Lattice doping regulated interfacial reactions in cathode for enhanced cycling stability.

Abstract:

:Interfacial reactions between electrode and electrolyte are critical, either beneficial or detrimental, for the performance of rechargeable batteries. The general approaches of controlling interfacial reactions are either applying a coating layer on cathode or modifying the electrolyte chemistry. Here we demonstrate an approach of modification of interfacial reactions through dilute lattice doping for enhanced battery properties. Using atomic level imaging, spectroscopic analysis and density functional theory calculation, we reveal aluminum dopants in lithium nickel cobalt aluminum oxide are partially dissolved in the bulk lattice with a tendency of enrichment near the primary particle surface and partially exist as aluminum oxide nano-islands that are epitaxially dressed on the primary particle surface. The aluminum concentrated surface lowers transition metal redox energy level and consequently promotes the formation of a stable cathode-electrolyte interphase. The present observations demonstrate a general principle as how the trace dopants modify the solid-liquid interfacial reactions for enhanced performance.

journal_name

Nat Commun

journal_title

Nature communications

authors

Zou L,Li J,Liu Z,Wang G,Manthiram A,Wang C

doi

10.1038/s41467-019-11299-2

subject

Has Abstract

pub_date

2019-08-01 00:00:00

pages

3447

issue

1

issn

2041-1723

pii

10.1038/s41467-019-11299-2

journal_volume

10

pub_type

杂志文章
  • miR-155 regulates differentiation of brown and beige adipocytes via a bistable circuit.

    abstract::Brown adipocytes are a primary site of energy expenditure and reside not only in classical brown adipose tissue but can also be found in white adipose tissue. Here we show that microRNA 155 is enriched in brown adipose tissue and is highly expressed in proliferating brown preadipocytes but declines after induction of ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2742

    authors: Chen Y,Siegel F,Kipschull S,Haas B,Fröhlich H,Meister G,Pfeifer A

    更新日期:2013-01-01 00:00:00

  • Heterozygous diploid and interspecies SCRaMbLEing.

    abstract::SCRaMbLE (Synthetic Chromosome Rearrangement and Modification by LoxP-mediated Evolution) is a genome restructuring technique that can be used in synthetic genomes such as that of Sc2.0, the synthetic yeast genome, which contains hundreds to thousands of strategically positioned loxPsym sites. SCRaMbLE has been used t...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04157-0

    authors: Shen MJ,Wu Y,Yang K,Li Y,Xu H,Zhang H,Li BZ,Li X,Xiao WH,Zhou X,Mitchell LA,Bader JS,Yuan Y,Boeke JD

    更新日期:2018-05-22 00:00:00

  • Robust quantum valley Hall effect for vortices in an interacting bosonic quantum fluid.

    abstract::Topologically protected pseudospin transport, analogous to the quantum spin Hall effect, cannot be strictly implemented for photons and in general bosons because of the lack of symmetry-protected pseudospins. Here we show that the required protection can be provided by the real-space topological excitation of an inter...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-06520-7

    authors: Bleu O,Malpuech G,Solnyshkov DD

    更新日期:2018-09-28 00:00:00

  • DNA methylation at enhancers identifies distinct breast cancer lineages.

    abstract::Breast cancers exhibit genome-wide aberrant DNA methylation patterns. To investigate how these affect the transcriptome and which changes are linked to transformation or progression, we apply genome-wide expression-methylation quantitative trait loci (emQTL) analysis between DNA methylation and gene expression. On a w...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-00510-x

    authors: Fleischer T,Tekpli X,Mathelier A,Wang S,Nebdal D,Dhakal HP,Sahlberg KK,Schlichting E,Oslo Breast Cancer Research Consortium (OSBREAC).,Børresen-Dale AL,Borgen E,Naume B,Eskeland R,Frigessi A,Tost J,Hurtado A,Kristensen VN

    更新日期:2017-11-09 00:00:00

  • MyoD induced enhancer RNA interacts with hnRNPL to activate target gene transcription during myogenic differentiation.

    abstract::Emerging evidence supports roles of enhancer RNAs (eRNAs) in regulating target gene. Here, we study eRNA regulation and function during skeletal myoblast differentiation. We provide a panoramic view of enhancer transcription and categorization of eRNAs. Master transcription factor MyoD is crucial in activating eRNA pr...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-13598-0

    authors: Zhao Y,Zhou J,He L,Li Y,Yuan J,Sun K,Chen X,Bao X,Esteban MA,Sun H,Wang H

    更新日期:2019-12-19 00:00:00

  • Exploring patterns enriched in a dataset with contrastive principal component analysis.

