Abstract:
:External magnetic field is a powerful approach to induce orientational order in originally disordered suspensions of magneto-responsive anisotropic particles. By small angle neutron scattering and optical birefringence measurement technology, we investigated the effect of magnetic field on the spatial ordering of hybrid amyloid fibrils with different aspect ratios (length-to-diameter) and flexibilities decorated by spherical Fe3O4 nanoparticles. A continuous paranematic ordering from an initially isotropic suspension was observed upon increasing magnetic field strength, with spatial orientation increasing with colloidal volume fraction. At constant dimensionless concentration, stiff hybrid fibrils with varying aspect ratios and volume fractions, fall on the same master curve, with equivalent degrees of ordering at identical magnetic fields. However, the semiflexible hybrid fibrils with contour length close to persistence length exhibit a lower degree of alignment. This is consistent with Khokhlov-Semenov theoretical predictions. These findings sharpen the experimental toolbox to design colloidal systems with controllable degree of orientational ordering.
journal_name
Biomacromoleculesjournal_title
Biomacromoleculesauthors
Zhao J,Bolisetty S,Isabettini S,Kohlbrecher J,Adamcik J,Fischer P,Mezzenga Rdoi
10.1021/acs.biomac.6b00539subject
Has Abstractpub_date
2016-08-08 00:00:00pages
2555-61issue
8eissn
1525-7797issn
1526-4602journal_volume
17pub_type
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