Sesquiterpene lactones of Centaurea scoparia.

Abstract:

:From the ethanolic extract of the aerial parts of Centaurea scoparia four new sesquiterpene lactones, belonging to the guaiane class, were isolated and identified, together with a known germacranolide. The structures were elucidated by spectroscopic methods including one- and two-dimensional NMR studies. The relative configuration was deduced from the 2D NOESY spectra. CD spectroscopy of the chlorinated compounds was used for determination of their absolute configuration.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Youssef DT

doi

10.1016/s0031-9422(98)00257-x

subject

Has Abstract

pub_date

1998-11-20 00:00:00

pages

1733-1737

issue

6

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(98)00257-X

journal_volume

49

pub_type

杂志文章
  • Functional characterization and correlation analysis of phenylalanine ammonia-lyase (PAL) in coumarin biosynthesis from Peucedanum praeruptorum Dunn.

    abstract::Coumarins exhibit many biological activities and are the main specialised metabolites of Peucedanum praeruptorum Dunn, an important plant used in traditional Chinese medicine. In preliminary studies, we cloned several genes involved in coumarin biosynthesis in P. praeruptorum, such as 4-coumarate: CoA ligase (4CL), p-...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.11.006

    authors: Sui Z,Luo J,Yao R,Huang C,Zhao Y,Kong L

    更新日期:2019-02-01 00:00:00

  • The structures of antioxidant and cytotoxic agents from natural source: anthraquinones and tannins from roots of Rumex patientia.

    abstract::A new anthraquinone glycoside, emodin-6-O-beta-D-glucopyranoside, and a new simple halogenated flavan-3-ol, 6-chlorocatechin, have been isolated from the roots of Rumex patientia L. together with seven known phenolic compounds. Their structures were elucidated on the basis of spectroscopic methods. Cytotoxic effects a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00337-5

    authors: Demirezer LO,Kuruüzüm-Uz A,Bergere I,Schiewe HJ,Zeeck A

    更新日期:2001-12-01 00:00:00

  • Triterpenoidal saponins from Gleditsia sinensis.

    abstract::Six bisdesmosidic triterpenoidal saponins, gleditsiosides H-K and gleditsia saponins C' and E', were isolated from the anomalous fruits of Gleditsia sinensis. Their structures were established by a combination of extensive NMR (DEPT, DQF-COSY, HETCOR, HOHAHA, HMBC and ROESY) studies and chemical degradation. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00238-1

    authors: Zhang Z,Koike K,Jia Z,Nikaido T,Guo D,Zheng J

    更新日期:1999-10-01 00:00:00

  • Abietane diterpenoids and triterpenoic acids from Salvia cilicica and their antileishmanial activities.

    abstract::Bioguided-fractionation of an acetone extract of the roots of Salvia cilicica (Lamiaceae) led to isolation of two new diterpenes, 7-hydroxy-12-methoxy-20-nor-abieta-1,5(10),7,9,12-pentaen-6,14-dione and abieta-8,12-dien-11,14-dione (12-deoxy-royleanone), together with oleanolic acid, ursolic acid, ferruginol, inuroyol...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00361-8

    authors: Tan N,Kaloga M,Radtke OA,Kiderlen AF,Oksüz S,Ulubelen A,Kolodziej H

    更新日期:2002-12-01 00:00:00

  • Potential sources of high value chemicals from leaves, stems and flowers of Miscanthus sinensis 'Goliath' and Miscanthus sacchariflorus.

    abstract::Society demands chemicals from sustainable sources. Identification of commercially important chemicals in crops increases value in biorefineries and reduces reliance on petrochemicals. Miscanthus sinensis and Miscanthus sacchariflorus are high-yielding distinct plants, which are sources of high-value chemicals and bio...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2013.04.004

    authors: Parveen I,Wilson T,Donnison IS,Cookson AR,Hauck B,Threadgill MD

    更新日期:2013-08-01 00:00:00

  • Dual metabolomics: a novel approach to understanding plant-pathogen interactions.

    abstract::One of the most well-characterised plant pathogenic interactions involves Arabidopsis thaliana and the bacteria Pseudomonas syringae pathovar tomato (Pst). The standard Pst inoculation procedure involves infiltration of large populations of bacteria into plant leaves which means that metabolite changes cannot be readi...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.01.006

    authors: Allwood JW,Clarke A,Goodacre R,Mur LA

    更新日期:2010-04-01 00:00:00

  • Properties of a polynucleotide synthesized by strain 74A of Neurospora crassa.