    abstract::Visualization and exploration of high-dimensional data is a ubiquitous challenge across disciplines. Widely used techniques such as principal component analysis (PCA) aim to identify dominant trends in one dataset. However, in many settings we have datasets collected under different conditions, e.g., a treatment and a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04608-8

    authors: Abid A,Zhang MJ,Bagaria VK,Zou J

    更新日期:2018-05-30 00:00:00

  • Benchmarking monolayer MoS2 and WS2 field-effect transistors.

    abstract::Here we benchmark device-to-device variation in field-effect transistors (FETs) based on monolayer MoS2 and WS2 films grown using metal-organic chemical vapor deposition process. Our study involves 230 MoS2 FETs and 160 WS2 FETs with channel lengths ranging from 5 μm down to 100 nm. We use statistical measures to eval...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20732-w

    authors: Sebastian A,Pendurthi R,Choudhury TH,Redwing JM,Das S

    更新日期:2021-01-29 00:00:00

  • Intensification of the meridional temperature gradient in the Great Barrier Reef following the Last Glacial Maximum.

    abstract::Tropical south-western Pacific temperatures are of vital importance to the Great Barrier Reef (GBR), but the role of sea surface temperatures (SSTs) in the growth of the GBR since the Last Glacial Maximum remains largely unknown. Here we present records of Sr/Ca and δ(18)O for Last Glacial Maximum and deglacial corals...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms5102

    authors: Felis T,McGregor HV,Linsley BK,Tudhope AW,Gagan MK,Suzuki A,Inoue M,Thomas AL,Esat TM,Thompson WG,Tiwari M,Potts DC,Mudelsee M,Yokoyama Y,Webster JM

    更新日期:2014-06-17 00:00:00

  • Embedding laser generated nanocrystals in BiVO4 photoanode for efficient photoelectrochemical water splitting.

    abstract::Addressing the intrinsic charge transport limitation of metal oxides has been of significance for pursuing viable PEC water splitting photoelectrodes. Growing a photoelectrode with conductive nanoobjects embedded in the matrix is promising for enhanced charge transport but remains a challenge technically. We herein sh...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10543-z

    authors: Jian J,Xu Y,Yang X,Liu W,Fu M,Yu H,Xu F,Feng F,Jia L,Friedrich D,van de Krol R,Wang H

    更新日期:2019-06-13 00:00:00

  • Rapid mechanochemical encapsulation of biocatalysts into robust metal-organic frameworks.

    abstract::Metal-organic frameworks (MOFs) have recently garnered consideration as an attractive solid substrate because the highly tunable MOF framework can not only serve as an inert host but also enhance the selectivity, stability, and/or activity of the enzymes. Herein, we demonstrate the advantages of using a mechanochemica...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12966-0

    authors: Wei TH,Wu SH,Huang YD,Lo WS,Williams BP,Chen SY,Yang HC,Hsu YS,Lin ZY,Chen XH,Kuo PE,Chou LY,Tsung CK,Shieh FK

    更新日期:2019-11-01 00:00:00

  • Error-correcting dynamics in visual working memory.

    abstract::Working memory is critical to cognition, decoupling behavior from the immediate world. Yet, it is imperfect; internal noise introduces errors into memory representations. Such errors have been shown to accumulate over time and increase with the number of items simultaneously held in working memory. Here, we show that ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11298-3

    authors: Panichello MF,DePasquale B,Pillow JW,Buschman TJ

    更新日期:2019-07-29 00:00:00

  • A novel Nrf2-miR-29-desmocollin-2 axis regulates desmosome function in keratinocytes.

    abstract::The Nrf2 transcription factor controls the expression of genes involved in the antioxidant defense system. Here, we identified Nrf2 as a novel regulator of desmosomes in the epidermis through the regulation of microRNAs. On Nrf2 activation, expression of miR-29a and miR-29b increases in cultured human keratinocytes an...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms6099

    authors: Kurinna S,Schäfer M,Ostano P,Karouzakis E,Chiorino G,Bloch W,Bachmann A,Gay S,Garrod D,Lefort K,Dotto GP,Beer HD,Werner S

    更新日期:2014-10-06 00:00:00

  • Author Correction: The energy cost of polypeptide knot formation and its folding consequences.

    abstract::The original version of this article contained an error in the spelling of the author Christian A.M. Wilson, which was incorrectly given as Christian M.A. Wilson. This has now been corrected in both the PDF and HTML versions of the article. ...

    journal_title:Nature communications

    pub_type: 杂志文章,已发布勘误

    doi:10.1038/s41467-017-02384-5

    authors: Bustamante A,Sotelo-Campos J,Guerra DG,Floor M,Wilson CAM,Bustamante C,Báez M

    更新日期:2017-12-14 00:00:00

  • Polymorphism of dislocation core structures at the atomic scale.

