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Tropylium tetrafluoroborate, a novel substrate for aldehyde oxidase.

Abstract：

:The stabilized carbonium ion salt, tropylium tetrafluoroborate, was oxidized to tropone (cycloheptatrienone) by rabbit liver aldehyde oxidase but not by the closely related molybdenum hydroxylase, xanthine oxidase. The tropylium cation is an aromatic hydrocarbon which lacks the aldehyde, imine, or iminium functional groups present in other substrates of aldehyde oxidase. The unique structural features of the tropylium ion should make it a useful tool for mechanistic studies of aldehyde oxidase.

journal_name

Biochem Biophys Res Commun

journal_title

Biochemical and biophysical research communications

authors

Banks RB,Barnett SD

doi

10.1016/0006-291x(86)90775-8

subject

Has Abstract

pub_date

1986-10-30 00:00:00

pages

609-15

issue

2

eissn

0006-291X

issn

1090-2104

pii

0006-291X(86)90775-8

journal_volume

140

pub_type

杂志文章

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