Effect of pH on Anaerobic Mild Steel Corrosion by Methanogenic Bacteria.

Abstract:

:Methanogens can use H(2) produced by cathodic depolarization-mediated oxidation of elemental iron to produce methane. Thermodynamic consideration of the cathodic depolarization mechanism predicts more oxidation of Fe at lower pH. Methanogenic responses to pH by Methanococcus deltae, Methanococcus thermolithotrophicus, and Methanosarcina barkeri were examined. When grown on H(2)-CO(2), these bacteria had pH optima from 6.2 to 7.0, but when all H(2) was supplied from Fe, methanogenic pH optima were lower, 5.4 to 6.5. Corrosion was monitored with and without cultures and at various pHs; more corrosion occurred when cultures were present, biologically induced corrosion was greatest at the pH optima for methanogenesis from Fe, and corrosion without cultures increased with a drop in pH.

journal_name

Appl Environ Microbiol

authors

Boopathy R,Daniels L

doi

10.1128/AEM.57.7.2104-2108.1991

keywords:

subject

Has Abstract

pub_date

1991-07-01 00:00:00

pages

2104-8

issue

7

eissn

0099-2240

issn

1098-5336

journal_volume

57

pub_type

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