    abstract::Dislocation defects together with their associated strain fields and segregated impurities are of considerable significance in many areas of materials science. However, their atomic-scale structures have remained extremely challenging to resolve, limiting our understanding of these ubiquitous defects. Here, by develop...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4239

    authors: Wang Z,Saito M,McKenna KP,Ikuhara Y

    更新日期:2014-01-01 00:00:00

  • Imaging local electronic corrugations and doped regions in graphene.

    abstract::Electronic structure heterogeneities are ubiquitous in two-dimensional graphene and profoundly impact the transport properties of this material. Here we show the mapping of discrete electronic domains within a single graphene sheet using scanning transmission X-ray microscopy in conjunction with ab initio density func...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1376

    authors: Schultz BJ,Patridge CJ,Lee V,Jaye C,Lysaght PS,Smith C,Barnett J,Fischer DA,Prendergast D,Banerjee S

    更新日期:2011-06-28 00:00:00

  • The NMDA receptor regulates competition of epithelial cells in the Drosophila wing.

    abstract::Cell competition is an emerging principle that eliminates suboptimal or potentially dangerous cells. For 'unfit' cells to be detected, their competitive status needs to be compared to the collective fitness of cells within a tissue. Here we report that the NMDA receptor controls cell competition of epithelial cells an...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-16070-6

    authors: Banreti AR,Meier P

    更新日期:2020-05-06 00:00:00

  • Pentlandite rocks as sustainable and stable efficient electrocatalysts for hydrogen generation.

    abstract::The need for sustainable catalysts for an efficient hydrogen evolution reaction is of significant interest for modern society. Inspired by comparable structural properties of [FeNi]-hydrogenase, here we present the natural ore pentlandite (Fe4.5Ni4.5S8) as a direct 'rock' electrode material for hydrogen evolution unde...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms12269

    authors: Konkena B,Junge Puring K,Sinev I,Piontek S,Khavryuchenko O,Dürholt JP,Schmid R,Tüysüz H,Muhler M,Schuhmann W,Apfel UP

    更新日期:2016-07-27 00:00:00

  • Synthetic ligands for PreQ1 riboswitches provide structural and mechanistic insights into targeting RNA tertiary structure.

    abstract::Riboswitches are naturally occurring RNA aptamers that regulate gene expression by binding to specific small molecules. Riboswitches control the expression of essential bacterial genes and are important models for RNA-small molecule recognition. Here, we report the discovery of a class of synthetic small molecules tha...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09493-3

    authors: Connelly CM,Numata T,Boer RE,Moon MH,Sinniah RS,Barchi JJ,Ferré-D'Amaré AR,Schneekloth JS Jr

    更新日期:2019-04-02 00:00:00

  • Nonstoichiometric acid-base reaction as reliable synthetic route to highly stable CH3NH3PbI3 perovskite film.

    abstract::Perovskite solar cells have received worldwide interests due to swiftly improved efficiency but the poor stability of the perovskite component hampers the device fabrication under normal condition. Herein, we develop a reliable nonstoichiometric acid-base reaction route to stable perovskite films by intermediate chemi...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13503

    authors: Long M,Zhang T,Chai Y,Ng CF,Mak TC,Xu J,Yan K

    更新日期:2016-11-15 00:00:00

  • Chemically induced Jahn-Teller ordering on manganite surfaces.

    abstract::Physical and electrochemical phenomena at the surfaces of transition metal oxides and their coupling to local functionality remains one of the enigmas of condensed matter physics. Understanding the emergent physical phenomena at surfaces requires the capability to probe the local composition, map order parameter field...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms5528

    authors: Gai Z,Lin W,Burton JD,Fuchigami K,Snijders PC,Ward TZ,Tsymbal EY,Shen J,Jesse S,Kalinin SV,Baddorf AP

    更新日期:2014-07-24 00:00:00

  • Changing temporal context in human temporal lobe promotes memory of distinct episodes.

    abstract::Memories of experiences that occur around the same time are linked together by a shared temporal context, represented by shared patterns of neural activity. However, shared temporal context may be problematic for selective retrieval of specific memories. Here, we examine intracranial EEG (iEEG) in the human temporal l...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-08189-4

    authors: El-Kalliny MM,Wittig JH Jr,Sheehan TC,Sreekumar V,Inati SK,Zaghloul KA

    更新日期:2019-01-14 00:00:00

  • Long distance spin communication in chemical vapour deposited graphene.

    abstract::Graphene is an ideal medium for long-distance spin communication in future spintronic technologies. So far, the prospect is limited by the smaller sizes of exfoliated graphene flakes and lower spin transport properties of large-area chemical vapour-deposited (CVD) graphene. Here we demonstrate a high spintronic perfor...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms7766

    authors: Kamalakar MV,Groenveld C,Dankert A,Dash SP

    更新日期:2015-04-10 00:00:00

  • Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation.

