Liquid phase blending of metal-organic frameworks.

Abstract:

:The liquid and glass states of metal-organic frameworks (MOFs) have recently become of interest due to the potential for liquid-phase separations and ion transport, alongside the fundamental nature of the latter as a new, fourth category of melt-quenched glass. Here we show that the MOF liquid state can be blended with another MOF component, resulting in a domain structured MOF glass with a single, tailorable glass transition. Intra-domain connectivity and short range order is confirmed by nuclear magnetic resonance spectroscopy and pair distribution function measurements. The interfacial binding between MOF domains in the glass state is evidenced by electron tomography, and the relationship between domain size and Tg investigated. Nanoindentation experiments are also performed to place this new class of MOF materials into context with organic blends and inorganic alloys.

journal_name

Nat Commun

journal_title

Nature communications

authors

Longley L,Collins SM,Zhou C,Smales GJ,Norman SE,Brownbill NJ,Ashling CW,Chater PA,Tovey R,Schönlieb CB,Headen TF,Terrill NJ,Yue Y,Smith AJ,Blanc F,Keen DA,Midgley PA,Bennett TD

doi

10.1038/s41467-018-04553-6

subject

Has Abstract

pub_date

2018-06-15 00:00:00

pages

2135

issue

1

issn

2041-1723

pii

10.1038/s41467-018-04553-6

journal_volume

9

pub_type

杂志文章
  • Observation of topological transport quantization by dissipation in fast Thouless pumps.

    abstract::Quantized dynamics is essential for natural processes and technological applications alike. The work of Thouless on quantized particle transport in slowly varying potentials (Thouless pumping) has played a key role in understanding that such quantization may be caused not only by discrete eigenvalues of a quantum syst...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-17510-z

    authors: Fedorova Z,Qiu H,Linden S,Kroha J

    更新日期:2020-07-27 00:00:00

  • Enriched conditioning expands the regenerative ability of sensory neurons after spinal cord injury via neuronal intrinsic redox signaling.

    abstract::Overcoming the restricted axonal regenerative ability that limits functional repair following a central nervous system injury remains a challenge. Here we report a regenerative paradigm that we call enriched conditioning, which combines environmental enrichment (EE) followed by a conditioning sciatic nerve axotomy tha...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-20179-z

    authors: De Virgiliis F,Hutson TH,Palmisano I,Amachree S,Miao J,Zhou L,Todorova R,Thompson R,Danzi MC,Lemmon VP,Bixby JL,Wittig I,Shah AM,Di Giovanni S

    更新日期:2020-12-21 00:00:00

  • Diapause is associated with a change in the polarity of secretion of insulin-like peptides.

    abstract::The insulin/IGF-1 signalling (IIS) pathway plays an important role in the regulation of larval diapause, the long-lived growth arrest state called dauer arrest, in Caenorhabditis elegans. In this nematode, 40 insulin-like peptides (ILPs) have been identified as putative ligands of the IIS pathway; however, it remains ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms10573

    authors: Matsunaga Y,Honda Y,Honda S,Iwasaki T,Qadota H,Benian GM,Kawano T

    更新日期:2016-02-03 00:00:00

  • Metallo-polyelectrolytes as a class of ionic macromolecules for functional materials.

    abstract::The fields of soft polymers and macromolecular sciences have enjoyed a unique combination of metals and organic frameworks in the name of metallopolymers or organometallic polymers. When metallopolymers carry charged groups, they form a class of metal-containing polyelectrolytes or metallo-polyelectrolytes. This revie...

    journal_title:Nature communications

    pub_type: 杂志文章,评审

    doi:10.1038/s41467-018-06475-9

    authors: Zhu T,Sha Y,Yan J,Pageni P,Rahman MA,Yan Y,Tang C

    更新日期:2018-10-18 00:00:00

  • Botulinum toxin A complex exploits intestinal M cells to enter the host and exert neurotoxicity.

