High-energy-density dual-ion battery for stationary storage of electricity using concentrated potassium fluorosulfonylimide.

Abstract:

:Graphite dual-ion batteries represent a potential battery concept for large-scale stationary storage of electricity, especially when constructed free of lithium and other chemical elements with limited natural reserves. Owing to their non-rocking-chair operation mechanism, however, the practical deployment of graphite dual-ion batteries is inherently limited by the need for large quantities of electrolyte solutions as reservoirs of all ions that are needed for complete charge and discharge of the electrodes. Thus far, lithium-free graphite dual-ion batteries have employed moderately concentrated electrolyte solutions (0.3-1 M), resulting in rather low cell-level energy densities of 20-70 Wh kg-1. In this work, we present a lithium-free graphite dual-ion battery utilizing a highly concentrated electrolyte solution of 5 M potassium bis(fluorosulfonyl)imide in alkyl carbonates. The resultant battery offers an energy density of 207 Wh kg-1, along with a high energy efficiency of 89% and an average discharge voltage of 4.7 V.

journal_name

Nat Commun

journal_title

Nature communications

authors

Kravchyk KV,Bhauriyal P,Piveteau L,Guntlin CP,Pathak B,Kovalenko MV

doi

10.1038/s41467-018-06923-6

subject

Has Abstract

pub_date

2018-10-26 00:00:00

pages

4469

issue

1

issn

2041-1723

pii

10.1038/s41467-018-06923-6

journal_volume

9

pub_type

杂志文章
  • Identification of an activation site in Bak and mitochondrial Bax triggered by antibodies.

    abstract::During apoptosis, Bak and Bax are activated by BH3-only proteins binding to the α2-α5 hydrophobic groove; Bax is also activated via a rear pocket. Here we report that antibodies can directly activate Bak and mitochondrial Bax by binding to the α1-α2 loop. A monoclonal antibody (clone 7D10) binds close to α1 in non-act...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11734

    authors: Iyer S,Anwari K,Alsop AE,Yuen WS,Huang DC,Carroll J,Smith NA,Smith BJ,Dewson G,Kluck RM

    更新日期:2016-05-24 00:00:00

  • Ferromagnetism induced by entangled charge and orbital orderings in ferroelectric titanate perovskites.

    abstract::In magnetic materials, the Pauli exclusion principle typically drives anti-alignment between electron spins on neighbouring species resulting in antiferromagnetic behaviour. Ferromagnetism exhibiting spontaneous spin alignment is a fairly rare behaviour, but once materialized is often associated with itinerant electro...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms7677

    authors: Bristowe NC,Varignon J,Fontaine D,Bousquet E,Ghosez P

    更新日期:2015-03-25 00:00:00

  • 4D Visualization of replication foci in mammalian cells corresponding to individual replicons.

    abstract::Since the pioneering proposal of the replicon model of DNA replication 50 years ago, the predicted replicons have not been identified and quantified at the cellular level. Here, we combine conventional and super-resolution microscopy of replication sites in live and fixed cells with computational image analysis. We co...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11231

    authors: Chagin VO,Casas-Delucchi CS,Reinhart M,Schermelleh L,Markaki Y,Maiser A,Bolius JJ,Bensimon A,Fillies M,Domaing P,Rozanov YM,Leonhardt H,Cardoso MC

    更新日期:2016-04-07 00:00:00

  • Improved ethanol electrooxidation performance by shortening Pd-Ni active site distance in Pd-Ni-P nanocatalysts.

    abstract::Incorporating oxophilic metals into noble metal-based catalysts represents an emerging strategy to improve the catalytic performance of electrocatalysts in fuel cells. However, effects of the distance between the noble metal and oxophilic metal active sites on the catalytic performance have rarely been investigated. H...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14136

    authors: Chen L,Lu L,Zhu H,Chen Y,Huang Y,Li Y,Wang L

    更新日期:2017-01-10 00:00:00

  • Terahertz spectroscopy on Faraday and Kerr rotations in a quantum anomalous Hall state.

