Bacterial leaching of metal sulfides proceeds by two indirect mechanisms via thiosulfate or via polysulfides and sulfur

Abstract:

:The acid-insoluble metal sulfides FeS2, MoS2, and WS2 are chemically attacked by iron(III) hexahydrate ions, generating thiosulfate, which is oxidized to sulfuric acid. Other metal sulfides are attacked by iron(III) ions and by protons, resulting in the formation of elemental sulfur via intermediary polysulfides. Sulfur is biooxidized to sulfuric acid. This explains leaching of metal sulfides by Thiobacillus thiooxidans.

journal_name

Appl Environ Microbiol

authors

Schippers A,Sand W

doi

10.1128/AEM.65.1.319-321.1999

subject

Has Abstract

pub_date

1999-01-01 00:00:00

pages

319-21

issue

1

eissn

0099-2240

issn

1098-5336

journal_volume

65

pub_type

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