Crevice corrosion products of dental amalgam.

Abstract:

:The objective of this study was to determine the in vitro corrosion products that resulted from crevice corrosion of low- and high-copper dental amalgams. Specimens were potentiostatically polarized in a chloride-containing electrolyte while set against a PTFE surface to form a crevice. After 16 h, corrosion products were examined by light microscopy, SEM, EDS, and XRD. Analysis showed the presence of three previously reported products [Sn4(OH)6Cl2, SnO, and Cu2O] and a new product, CuCl, which formed on high-copper, gamma 2-free amalgams. Thermodynamic considerations show that CuCl is stable for the reported in vivo potentials of amalgam restorations and the high acidity and high chloride ion concentration associated with crevice corrosion.

journal_name

J Dent Res

authors

Sutow EJ,Jones DW,Hall GC,Owen CG

doi

10.1177/00220345910700071301

subject

Has Abstract

pub_date

1991-07-01 00:00:00

pages

1082-7

issue

7

eissn

0022-0345

issn

1544-0591

journal_volume

70

pub_type

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