    abstract::Electrodynamic responses from three-dimensional topological insulators are characterized by the universal magnetoelectric term constituent of the Lagrangian formalism. The quantized magnetoelectric coupling, which is generally referred to as topological magnetoelectric effect, has been predicted to induce exotic pheno...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms12245

    authors: Okada KN,Takahashi Y,Mogi M,Yoshimi R,Tsukazaki A,Takahashi KS,Ogawa N,Kawasaki M,Tokura Y

    更新日期:2016-07-20 00:00:00

  • Metamaterials with index ellipsoids at arbitrary k-points.

    abstract::Propagation behaviors of electromagnetic waves are governed by the equifrequency surface of the medium. Up to now, ordinary materials, including the medium exist in nature and the man-made metamaterials, always have an equifrequency surface (ellipsoid or hyperboloid) centered at zero k-point. Here we propose a new typ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04490-4

    authors: Chen WJ,Hou B,Zhang ZQ,Pendry JB,Chan CT

    更新日期:2018-05-25 00:00:00

  • Harnessing the landscape of microbial culture media to predict new organism-media pairings.

    abstract::Culturing microorganisms is a critical step in understanding and utilizing microbial life. Here we map the landscape of existing culture media by extracting natural-language media recipes into a Known Media Database (KOMODO), which includes >18,000 strain-media combinations, >3300 media variants and compound concentra...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms9493

    authors: Oberhardt MA,Zarecki R,Gronow S,Lang E,Klenk HP,Gophna U,Ruppin E

    更新日期:2015-10-13 00:00:00

  • Genome-wide association meta-analysis identifies GP2 gene risk variants for pancreatic cancer.

    abstract::Pancreatic cancer is the fourth leading cause of cancer-related deaths in Japan. To identify risk loci, we perform a meta-analysis of three genome-wide association studies comprising 2,039 pancreatic cancer patients and 32,592 controls in the Japanese population. Here, we identify 3 (13q12.2, 13q22.1, and 16p12.3) gen...

    journal_title:Nature communications

    pub_type: 杂志文章,meta分析

    doi:10.1038/s41467-020-16711-w

    authors: Lin Y,Nakatochi M,Hosono Y,Ito H,Kamatani Y,Inoko A,Sakamoto H,Kinoshita F,Kobayashi Y,Ishii H,Ozaka M,Sasaki T,Matsuyama M,Sasahira N,Morimoto M,Kobayashi S,Fukushima T,Ueno M,Ohkawa S,Egawa N,Kuruma S,Mori M,

    更新日期:2020-06-24 00:00:00

  • Electron-vibration coupling induced renormalization in the photoemission spectrum of diamondoids.

    abstract::The development of theories and methods devoted to the accurate calculation of the electronic quasi-particle states and levels of molecules, clusters and solids is of prime importance to interpret the experimental data. These quantum systems are often modelled by using the Born-Oppenheimer approximation where the coup...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms11327

    authors: Gali A,Demján T,Vörös M,Thiering G,Cannuccia E,Marini A

    更新日期:2016-04-22 00:00:00

  • Quasi-continuous transition from a Fermi liquid to a spin liquid in κ-(ET)2Cu2(CN)3.

    abstract::The Mott metal-insulator transition-a manifestation of Coulomb interactions among electrons-is known as a discontinuous transition. Recent theoretical studies, however, suggest that the transition is continuous if the Mott insulator carries a spin liquid with a spinon Fermi surface. Here, we demonstrate the case of a ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02679-7

    authors: Furukawa T,Kobashi K,Kurosaki Y,Miyagawa K,Kanoda K

    更新日期:2018-01-22 00:00:00

  • Fibroblast growth factor 21 increases insulin sensitivity through specific expansion of subcutaneous fat.

    abstract::Although the pharmacological effects of fibroblast growth factor 21 (FGF21) are well-documented, uncertainty about its role in regulating excessive energy intake remains. Here, we show that FGF21 improves systemic insulin sensitivity by promoting the healthy expansion of subcutaneous adipose tissue (SAT). Serum FGF21 ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02677-9

    authors: Li H,Wu G,Fang Q,Zhang M,Hui X,Sheng B,Wu L,Bao Y,Li P,Xu A,Jia W

    更新日期:2018-01-18 00:00:00

  • No saturation in the accumulation of alien species worldwide.

