Improved dental adhesive formulations based on reactive nanogel additives.

Abstract:

:Current challenges in adhesive dentistry include over-hydrophilic bonding formulations, which facilitate water percolation through the hybrid layer and result in unreliable bonded interfaces. This study introduces nanogel-modified adhesives as a way to control the material's hydrophobic character without changing the basic monomer formulation (keeping water-chasing capacity and operatory techniques unaltered). Nanogel additives of varied hydrophobicity were synthesized in solution, rendering 10- to 100-nm-sized particles. A model BisGMA/HEMA solvated adhesive was prepared (control), to which reactive nanogels were added. The increase in adhesive viscosity did not impair solvent removal by air-thinning. The degree of conversion in the adhesive was similar between control and nanogel-modified materials, while the bulk dry and, particularly, the wet mechanical properties were significantly improved through nanogel-based network reinforcement and reduced water solubility. As preliminary validation of this approach, short-term micro-tensile bond strengths to acid-etched and primed dentin were significantly enhanced by nanogel inclusion in the adhesive resins.

journal_name

J Dent Res

authors

Morães RR,Garcia JW,Wilson ND,Lewis SH,Barros MD,Yang B,Pfeifer CS,Stansbury JW

doi

10.1177/0022034511426573

subject

Has Abstract

pub_date

2012-02-01 00:00:00

pages

179-84

issue

2

eissn

0022-0345

issn

1544-0591

pii

0022034511426573

journal_volume

91

pub_type

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