    abstract::To cause food-borne botulism, botulinum neurotoxin (BoNT) in the gastrointestinal lumen must traverse the intestinal epithelial barrier. However, the mechanism by which BoNT crosses the intestinal epithelial barrier remains unclear. BoNTs are produced along with one or more non-toxic components, with which they form p...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms7255

    authors: Matsumura T,Sugawara Y,Yutani M,Amatsu S,Yagita H,Kohda T,Fukuoka S,Nakamura Y,Fukuda S,Hase K,Ohno H,Fujinaga Y

    更新日期:2015-02-17 00:00:00

  • Publisher Correction: Proton mediated spin state transition of cobalt heme analogs.

    abstract::In the original version of this Article, the four structural depictions of orbital distributions were inadvertently omitted from Figure 5. This has now been corrected in both the HTML and PDF versions of the Article. ...

    journal_title:Nature communications

    pub_type: 已发布勘误

    doi:10.1038/s41467-019-10880-z

    authors: Zhao J,Peng Q,Wang Z,Xu W,Xiao H,Wu Q,Sun HL,Ma F,Zhao J,Sun CJ,Zhao J,Li J

    更新日期:2019-06-21 00:00:00

  • Electrografting of calix[4]arenediazonium salts to form versatile robust platforms for spatially controlled surface functionalization.

    abstract::An essential issue in the development of materials presenting an accurately functionalized surface is to achieve control of layer structuring. Whereas the very popular method based on the spontaneous adsorption of alkanethiols on metal faces stability problems, the reductive electrografting of aryldiazonium salts yiel...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2121

    authors: Mattiuzzi A,Jabin I,Mangeney C,Roux C,Reinaud O,Santos L,Bergamini JF,Hapiot P,Lagrost C

    更新日期:2012-01-01 00:00:00

  • Genetic circuit characterization by inferring RNA polymerase movement and ribosome usage.

    abstract::To perform their computational function, genetic circuits change states through a symphony of genetic parts that turn regulator expression on and off. Debugging is frustrated by an inability to characterize parts in the context of the circuit and identify the origins of failures. Here, we take snapshots of a large gen...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-18630-2

    authors: Espah Borujeni A,Zhang J,Doosthosseini H,Nielsen AAK,Voigt CA

    更新日期:2020-10-05 00:00:00

  • Engineering and optimising deaminase fusions for genome editing.

    abstract::Precise editing is essential for biomedical research and gene therapy. Yet, homology-directed genome modification is limited by the requirements for genomic lesions, homology donors and the endogenous DNA repair machinery. Here we engineered programmable cytidine deaminases and test if we could introduce site-specific...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms13330

    authors: Yang L,Briggs AW,Chew WL,Mali P,Guell M,Aach J,Goodman DB,Cox D,Kan Y,Lesha E,Soundararajan V,Zhang F,Church G

    更新日期:2016-11-02 00:00:00

  • Dual regulatory switch through interactions of Tcf7l2/Tcf4 with stage-specific partners propels oligodendroglial maturation.

    abstract::Constitutive activation of Wnt/β-catenin inhibits oligodendrocyte myelination. Tcf7l2/Tcf4, a β-catenin transcriptional partner, is required for oligodendrocyte differentiation. How Tcf7l2 modifies β-catenin signalling and controls myelination remains elusive. Here we define a stage-specific Tcf7l2-regulated transcrip...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms10883

    authors: Zhao C,Deng Y,Liu L,Yu K,Zhang L,Wang H,He X,Wang J,Lu C,Wu LN,Weng Q,Mao M,Li J,van Es JH,Xin M,Parry L,Goldman SA,Clevers H,Lu QR

    更新日期:2016-03-09 00:00:00

  • Directional translocation resistance of Zika xrRNA.

