Multi-purpose bonding performance of newly synthesized phosphonic acid monomers.

Abstract:

:Multi-purpose bonding performance of three kinds of newly synthesized phosphonic acid monomers was investigated. Methacryloxyalkyl or acryloxyalkyl phosphonoacetates of 6-MHPA, 6-AHPA, 10-MDPA were synthesized in 42.8-51.9% yields with a light yellow viscous liquid, and identified as new compounds by 1H NMR, IR, and elemental analysis. Conventional adhesive monomers, namely VBPA, 4-META, and 4-AETA, and CEBA-p-TSMo-t-BPMA initiator were also used. Seven experimental composite-type adhesive resins comprising these six kinds of adhesive monomers and None (control) with the initiator were prepared. Tensile bond strengths of adhesive resins to unetched ground enamel and dentin, ground porcelain, and sandblasted Ni-Cr alloy were measured at a crosshead speed of 1.0 mm/min. Results showed that except with VBPA, there were no significant differences among 6-MHPA, 6-AHPA, 10-MDPA, 4-AETA, and 4-META in bonding performance to the adherends (p<0.01). It was found that the new phosphonic acid monomers provided good multipurpose adhesion to all adherends tested.

journal_name

Dent Mater J

journal_title

Dental materials journal

authors

Ikemura K,Tay FR,Nishiyama N,Pashley DH,Endo T

doi

10.4012/dmj.26.105

subject

Has Abstract

pub_date

2007-01-01 00:00:00

pages

105-15

issue

1

eissn

0287-4547

issn

1881-1361

journal_volume

26

pub_type

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