A generalized non-local optical response theory for plasmonic nanostructures.

Abstract:

:Metallic nanostructures exhibit a multitude of optical resonances associated with localized surface plasmon excitations. Recent observations of plasmonic phenomena at the sub-nanometre to atomic scale have stimulated the development of various sophisticated theoretical approaches for their description. Here instead we present a comparatively simple semiclassical generalized non-local optical response theory that unifies quantum pressure convection effects and induced charge diffusion kinetics, with a concomitant complex-valued generalized non-local optical response parameter. Our theory explains surprisingly well both the frequency shifts and size-dependent damping in individual metallic nanoparticles as well as the observed broadening of the crossover regime from bonding-dipole plasmons to charge-transfer plasmons in metal nanoparticle dimers, thus unravelling a classical broadening mechanism that even dominates the widely anticipated short circuiting by quantum tunnelling. We anticipate that our theory can be successfully applied in plasmonics to a wide class of conducting media, including doped semiconductors and low-dimensional materials such as graphene.

journal_name

Nat Commun

journal_title

Nature communications

authors

Mortensen NA,Raza S,Wubs M,Søndergaard T,Bozhevolnyi SI

doi

10.1038/ncomms4809

subject

Has Abstract

pub_date

2014-05-02 00:00:00

pages

3809

issn

2041-1723

pii

ncomms4809

journal_volume

5

pub_type

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