Continuously Adjustable, Molecular-Sieving "Gate" on 5A Zeolite for Distinguishing Small Organic Molecules by Size.

Abstract:

:Zeolites/molecular sieves with uniform, molecular-sized pores are important for many adsorption-based separation processes. Pore size gaps, however, exist in the current zeolite family. This leads to a great challenge of separating molecules with size differences at ~0.01 nm level. Here, we report a novel concept, pore misalignment, to form a continuously adjustable, molecular-sieving "gate" at the 5A zeolite pore entrance without sacrificing the internal capacity. Misalignment of the micropores of the alumina coating with the 5A zeolite pores was related with and facilely adjusted by the coating thickness. For the first time, organic molecules with sub-0.01 nm size differences were effectively distinguished via appropriate misalignment. This novel concept may have great potential to fill the pore size gaps of the zeolite family and realize size-selective adsorption separation.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Song Z,Huang Y,Xu WL,Wang L,Bao Y,Li S,Yu M

doi

10.1038/srep13981

subject

Has Abstract

pub_date

2015-09-11 00:00:00

pages

13981

issn

2045-2322

pii

srep13981

journal_volume

5

pub_type

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