    abstract::xrRNAs from flaviviruses survive in host cells because of their exceptional dichotomic response to the unfolding action of different enzymes. They can be unwound, and hence copied, by replicases, and yet can resist degradation by exonucleases. How the same stretch of xrRNA can encode such diverse responses is an open ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-17508-7

    authors: Suma A,Coronel L,Bussi G,Micheletti C

    更新日期:2020-07-27 00:00:00

  • Strong selection during the last millennium for African ancestry in the admixed population of Madagascar.

    abstract::While admixed populations offer a unique opportunity to detect selection, the admixture in most of the studied populations occurred too recently to produce conclusive signals. By contrast, Malagasy populations originate from admixture between Asian and African populations that occurred ~27 generations ago, providing p...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-03342-5

    authors: Pierron D,Heiske M,Razafindrazaka H,Pereda-Loth V,Sanchez J,Alva O,Arachiche A,Boland A,Olaso R,Deleuze JF,Ricaut FX,Rakotoarisoa JA,Radimilahy C,Stoneking M,Letellier T

    更新日期:2018-03-02 00:00:00

  • Surface transfer doping induced effective modulation on ambipolar characteristics of few-layer black phosphorus.

    abstract::Black phosphorus, a fast emerging two-dimensional material, has been configured as field effect transistors, showing a hole-transport-dominated ambipolar characteristic. Here we report an effective modulation on ambipolar characteristics of few-layer black phosphorus transistors through in situ surface functionalizati...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms7485

    authors: Xiang D,Han C,Wu J,Zhong S,Liu Y,Lin J,Zhang XA,Ping Hu W,Özyilmaz B,Neto AH,Wee AT,Chen W

    更新日期:2015-03-12 00:00:00

  • Caspase-11 signaling enhances graft-versus-host disease.

    abstract::Acute graft-versus-host disease (GVHD) remains a major obstacle for the wider usage of allogeneic hematopoietic stem cell transplantation (allo-HSCT), which is an effective therapy for hematopoietic malignancy. Here we show that caspase-11, the cytosolic receptor for bacterial endotoxin (lipopolysaccharide: LPS), enha...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-11895-2

    authors: Lu Y,Meng R,Wang X,Xu Y,Tang Y,Wu J,Xue Q,Yu S,Duan M,Shan D,Wang Q,Wang H,Billiar TR,Xiao X,Chen F,Lu B

    更新日期:2019-09-06 00:00:00

  • In situ observations of an active MoS2 model hydrodesulfurization catalyst.

    abstract::The hydrodesulfurization process is one of the cornerstones of the chemical industry, removing harmful sulfur from oil to produce clean hydrocarbons. The reaction is catalyzed by the edges of MoS2 nanoislands and is operated in hydrogen-oil mixtures at 5-160 bar and 260-380 °C. Until now, it has remained unclear how t...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10526-0

    authors: Mom RV,Louwen JN,Frenken JWM,Groot IMN

    更新日期:2019-06-11 00:00:00

  • Signature of quantum Griffiths singularity state in a layered quasi-one-dimensional superconductor.

    abstract::Quantum Griffiths singularity was theoretically proposed to interpret the phenomenon of divergent dynamical exponent in quantum phase transitions. It has been discovered experimentally in three-dimensional (3D) magnetic metal systems and two-dimensional (2D) superconductors. But, whether this state exists in lower dim...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-07123-y

    authors: Zhang E,Zhi J,Zou YC,Ye Z,Ai L,Shi J,Huang C,Liu S,Lin Z,Zheng X,Kang N,Xu H,Wang W,He L,Zou J,Liu J,Mao Z,Xiu F

    更新日期:2018-11-07 00:00:00

  • Long-lived unipotent Blimp1-positive luminal stem cells drive mammary gland organogenesis throughout adult life.

    abstract::The hierarchical relationships between various stem and progenitor cell subpopulations driving mammary gland morphogenesis and homoeostasis are poorly understood. Conditional inactivation experiments previously demonstrated that expression of the zinc finger transcriptional repressor Blimp1/PRDM1 is essential for the ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-01971-w

    authors: Elias S,Morgan MA,Bikoff EK,Robertson EJ

    更新日期:2017-11-20 00:00:00

  • Excitonic effects from geometric order and disorder explain broadband optical absorption in eumelanin.