    abstract::A polynucleotide (or a fragment of RNA) was purified to apparent homogeneity by HPLC from mycelium of the wild strain 74A of the mould Neurospora crassa, after growth on sucrose and in the presence of saturating amounts of inorganic phosphate (Pi) for 72 hr at 30 degrees. The M(r) was ca 20,000 as determined by HPLC a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00531-5

    authors: Carmona EC,Han SW,Palma MS,Rossi A

    更新日期:1996-02-01 00:00:00

  • Early biotic stress detection in tomato (Solanum lycopersicum) by BVOC emissions.

    abstract::We investigated impacts of early and mild biotic stress on Biogenic Volatile Organic Compounds (BVOC) emissions from tomato in order to test their potential for early (biotic) stress detection. Tomato plants were exposed to two common fungal pathogens, Botrytis cinerea and Oidium neolycopesici and the sap-sucking aphi...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.09.006

    authors: Kasal-Slavik T,Eschweiler J,Kleist E,Mumm R,Goldbach HE,Schouten A,Wildt J

    更新日期:2017-12-01 00:00:00

  • A previously undescribed phenylethanoid glycoside from Callicarpa kwangtungensis Chun acts as an agonist of the Na/K-ATPase signal transduction pathway.

    abstract::The new concept that Na/K-ATPase acts as a receptor prompted us to look for new ligands from Callicarpa kwangtungensis Chun. Using column chromatography, an undescribed phenethyl alcohol glycoside, callicarpanoside A, and an undescribed benzyl alcohol glycoside, callicarpanoside B, along with twelve known polyphenols ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2020.112577

    authors: Xu Y,Jiang X,Xu J,Qu W,Xie Z,Jiang RW,Feng F

    更新日期:2021-01-01 00:00:00

  • Hierridin B and 2,4-dimethoxy-6-heptadecyl-phenol, secondary metabolites from the cyanobacterium Phormidium ectocarpi with antiplasmodial activity.

    abstract::Bioassay guided fractionation of the lipophilic extract of the marine cyanobacterium Phormidium ectocarpi yielded a new natural product hierridin B and the previously described compound 2,4-dimethoxy-6-heptadecyl-phenol. Both structures were secured by extensive spectroscopic analysis (1D and 2D NMR, MS, GC-MS, IR). T...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(98)00440-3

    authors: Papendorf O,König GM,Wright AD

    更新日期:1998-12-01 00:00:00

  • Styryl-pyrones from Goniothalamus arvensis.

    abstract::Two novel styrl-pyrones, (+)-garvensintriol and (+)-etharvendiol, together with a known cytotoxic furano-furone, (+)-goniofufurone, have been isolated from the stem bark of Goniothalamus arvensis. A different relative configuration, cis-erythro-erythro for garvensintriol and cis-threo-erythro for etharvendiol, is esta...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(97)00770-x

    authors: Bermejo A,Blázquez MA,Rao KS,Cortes D

    更新日期:1998-04-01 00:00:00

  • Oleanane-type triterpene saponins with collagen synthesis-promoting activity from the flowers of Bellis perennis.

    abstract::The methanol extract from Bellis perennis (Asteraceae) flowers was found to promote collagen synthesis in normal human dermal fibroblasts (NHDFs). Seven oleanane-type triterpene saponins, perennisosides XIII-XIX, and two known saponins, bellissaponins BS5 and BS9, were isolated from the methanol extract. The structure...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2015.05.011

    authors: Morikawa T,Ninomiya K,Takamori Y,Nishida E,Yasue M,Hayakawa T,Muraoka O,Li X,Nakamura S,Yoshikawa M,Matsuda H

    更新日期:2015-08-01 00:00:00

  • Characterization of recombinant nitrile-specifier proteins (NSPs) of Arabidopsis thaliana: dependency on Fe(II) ions and the effect of glucosinolate substrate and reaction conditions.

    abstract::Glucosinolates are plant secondary metabolites that are part of a plant defence system against pathogens and pests, the myrosinase-glucosinolate system, in which glucosinolates get activated by enzymic degradation through thioglucoside glucohydrolases called myrosinases. Epithiospecifier protein (ESP) and nitrile-spec...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2012.08.004

    authors: Kong XY,Kissen R,Bones AM

    更新日期:2012-12-01 00:00:00

  • Cucurbitacins from Bacopa monnieri.

    abstract::Four cucurbitacins, bacobitacin A-D (1-4) as well as, a known cytotoxic, cucurbitacin E (5) together with three known phenylethanoid glycosides, monnieraside I, III and plantioside B were isolated form the aerial part of Bacopa monnieri. Their structures were elucidated on the basis of extensive spectroscopic investig...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2007.03.013

    authors: Bhandari P,Kumar N,Singh B,Kaul VK

    更新日期:2007-05-01 00:00:00

  • Estrogenic properties of coumarins and meroterpene from the fruits of Cullen corylifolium: Experimental and computational studies.

