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Mitigating oxygen loss to improve the cycling performance of high capacity cation-disordered cathode materials.

Abstract：

:Recent progress in the understanding of percolation theory points to cation-disordered lithium-excess transition metal oxides as high-capacity lithium-ion cathode materials. Nevertheless, the oxygen redox processes required for these materials to deliver high capacity can trigger oxygen loss, which leads to the formation of resistive surface layers on the cathode particles. We demonstrate here that, somewhat surprisingly, fluorine can be incorporated into the bulk of disordered lithium nickel titanium molybdenum oxides using a standard solid-state method to increase the nickel content, and that this compositional modification is very effective in reducing oxygen loss, improving energy density, average voltage, and rate performance. We argue that the valence reduction on the anion site, offered by fluorine incorporation, opens up significant opportunities for the design of high-capacity cation-disordered cathode materials.The performance of lithium-excess cation-disordered oxides as cathode materials relies on the extent to which the oxygen loss during cycling is mitigated. Here, the authors show that incorporating fluorine is an effective strategy which substantially improves the cycling stability of such a material.

journal_name

Nat Commun

journal_title

Nature communications

authors

Lee J,Papp JK,Clément RJ,Sallis S,Kwon DH,Shi T,Yang W,McCloskey BD,Ceder G

doi

10.1038/s41467-017-01115-0

subject

Has Abstract

pub_date

2017-10-17 00:00:00

pages

981

issue

1

issn

2041-1723

pii

10.1038/s41467-017-01115-0

journal_volume

8

pub_type

杂志文章

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