    abstract::Eumelanin is a ubiquitous biological pigment, and the origin of its broadband absorption spectrum has long been a topic of scientific debate. Here, we report a first-principles computational investigation to explain its broadband absorption feature. These computations are complemented by experimental results showing a...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms4859

    authors: Chen CT,Chuang C,Cao J,Ball V,Ruch D,Buehler MJ

    更新日期:2014-05-22 00:00:00

  • Exploring the ternary interactions in Cu-ZnO-ZrO2 catalysts for efficient CO2 hydrogenation to methanol.

    abstract::The synergistic interaction among different components in complex catalysts is one of the crucial factors in determining catalytic performance. Here we report the interactions among the three components in controlling the catalytic performance of Cu-ZnO-ZrO2 (CZZ) catalyst for CO2 hydrogenation to methanol. The in sit...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-09072-6

    authors: Wang Y,Kattel S,Gao W,Li K,Liu P,Chen JG,Wang H

    更新日期:2019-03-11 00:00:00

  • Electropolymerization on wireless electrodes towards conducting polymer microfibre networks.

    abstract::Conducting polymers can be easily obtained by electrochemical oxidation of aromatic monomers on an electrode surface as a film state. To prepare conducting polymer fibres by electropolymerization, templates such as porous membranes are necessary in the conventional methods. Here we report the electropolymerization of ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms10404

    authors: Koizumi Y,Shida N,Ohira M,Nishiyama H,Tomita I,Inagi S

    更新日期:2016-01-25 00:00:00

  • Publisher Correction: The TLR7/8 agonist R848 remodels tumor and host responses to promote survival in pancreatic cancer.

    abstract::An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title:Nature communications

    pub_type: 已发布勘误

    doi:10.1038/s41467-019-13151-z

    authors: Michaelis KA,Norgard MA,Zhu X,Levasseur PR,Sivagnanam S,Liudahl SM,Burfeind KG,Olson B,Pelz KR,Ramos DMA,Maurer HC,Olive KP,Coussens LM,Morgan TK,Marks DL

    更新日期:2019-11-15 00:00:00

  • Copper sulfide nanoparticles as a photothermal switch for TRPV1 signaling to attenuate atherosclerosis.

    abstract::Atherosclerosis is characterized by the accumulation of lipids within the arterial wall. Although activation of TRPV1 cation channels by capsaicin may reduce lipid storage and the formation of atherosclerotic lesions, a clinical use for capsaicin has been limited by its chronic toxicity. Here we show that coupling of ...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02657-z

    authors: Gao W,Sun Y,Cai M,Zhao Y,Cao W,Liu Z,Cui G,Tang B

    更新日期:2018-01-15 00:00:00

  • A bright triggered twin-photon source in the solid state.

    abstract::A non-classical light source emitting pairs of identical photons represents a versatile resource of interdisciplinary importance with applications in quantum optics and quantum biology. To date, photon twins have mostly been generated using parametric downconversion sources, relying on Poissonian number distributions,...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms14870

    authors: Heindel T,Thoma A,von Helversen M,Schmidt M,Schlehahn A,Gschrey M,Schnauber P,Schulze JH,Strittmatter A,Beyer J,Rodt S,Carmele A,Knorr A,Reitzenstein S

    更新日期:2017-04-03 00:00:00

  • Tunable self-healing of magnetically propelling colloidal carpets.

    abstract::The process of crystallization is difficult to observe for transported, out-of-equilibrium systems, as the continuous energy injection increases activity and competes with ordering. In emerging fields such as microfluidics and active matter, the formation of long-range order is often frustrated by the presence of hydr...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-10255-4

    authors: Massana-Cid H,Meng F,Matsunaga D,Golestanian R,Tierno P

    更新日期:2019-06-04 00:00:00

  • Taxonomic and functional diversity change is scale dependent.