    abstract::Coumarins and meroterpene from the fruits of Cullen corylifolium were evaluated for their ability to bind and activate human estrogen receptor α (hERα) by a combination of in vitro studies and molecular dynamics simulations. The recombinant hERα ligand binding domain (hERα-LBD) was produced in BL21 (DE3)pLysS and the ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.05.010

    authors: Zhang T,Zhong S,Hou L,Li T,Xing X,Guan T,Zhang J,Wang Y

    更新日期:2018-08-01 00:00:00

  • Phytochemical genomics of the Madagascar periwinkle: Unravelling the last twists of the alkaloid engine.

    abstract::The Madagascar periwinkle produces a large palette of Monoterpenoid Indole Alkaloids (MIAs), a class of complex alkaloids including some of the most valuable plant natural products with precious therapeutical values. Evolutionary pressure on one of the hotspots of biodiversity has obviously turned this endemic Malagas...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2014.07.023

    authors: Dugé de Bernonville T,Clastre M,Besseau S,Oudin A,Burlat V,Glévarec G,Lanoue A,Papon N,Giglioli-Guivarc'h N,St-Pierre B,Courdavault V

    更新日期:2015-05-01 00:00:00

  • Mulinane-type diterpenoids from Azorella compacta display antiplasmodial activity.

    abstract::Two mulinane-type diterpenoids were isolated from Azorella compacta; namely 20-hydroxymulin-11,13-dienyl acetate and 13,14-dihydroxymulin-11-en-20-oic acid. The structures were elucidated by analysis of their spectroscopic data. These compounds, as well as three previously isolated diterpenes, were evaluated as potent...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.06.011

    authors: Loyola LA,Bórquez J,Morales G,San-Martín A,Darias J,Flores N,Giménez A

    更新日期:2004-07-01 00:00:00

  • The bio-transformation of ent-19-hydroxykaur-16-en-15-one by Cephalosporium aphidicola.

    abstract::ent-19-Hydroxykaur-16-en-15-one is transformed to ent-3 beta,16 beta,19-trihydroxykauran-15-one by Cephalosporium aphidicola. The structure of this metabolite was established by X-ray crystallography. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(94)85065-8

    authors: Boaventura MA,Hanson JR,Hitchcock PB,Takahashi JA

    更新日期:1994-09-01 00:00:00

  • Identification of endogenous gibberellins in strawberry, including the novel gibberellins GA123, GA124 and GA125.

    abstract::Extracts of carboxylic acids from immature fruits of strawberry (Fragaria x ananassa Duch. cv. Elsanta) were analysed for gibberellins by combined gas chromatography-mass spectrometry. The following previously characterised gibberellins were identified by comparison of their mass spectra and Kovats retention indices (...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00237-5

    authors: Blake PS,Taylor DR,Crisp CM,Mander LN,Owen DJ

    更新日期:2000-12-01 00:00:00

  • Withanolides from aerial parts of Nicandra physalodes.

    abstract::Twenty withanolides, including previously unknown nicanlodes A-M, were isolated from aerial parts of Nicandra physalodes. Their structural elucidations were unambiguously achieved through interpretation of extensive spectroscopic data (NMR and HRMS) and by comparison with literature data. Nicanlodes A and B have an un...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.02.009

    authors: Yu MY,Zhao GT,Liu JQ,Khan A,Peng XR,Zhou L,Dong JR,Li HZ,Qiu MH

    更新日期:2017-05-01 00:00:00

  • Occurrence and biological significance of proanthocyanidins in the American diet.

    abstract::Dietary intake of proanthocyanidins (PAs) has been largely unknown because of the lack of reliable values for their content in foods. Recent development of an analytical method for PAs has allowed the quantification of individual oligomers and polymers. This method has been employed to analyze food samples collected u...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2005.03.025

    authors: Prior RL,Gu L

    更新日期:2005-09-01 00:00:00

  • Characterization and oxidative in vitro cross-linking of an extensin-like protein and a proline-rich protein purified from chickpea cell walls.

    abstract::Two cell wall proteins from chickpea, known to be rapidly insolubilised by an elicitor-stimulated oxidative burst in-vivo, were purified from suspension cells. N-terminal protein sequencing revealed them as a proline-rich protein and an extensin-like protein. Oxidative cross-linking could be modelled in an in vitro sy...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00463-x

    authors: Otte O,Barz W

    更新日期:2000-01-01 00:00:00

  • Vernoguinosterol and vernoguinoside, trypanocidal stigmastane derivatives from Vernonia guineensis (Asteraceae).