    abstract::Although research on human-mediated exchanges of species has substantially intensified during the last centuries, we know surprisingly little about temporal dynamics of alien species accumulations across regions and taxa. Using a novel database of 45,813 first records of 16,926 established alien species, we show that ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14435

    authors: Seebens H,Blackburn TM,Dyer EE,Genovesi P,Hulme PE,Jeschke JM,Pagad S,Pyšek P,Winter M,Arianoutsou M,Bacher S,Blasius B,Brundu G,Capinha C,Celesti-Grapow L,Dawson W,Dullinger S,Fuentes N,Jäger H,Kartesz J,Kenis M

    更新日期:2017-02-15 00:00:00

  • The iBeetle large-scale RNAi screen reveals gene functions for insect development and physiology.

    abstract::Genetic screens are powerful tools to identify the genes required for a given biological process. However, for technical reasons, comprehensive screens have been restricted to very few model organisms. Therefore, although deep sequencing is revealing the genes of ever more insect species, the functional studies predom...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms8822

    authors: Schmitt-Engel C,Schultheis D,Schwirz J,Ströhlein N,Troelenberg N,Majumdar U,Dao VA,Grossmann D,Richter T,Tech M,Dönitz J,Gerischer L,Theis M,Schild I,Trauner J,Koniszewski ND,Küster E,Kittelmann S,Hu Y,Lehmann S,S

    更新日期:2015-07-28 00:00:00

  • The transferability of lipid loci across African, Asian and European cohorts.

    abstract::Most genome-wide association studies are based on samples of European descent. We assess whether the genetic determinants of blood lipids, a major cardiovascular risk factor, are shared across populations. Genetic correlations for lipids between European-ancestry and Asian cohorts are not significantly different from ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-12026-7

    authors: Kuchenbaecker K,Telkar N,Reiker T,Walters RG,Lin K,Eriksson A,Gurdasani D,Gilly A,Southam L,Tsafantakis E,Karaleftheri M,Seeley J,Kamali A,Asiki G,Millwood IY,Holmes M,Du H,Guo Y,Kumari M,Dedoussis G,Li L,Chen Z

    更新日期:2019-09-24 00:00:00

  • A helitron-induced RabGDIα variant causes quantitative recessive resistance to maize rough dwarf disease.

    abstract::Maize rough dwarf disease (MRDD), caused by various species of the genus Fijivirus, threatens maize production worldwide. We previously identified a quantitative locus qMrdd1 conferring recessive resistance to one causal species, rice black-streaked dwarf virus (RBSDV). Here, we show that Rab GDP dissociation inhibito...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-14372-3

    authors: Liu Q,Deng S,Liu B,Tao Y,Ai H,Liu J,Zhang Y,Zhao Y,Xu M

    更新日期:2020-01-24 00:00:00

  • Author Correction: Identification of multiple risk loci and regulatory mechanisms influencing susceptibility to multiple myeloma.

    abstract::The original version of this Article contained an error in the spelling of a member of the PRACTICAL Consortium, Manuela Gago-Dominguez, which was incorrectly given as Manuela Gago Dominguez. This has now been corrected in both the PDF and HTML versions of the Article. Furthermore, in the original HTML version of this...

    journal_title:Nature communications

    pub_type: 杂志文章,已发布勘误

    doi:10.1038/s41467-018-08107-8

    authors: Went M,Sud A,Försti A,Halvarsson BM,Weinhold N,Kimber S,van Duin M,Thorleifsson G,Holroyd A,Johnson DC,Li N,Orlando G,Law PJ,Ali M,Chen B,Mitchell JS,Gudbjartsson DF,Kuiper R,Stephens OW,Bertsch U,Broderick P,Ca

    更新日期:2019-01-10 00:00:00

  • Integrin α7 is a functional cancer stem cell surface marker in oesophageal squamous cell carcinoma.