    abstract::Estimates of recent biodiversity change remain inconsistent, debated, and infrequently assessed for their functional implications. Here, we report that spatial scale and type of biodiversity measurement influence evidence of temporal biodiversity change. We show a pervasive scale dependence of temporal trends in taxon...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04889-z

    authors: Jarzyna MA,Jetz W

    更新日期:2018-07-02 00:00:00

  • Design of highly efficient deep-blue organic afterglow through guest sensitization and matrices rigidification.

    abstract::Blue/deep-blue emission is crucial for organic optoelectronics but remains a formidable challenge in organic afterglow due to the difficulties in populating and stabilizing the high-energy triplet excited states. Here, a facile strategy to realize the efficient deep-blue organic afterglow is proposed via host molecule...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-020-18572-9

    authors: Xu S,Wang W,Li H,Zhang J,Chen R,Wang S,Zheng C,Xing G,Song C,Huang W

    更新日期:2020-09-23 00:00:00

  • The nuclear pore complex prevents sister chromatid recombination during replicative senescence.

    abstract::The Nuclear Pore Complex (NPC) has emerged as an important hub for processing various types of DNA damage. Here, we uncover that fusing a DNA binding domain to the NPC basket protein Nup1 reduces telomere relocalization to nuclear pores early after telomerase inactivation. This Nup1 modification also impairs the reloc...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-019-13979-5

    authors: Aguilera P,Whalen J,Minguet C,Churikov D,Freudenreich C,Simon MN,Géli V

    更新日期:2020-01-09 00:00:00

  • Discordant congenital Zika syndrome twins show differential in vitro viral susceptibility of neural progenitor cells.

    abstract::Congenital Zika syndrome (CZS) causes early brain development impairment by affecting neural progenitor cells (NPCs). Here, we analyze NPCs from three pairs of dizygotic twins discordant for CZS. We compare by RNA-Seq the NPCs derived from CZS-affected and CZS-unaffected twins. Prior to Zika virus (ZIKV) infection the...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-017-02790-9

    authors: Caires-Júnior LC,Goulart E,Melo US,Araujo BHS,Alvizi L,Soares-Schanoski A,de Oliveira DF,Kobayashi GS,Griesi-Oliveira K,Musso CM,Amaral MS,daSilva LF,Astray RM,Suárez-Patiño SF,Ventini DC,Gomes da Silva S,Yamamoto GL,Ez

    更新日期:2018-02-02 00:00:00

  • Mouse urinary peptides provide a molecular basis for genotype discrimination by nasal sensory neurons.

    abstract::Selected groups of peptides, including those that are presented by major histocompatibility complex (MHC) proteins, have been proposed to transmit information to the olfactory system of vertebrates via their ability to stimulate chemosensory neurons. However, the lack of knowledge about such peptides in natural source...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/ncomms2610

    authors: Sturm T,Leinders-Zufall T,Maček B,Walzer M,Jung S,Pömmerl B,Stevanović S,Zufall F,Overath P,Rammensee HG

    更新日期:2013-01-01 00:00:00

  • ADAR1-mediated regulation of melanoma invasion.

    abstract::Melanoma cells use different migratory strategies to exit the primary tumor mass and invade surrounding and subsequently distant tissues. We reported previously that ADAR1 expression is downregulated in metastatic melanoma, thereby facilitating proliferation. Here we show that ADAR1 silencing enhances melanoma cell in...

    journal_title:Nature communications

    pub_type: 杂志文章

    doi:10.1038/s41467-018-04600-2

    authors: Nemlich Y,Baruch EN,Besser MJ,Shoshan E,Bar-Eli M,Anafi L,Barshack I,Schachter J,Ortenberg R,Markel G

    更新日期:2018-05-31 00:00:00