    abstract::Two bitter stigmastane derivatives, vernoguinosterol (1) and vernoguinoside (2), have been isolated from the stem bark of Vernonia guineensis and their structures eludicated using spectroscopic methods. The new compounds exhibit trypanocidal activity. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00448-4

    authors: Tchinda AT,Tsopmo A,Tane P,Ayafor JF,Connolly JD,Sterner O

    更新日期:2002-02-01 00:00:00

  • Probing the transcriptome of Aconitum carmichaelii reveals the candidate genes associated with the biosynthesis of the toxic aconitine-type C19-diterpenoid alkaloids.

    abstract::Aconitum carmichaelii has long been used as a traditional Chinese medicine, and its processed lateral roots are known commonly as fuzi. Aconitine-type C19-diterpenoid alkaloids accumulating in the lateral roots are some of the main toxicants of this species, yet their biosynthesis remains largely unresolved. As a firs...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.04.022

    authors: Zhao D,Shen Y,Shi Y,Shi X,Qiao Q,Zi S,Zhao E,Yu D,Kennelly EJ

    更新日期:2018-08-01 00:00:00

  • On the formation of lignin polysaccharide networks in Norway spruce.

    abstract::In this study we were mirroring suggested in vivo phenomena of lignin-hemicellulose complex formation in vitro, by cross-linking Norway spruce (Picea abies) galactoglucomannans, xylans and lignin moieties to high molecular weight complexes by laccase treatment. We were able to observe the oxidation and cross-linking o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.10.027

    authors: Oinonen P,Zhang L,Lawoko M,Henriksson G

    更新日期:2015-03-01 00:00:00

  • Polyacetylene glycosides from Pratia nummularia cultures.

    abstract::Two polyacetylene glycosides, lobetyol 9-O-glc(6)-(1)rha (pratialin-A) and lobetyol 9-O-glc(6)-(1)glc(6)-(1)glc (pratialin-B), were isolated from Pratia nummularia (Campanulaceae) callus and hairy root cultures and their chemical structures were determined by analysis of spectroscopic data. From the methanol extract o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00669-6

    authors: Ishimaru K,Osabe M,Yan L,Fujioka T,Mihashi K,Tanaka N

    更新日期:2003-02-01 00:00:00

  • Antimicrobial constituents of Scrophularia deserti.

    abstract::A study of the chemistry and antibacterial activity of Scrophularia deserti led to the isolation of eight compounds, including the metabolite 3(zeta)-hydroxy-octadeca-4(E),6(Z)-dienoic acid (1). The known compounds ajugoside (2), scropolioside B (3), 6-O-alpha-L-rhamnopyranosylcatalpol (4), buddlejoside A(8) (5), scro...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.05.011

    authors: Stavri M,Mathew KT,Gibbons S

    更新日期:2006-07-01 00:00:00

  • Volatile constituents of wild and in vitro cultivated Gloeophyllum odoratum.

    abstract::The brown-rot fungus Gloeophyllum odoratum was collected from spruce stumps in southern Finland. The volatiles in the fruiting body and fungal cultures grown in malt extract and liquid medium were investigated. Chitin, chitosan and D-(+)-glucosamine at a concentration of 450 mgl-1 medium were used as elicitors. Chitos...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)90463-1

    authors: Kahlos K,Kiviranta JL,Hiltunen RV

    更新日期:1994-07-01 00:00:00

  • Hemicellulosic polysaccharides from bamboo shoot cell-walls.

    abstract::Cell-wall polysaccharides of bamboo shoots were extracted with chelating reagent (CDTA, trans-1,2-cyclohexanediamine-N,N,N',N'-tetraacetic acid), Na(2)CO(3) and KOH solutions. Glycosyl composition and glycosyl linkage analyses showed that the hemicellulose was composed of arabinoxylan, (1-->3, 1-->4)-beta-D-glucan, xy...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(98)00237-4

    authors: Edashige Y,Ishii T

    更新日期:1998-11-20 00:00:00

  • Production of (+)-5-deoxystrigol by Lotus japonicus root culture.

    abstract::Lotus japonicus roots, cultured in a modified B5 medium, produced and secreted germination stimulants that induced Striga hermonthica seed germination. The germination-inducing activity was detected both in the roots and the culture filtrate. Following bioassay-guided purification procedures, an active compound was is...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2007.06.011

    authors: Sugimoto Y,Ueyama T

    更新日期:2008-01-01 00:00:00