    abstract::Non-CG methylation has been associated with stemness regulation in embryonic stem cells. By comparing differentially expressed genes affected by non-CG methylation between tumour and corresponding non-tumour tissues in oesophageal squamous cell carcinoma (OSCC), we find that Integrin α7 (ITGA7) is characterized as a p...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13568

    authors: Ming XY,Fu L,Zhang LY,Qin YR,Cao TT,Chan KW,Ma S,Xie D,Guan XY

    更新日期:2016-12-07 00:00:00

  • Metallic surface doping of metal halide perovskites.

    abstract::Intentional doping is the core of semiconductor technologies to tune electrical and optical properties of semiconductors for electronic devices, however, it has shown to be a grand challenge for halide perovskites. Here, we show that some metal ions, such as silver, strontium, cerium ions, which exist in the precursor...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20110-6

    authors: Lin Y,Shao Y,Dai J,Li T,Liu Y,Dai X,Xiao X,Deng Y,Gruverman A,Zeng XC,Huang J

    更新日期:2021-01-04 00:00:00

  • Publisher Correction: Reconciling qualitative, abstract, and scalable modeling of biological networks.

    abstract::An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title:Nature communications

    pub_type: 已发布勘误

    doi:10.1038/s41467-020-18766-1

    authors: Paulevé L,Kolčák J,Chatain T,Haar S

    更新日期:2020-09-24 00:00:00

  • Selective and low temperature transition metal intercalation in layered tellurides.

    abstract::Layered materials embrace rich intercalation reactions to accommodate high concentrations of foreign species within their structures, and find many applications spanning from energy storage, ion exchange to secondary batteries. Light alkali metals are generally most easily intercalated due to their light mass, high ch...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13809

    authors: Yajima T,Koshiko M,Zhang Y,Oguchi T,Yu W,Kato D,Kobayashi Y,Orikasa Y,Yamamoto T,Uchimoto Y,Green MA,Kageyama H

    更新日期:2016-12-14 00:00:00

  • Excited-state vibrational dynamics toward the polaron in methylammonium lead iodide perovskite.

    abstract::Hybrid organic-inorganic perovskites have attractive optoelectronic properties including exceptional solar cell performance. The improved properties of perovskites have been attributed to polaronic effects involving stabilization of localized charge character by structural deformations and polarizations. Here we exami...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04946-7

    authors: Park M,Neukirch AJ,Reyes-Lillo SE,Lai M,Ellis SR,Dietze D,Neaton JB,Yang P,Tretiak S,Mathies RA

    更新日期:2018-06-28 00:00:00

  • A bilateral interfacial passivation strategy promoting efficiency and stability of perovskite quantum dot light-emitting diodes.

    abstract::Perovskite quantum-dot-based light-emitting diodes (QLEDs) possess the features of wide gamut and real color expression, which have been considered as candidates for high-quality lightings and displays. However, massive defects are prone to be reproduced during the quantum dot (QD) film assembly, which would sorely af...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-17633-3

    authors: Xu L,Li J,Cai B,Song J,Zhang F,Fang T,Zeng H

    更新日期:2020-08-06 00:00:00

  • Nanocasting SiO2 into metal-organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts.

    abstract::Single-atom catalysts (SACs) have sparked broad interest recently while the low metal loading poses a big challenge for further applications. Herein, a dual protection strategy has been developed to give high-content SACs by nanocasting SiO2 into porphyrinic metal-organic frameworks (MOFs). The pyrolysis of SiO2@MOF c...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-16715-6

    authors: Jiao L,Zhang R,Wan G,Yang W,Wan X,Zhou H,Shui J,Yu SH,Jiang HL

    更新日期:2020-06-05 00:00:00

  • Observation of an evolving magnetic flux rope before and during a solar eruption.

    abstract::Explosive energy release is a common phenomenon occurring in magnetized plasma systems ranging from laboratories, Earth's magnetosphere, the solar corona and astrophysical environments. Its physical explanation is usually attributed to magnetic reconnection in a thin current sheet. Here we report the important role of...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms1753

    authors: Zhang J,Cheng X,Ding MD

    更新日期:2012-03-20 00:00:00

  • Epigenetic engineering reveals a balance between histone modifications and transcription in kinetochore maintenance.

