2S production in E. coli.

    abstract::Prokaryotes and eukaryotes alike endogenously generate the gaseous molecule hydrogen sulfide (H2S). Bacterial H2S acts as a cytoprotectant against antibiotics-induced stress and promotes redox homeostasis. In E. coli, endogenous H2S production is primarily dependent on 3-mercaptopyruvate sulfurtransferase (3MST), enco...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10785-x

    authors: Luhachack L,Rasouly A,Shamovsky I,Nudler E

    更新日期:2019-06-28 00:00:00

  • Outlines of the pore in open and closed conformations describe the gating mechanism of ASIC1.

    abstract::The proton-activated sodium channel ASIC1 belongs to the ENaC/Degenerins family of ion channels. Little is known about gating of the pore in any member of this class. Here we outline the shape of the ion pathway of ASIC1 in the open and closed conformations by measuring apparent rates of cysteine modification by thiol...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1409

    authors: Li T,Yang Y,Canessa CM

    更新日期:2011-07-19 00:00:00

  • Publisher Correction: Hierarchical self-entangled carbon nanotube tube networks.

    abstract::The original version of this Article was missing the ORCID ID of Professor Nicola Pugno.Also in the original version of this Article, the third to last sentence of the fourth paragraph of the Results incorrectly read 'However, the stepwise addition of CNTs increases the self-entanglement and thereby the compressive st...

    journal_title:Nature communications

    pub_type: 杂志文章,已发布勘误

    doi:10.1038/s41467-017-02372-9

    authors: Schütt F,Signetti S,Krüger H,Röder S,Smazna D,Kaps S,Gorb SN,Mishra YK,Pugno NM,Adelung R

    更新日期:2018-01-09 00:00:00

  • Ultrasensitive and label-free molecular-level detection enabled by light phase control in magnetoplasmonic nanoantennas.

    abstract::Systems allowing label-free molecular detection are expected to have enormous impact on biochemical sciences. Research focuses on materials and technologies based on exploiting localized surface plasmon resonances in metallic nanostructures. The reason for this focused attention is their suitability for single-molecul...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms7150

    authors: Maccaferri N,Gregorczyk KE,de Oliveira TV,Kataja M,van Dijken S,Pirzadeh Z,Dmitriev A,Åkerman J,Knez M,Vavassori P

    更新日期:2015-02-02 00:00:00

  • The child brain computes and utilizes internalized maternal choices.

    abstract::As children grow, they gradually learn how to make decisions independently. However, decisions like choosing healthy but less-tasty foods can be challenging for children whose self-regulation and executive cognitive functions are still maturing. We propose a computational decision-making process in which children esti...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11700

    authors: Lim SL,Cherry JB,Davis AM,Balakrishnan SN,Ha OR,Bruce JM,Bruce AS

    更新日期:2016-05-24 00:00:00