Abstract:
:Extracts of carboxylic acids from immature fruits of strawberry (Fragaria x ananassa Duch. cv. Elsanta) were analysed for gibberellins by combined gas chromatography-mass spectrometry. The following previously characterised gibberellins were identified by comparison of their mass spectra and Kovats retention indices (KRIs) with those of standards or published data: GA1, GA3, GA5, GA8, GA12, GA17, GA19, GA20, GA29, GA44, GA48, GA49, GA53, GA77, GA97, GA111 and GA112. Evidence for endogenous 1-epi GA61 (GA119) and 11alpha-OH-GA12 was also obtained. In addition, a number of putative GAs were detected. Of these, three were shown to be 12alpha-hydroxy-GA53, 12alpha-hydroxy-GA44, and 12alpha-hydroxy-GA19 by comparison with authentic compounds prepared by rational synthesis, and have been allocated the descriptors GA123, GA124 and GA125, respectively.
journal_name
Phytochemistryjournal_title
Phytochemistryauthors
Blake PS,Taylor DR,Crisp CM,Mander LN,Owen DJdoi
10.1016/s0031-9422(00)00237-5subject
Has Abstractpub_date
2000-12-01 00:00:00pages
887-90issue
8eissn
0031-9422issn
1873-3700pii
S0031942200002375journal_volume
55pub_type
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