    abstract::Centromeres consist of specialized centrochromatin containing CENP-A nucleosomes intermingled with H3 nucleosomes carrying transcription-associated modifications. We have designed a novel synthetic biology 'in situ epistasis' analysis in which H3 dimethylated on lysine 4 (H3K4me2) demethylase LSD2 plus synthetic modul...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13334

    authors: Molina O,Vargiu G,Abad MA,Zhiteneva A,Jeyaprakash AA,Masumoto H,Kouprina N,Larionov V,Earnshaw WC

    更新日期:2016-11-14 00:00:00

  • Drawing a high-resolution functional map of adeno-associated virus capsid by massively parallel sequencing.

    abstract::Adeno-associated virus (AAV) capsid engineering is an emerging approach to advance gene therapy. However, a systematic analysis on how each capsid amino acid contributes to multiple functions remains challenging. Here we show proof-of-principle and successful application of a novel approach, termed AAV Barcode-Seq, th...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4075

    authors: Adachi K,Enoki T,Kawano Y,Veraz M,Nakai H

    更新日期:2014-01-01 00:00:00

  • The structural basis of promiscuity in small multidrug resistance transporters.

    abstract::By providing broad resistance to environmental biocides, transporters from the small multidrug resistance (SMR) family drive the spread of multidrug resistance cassettes among bacterial populations. A fundamental understanding of substrate selectivity by SMR transporters is needed to identify the types of selective pr...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-19820-8

    authors: Kermani AA,Macdonald CB,Burata OE,Ben Koff B,Koide A,Denbaum E,Koide S,Stockbridge RB

    更新日期:2020-11-27 00:00:00

  • Quantum Hall states observed in thin films of Dirac semimetal Cd3As2.

    abstract::A well known semiconductor Cd3As2 has reentered the spotlight due to its unique electronic structure and quantum transport phenomena as a topological Dirac semimetal. For elucidating and controlling its topological quantum state, high-quality Cd3As2 thin films have been highly desired. Here we report the development o...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02423-1

    authors: Uchida M,Nakazawa Y,Nishihaya S,Akiba K,Kriener M,Kozuka Y,Miyake A,Taguchi Y,Tokunaga M,Nagaosa N,Tokura Y,Kawasaki M

    更新日期:2017-12-22 00:00:00

  • Single-cell RNA landscape of intratumoral heterogeneity and immunosuppressive microenvironment in advanced osteosarcoma.

    abstract::Osteosarcoma is the most frequent primary bone tumor with poor prognosis. Through RNA-sequencing of 100,987 individual cells from 7 primary, 2 recurrent, and 2 lung metastatic osteosarcoma lesions, 11 major cell clusters are identified based on unbiased clustering of gene expression profiles and canonical markers. The...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20059-6

    authors: Zhou Y,Yang D,Yang Q,Lv X,Huang W,Zhou Z,Wang Y,Zhang Z,Yuan T,Ding X,Tang L,Zhang J,Yin J,Huang Y,Yu W,Wang Y,Zhou C,Su Y,He A,Sun Y,Shen Z,Qian B,Meng W,Fei J,Yao Y,Pan X,Chen P,Hu H

    更新日期:2020-12-10 00:00:00

  • Time-space-resolved origami hierarchical electronics for ultrasensitive detection of physical and chemical stimuli.

    abstract::Recent years have witnessed thriving progress of flexible and portable electronics, with very high demand for cost-effective and tailor-made multifunctional devices. Here, we report on an ingenious origami hierarchical sensor array (OHSA) written with a conductive ink. Thanks to origami as a controllable hierarchical ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09070-8

    authors: Zhang M,Sun JJ,Khatib M,Lin ZY,Chen ZH,Saliba W,Gharra A,Horev YD,Kloper V,Milyutin Y,Huynh TP,Brandon S,Shi G,Haick H

    更新日期:2019-03-08 00:00:00