Facile synthesis and structural characterization of amylose-Fatty Acid inclusion complexes.

Abstract:

:Amylose-fatty acid inclusion complexes can be easily prepared by simple mixing in hot aqueous solutions. Above a critical chain length (C6) of the fatty acid insoluble complexes between amylose and each fatty acid (C8, C10, C12, C14, C16) were precipitated from the solution, and characterized by FT-IR, XRD, DSC, and SEC. The presence of the characteristic (CO) FT-IR absorption peak at 1 710 cm(-1) confirmed the inclusion of the fatty acids inside the amylose helix. XRD showed the same characteristic features of the V amylose single helical structure. Both SEC and DSC revealed that longer fatty acids can form inclusion complexes with amylose fractions having higher degree of polymerization, leading to greater yields, and higher thermal stability (higher melting temperature and enthalpy) of the amylose-complexes.

journal_name

Macromol Biosci

authors

Cao Z,Woortman AJ,Rudolf P,Loos K

doi

10.1002/mabi.201400464

subject

Has Abstract

pub_date

2015-05-01 00:00:00

pages

691-7

issue

5

eissn

1616-5187

issn

1616-5195

journal_volume

15

pub_type

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