Abstract:
:The supramolecular self-assembly of macromonomers may serve as a first step to prepare well-defined, highly functionalized, hierarchically structured, conjugated polymers. Functional diacetylene macromonomers equipped with an oligopeptide segment designed to promote self-assembly into parallel beta-sheet type structures and a polydisperse, aliphatic coil segment to prevent global ordering give rise to supramolecular polymers with a tubular double-helical quarternary structure in organic solution. These supramolecular polymers may then be converted into the corresponding poly(diacetylene)s by UV irradiation under retention of their hierarchical structure.
journal_name
Macromol Bioscijournal_title
Macromolecular bioscienceauthors
Jahnke E,Millerioux AS,Severin N,Rabe JP,Frauenrath Hdoi
10.1002/mabi.200600226subject
Has Abstractpub_date
2007-02-12 00:00:00pages
136-43issue
2eissn
1616-5187issn
1616-5195journal_volume
7pub_type
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