Analysis of fracture surface of titanium-porcelain bonding by electron spectroscopy for chemical analysis.

Abstract:

:Three commercially available porcelains bonded to titanium were evaluated to determine the weakest zone of the titanium-porcelain bonding structures. Tensile bond tests were performed for these specimens (NO, DU, and VI) and for Ni-Cr alloy-porcelain bonding samples that served as controls. The maximum bond strengths between porcelain and titanium and the Ni-Cr alloy subjected to different metal surface treatments were compared. Sand blasting effectively increased bond strengths in titanium-porcelain bonding materials. No statistically significant differences in the maximum bond strengths were found between the NO sample and a control; however, sample NO exhibited greater maximum bond strength than DU and VI samples. The bond strengths increased with increasing area fractions of porcelain failure on fracture surfaces. The weakest zones were investigated based on the oxygen chemical states determined by electron spectroscopy for chemical analysis, which include bridging oxygen (Si-O-Si), nonbridging oxygen (Si-O(-) M(+)), and titanium oxide (O(2-)) states. We concluded that the titanium oxide layer is the weakest zone of titanium-porcelain bonding structures.

journal_name

Dent Mater J

journal_title

Dental materials journal

authors

Kannari Y,Endo K,Ida Y,Ochi M,Ohno H

doi

10.4012/dmj.2013-263

subject

Has Abstract

pub_date

2014-01-01 00:00:00

pages

689-95

issue

5

eissn

0287-4547

issn

1881-1361

pii

DN/JST.JSTAGE/dmj/2013-263

journal_volume

33

pub_type

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