A new ether-based electrolyte for dendrite-free lithium-metal based rechargeable batteries.

Abstract:

:A new ether-based electrolyte to match lithium metal electrode is prepared by introducing 1, 4-dioxane as co-solvent into lithium bis(fluorosulfonyl)imide/1,2-dimethoxyethane solution. Under the synergetic effect of solvents and salt, this simple liquid electrolyte presents stable Li cycling with dendrite-free Li deposition even at relatively high current rate, high coulombic efficiency of ca. 98%, and good anodic stability up to ~4.87 V vs Li RE. Its excellent performance will open up a new possibility for high energy-density rechargeable Li metal battery system.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Miao R,Yang J,Xu Z,Wang J,Nuli Y,Sun L

doi

10.1038/srep21771

subject

Has Abstract

pub_date

2016-02-16 00:00:00

pages

21771

issn

2045-2322

pii

srep21771

journal_volume

6

pub_type

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