    abstract::Transition-metal-catalyzed alkene hydrosilylation is one of the most important homogeneous catalytic reactions, and the development of methods that use base metals, especially iron, as catalysts for this transformation is a growing area of research. However, the limited number of ligand scaffolds applicable for base-m...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02472-6

    authors: Hu MY,He Q,Fan SJ,Wang ZC,Liu LY,Mu YJ,Peng Q,Zhu SF

    更新日期:2018-01-15 00:00:00

  • Global rewiring of cellular metabolism renders Saccharomyces cerevisiae Crabtree negative.

    abstract::Saccharomyces cerevisiae is a Crabtree-positive eukaryal model organism. It is believed that the Crabtree effect has evolved as a competition mechanism by allowing for rapid growth and production of ethanol at aerobic glucose excess conditions. This inherent property of yeast metabolism and the multiple mechanisms und...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-05409-9

    authors: Dai Z,Huang M,Chen Y,Siewers V,Nielsen J

    更新日期:2018-08-03 00:00:00

  • Rational combination of oncolytic vaccinia virus and PD-L1 blockade works synergistically to enhance therapeutic efficacy.

    abstract::Both anti-PD1/PD-L1 therapy and oncolytic virotherapy have demonstrated promise, yet have exhibited efficacy in only a small fraction of cancer patients. Here we hypothesized that an oncolytic poxvirus would attract T cells into the tumour, and induce PD-L1 expression in cancer and immune cells, leading to more suscep...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14754

    authors: Liu Z,Ravindranathan R,Kalinski P,Guo ZS,Bartlett DL

    更新日期:2017-03-27 00:00:00

  • Metallic surface doping of metal halide perovskites.

    abstract::Intentional doping is the core of semiconductor technologies to tune electrical and optical properties of semiconductors for electronic devices, however, it has shown to be a grand challenge for halide perovskites. Here, we show that some metal ions, such as silver, strontium, cerium ions, which exist in the precursor...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20110-6

    authors: Lin Y,Shao Y,Dai J,Li T,Liu Y,Dai X,Xiao X,Deng Y,Gruverman A,Zeng XC,Huang J

    更新日期:2021-01-04 00:00:00

  • Multi-level chirality in liquid crystals formed by achiral molecules.

    abstract::Complex materials often exhibit a hierarchical structure with an intriguing mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. In particular, the chirality of biological molecules such as nucleic acids and amino acids is responsible for the helical structure of D...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09862-y

    authors: Salamończyk M,Vaupotič N,Pociecha D,Walker R,Storey JMD,Imrie CT,Wang C,Zhu C,Gorecka E

    更新日期:2019-04-23 00:00:00

  • Regulation of miR-200c/141 expression by intergenic DNA-looping and transcriptional read-through.

    abstract::The miR-200 family members have been implicated in stress responses and ovarian tumorigenesis. Here, we find that miR-200c/141 transcription is intimately linked to the transcription of the proximal upstream gene PTPN6 (SHP1) in all physiological conditions tested. PTPN6 and miR-200c/141 are transcriptionally co-regul...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9959

    authors: Batista L,Bourachot B,Mateescu B,Reyal F,Mechta-Grigoriou F

    更新日期:2016-01-04 00:00:00

  • Blood coagulation protein fibrinogen promotes autoimmunity and demyelination via chemokine release and antigen presentation.

    abstract::Autoimmunity and macrophage recruitment into the central nervous system (CNS) are critical determinants of neuroinflammatory diseases. However, the mechanisms that drive immunological responses targeted to the CNS remain largely unknown. Here we show that fibrinogen, a central blood coagulation protein deposited in th...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9164

    authors: Ryu JK,Petersen MA,Murray SG,Baeten KM,Meyer-Franke A,Chan JP,Vagena E,Bedard C,Machado MR,Rios Coronado PE,Prod'homme T,Charo IF,Lassmann H,Degen JL,Zamvil SS,Akassoglou K

    更新日期:2015-09-10 00:00:00

  • Freestanding three-dimensional core-shell nanoarrays for lithium-ion battery anodes.

    abstract::Structural degradation and low conductivity of transition-metal oxides lead to severe capacity fading in lithium-ion batteries. Recent efforts to solve this issue have mainly focused on using nanocomposites or hybrids by integrating nanosized metal oxides with conducting additives. Here we design specific hierarchical...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11774

    authors: Tan G,Wu F,Yuan Y,Chen R,Zhao T,Yao Y,Qian J,Liu J,Ye Y,Shahbazian-Yassar R,Lu J,Amine K

    更新日期:2016-06-03 00:00:00