Sesquiterpenoid glycosides from glandular trichomes of the wild tomato relative Solanum habrochaites.

Abstract:

:Profiles of terpenoid glycoside metabolites in glandular trichomes of Solanum habrochaites LA1777 leaves were generated using ultrahigh performance liquid chromatography/time-of-flight mass spectrometry with multiplexing of non-selective collision-induced dissociation (CID). Profiling data suggested a diverse group of 52 sesquiterpenoid glycosides, and fragment ions observed in both non-selective CID mass spectra and true tandem mass spectrometry (MS/MS) product ion spectra documented variation in extent of glycosylation and the presence of malonate or acetate esters. Up to 10 isomers were detected for some metabolites. Malonate and acetate esters of three sesquiterpene diol glucosides and one unmodified diglucoside were purified using reversed phase semipreparative HPLC and analyzed and identified using 1D and 2D NMR and mass spectrometry. All four of the isolated products were glucosides of campheranane-2,12-diol.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Ekanayaka EA,Li C,Jones AD

doi

10.1016/j.phytochem.2013.11.011

subject

Has Abstract

pub_date

2014-02-01 00:00:00

pages

223-31

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(13)00446-9

journal_volume

98

pub_type

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