A triterpenoid saponin from Phytolacca esculenta.

Abstract:

:A new triterpenoid saponin, 3-O-[beta-D-glucopyranosyl(1----4)-beta-D- xylopyranosyl]-28-O-beta-D-glucopyranosyl-30-methyloleanate-9(11), 12-dien- 2,3,23-trihydroxyl-28-oic acid, was isolated from the roots of Phytolacca esculenta. The structure was assigned by chemical methods and spectral analysis (1H, 13C, DEPT NMR, EIMS and FABMS) including 1H-1H COSY, 1H-13C COSY and 1H-1H NOESY.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Yi YH

doi

10.1016/0031-9422(92)83327-u

subject

Has Abstract

pub_date

1992-07-01 00:00:00

pages

2552-4

issue

7

eissn

0031-9422

issn

1873-3700

pii

0031-9422(92)83327-U

journal_volume

31

pub_type

杂志文章
  • Tuber borchii fruit body: 2-dimensional profile and protein identification.

    abstract::The formation of the fruit body represents the final phase of the ectomycorrhizal fungus T. borchii life cycle. Very little is known concerning the molecular and biochemical processes involved in the fructification phase. 2-DE maps of unripe and ripe ascocarps revealed different protein expression levels and the compa...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.02.012

    authors: Pierleoni R,Buffalini M,Vallorani L,Guidi C,Zeppa S,Sacconi C,Pucci P,Amoresano A,Casbarra A,Stocchi V

    更新日期:2004-04-01 00:00:00

  • Polygalasaponins XLII-XLVI from roots of Polygala glomerata.

    abstract::Five new oleanane-type saponins, polygalasaponins XLII-XLVI, along with two known saponins were isolated from the roots of Polygala glomerata Lour. The structures of polygalasaponins XLII-XLVI were elucidated as 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl- (1-->2)-{...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(97)00439-1

    authors: Zhang D,Miyase T,Kuroyanagi M,Umehara K,Noguchi H

    更新日期:1998-02-01 00:00:00

  • The biosynthetic origin of oxygen functions in phenylphenalenones of Anigozanthos preissii inferred from NMR- and HRMS-based isotopologue analysis.

    abstract::The biosynthetic origin of 9-phenylphenalenones and the sequence according to which their oxygen functionalities are introduced were studied using nuclear magnetic resonance (NMR) spectroscopy and high-resolution electrospray ionization mass spectrometry (HRESIMS). (13)C-labelled precursors were administered to root c...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.10.007

    authors: Munde T,Maddula RK,Svatos A,Schneider B

    更新日期:2011-01-01 00:00:00

  • Differing mechanisms of simple nitrile formation on glucosinolate degradation in Lepidium sativum and Nasturtium officinale seeds.

    abstract::Glucosinolates are sulphur-containing glycosides found in brassicaceous plants that can be hydrolysed enzymatically by plant myrosinase or non-enzymatically to form primarily isothiocyanates and/or simple nitriles. From a human health perspective, isothiocyanates are quite important because they are major inducers of ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2009.07.035

    authors: Williams DJ,Critchley C,Pun S,Chaliha M,O'Hare TJ

    更新日期:2009-07-01 00:00:00

  • A new triterpenoid from the fern Adiantum lunulatum and evaluation of antibacterial activity.

    abstract::A new triterpenoid, 22,29xi-epoxy-30-norhopane-13beta-ol (1) was isolated together with six known compounds viz., fern-9(11)-en-6alpha-ol. fern-9(11)-ene, fern-9(11)-en-25-oic acid, fern-9(11)-en-28-ol, filicenol-B, adiantone and oxidation product of fern-9(11)-en-6alpha-ol obtained as 6-oxofern-9(11)-ene from the who...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00334-4

    authors: Reddy VL,Ravikanth V,Rao TP,Diwan PV,Venkateswarlu Y

    更新日期:2001-01-01 00:00:00

  • Transformations of testosterone and related steroids by Botrytis cinerea.

    abstract::Botrytis cinerea (strain AM235) was used to investigate the transformations of testosterone and related steroids. It was found that the position and stereochemistry of the introduced hydroxyl group, as well as the yield of products, depended on the structure of the substrate. Botrytis cinerea converts the examined sub...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00490-9

    authors: Huszcza E,Dmochowska-Gładysz J

    更新日期:2003-01-01 00:00:00

  • Ester-type cephalotaxus alkaloids from Cephalotaxus harringtonia var. drupacea.

    abstract::Three alkaloids, neoharringtonine, homoneoharringtonine and 3'S-hydroxyneoharringtonine, were isolated from the leaves and stems of Cephalotaxus harringtonia var. drupacea. Their structures were established by spectroscopic methods, including two-dimensional NMR and CD spectra, and their antileukaemic activity was eva...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(96)00574-2

    authors: Takano I,Yasuda I,Nishijima M,Yanagi Y,Takeya K,Itokawa H

    更新日期:1997-02-01 00:00:00

  • On the propensity of lignin to associate: a size exclusion chromatography study with lignin derivatives isolated from different plant species.

    abstract::Despite evidence that lignin associates under both aqueous and organic media, the magnitude and nature of the underlying driving forces are still a matter of discussion. The present paper addresses this issue by examining both solution properties and size exclusion behaviour of lignins isolated from five different spe...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2007.05.026

    authors: Guerra A,Gaspar AR,Contreras S,Lucia LA,Crestini C,Argyropoulos DS

    更新日期:2007-10-01 00:00:00

  • Methyl angolensate and mexicanolide-type limonoids from the seeds of Cipadessa baccifera.

    abstract::Six new methyl angolensate type (1-6) and three new mexicanolide-type (7-9) limonoids, along with six known limonoids (10-15), were isolated from the seeds of Cipadessa baccifera. The structures of all these compounds were established by extensive 1D, 2D NMR, and HRESIMS experiments, and structures of 11 and 13 were f...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2013.11.006

    authors: Siva B,Poornima B,Venkanna A,Prasad KR,Sridhar B,Nayak VL,Ramakrishna S,Babu KS

    更新日期:2014-02-01 00:00:00

  • Induction of acid phosphatase transcripts, protein and enzymatic activity by simulated herbivory of hybrid poplar.

    abstract::Herbivory and wounding upregulate a large suite of defense genes in hybrid poplar leaves. A strongly wound- and herbivore-induced gene with high similarity to Arabidopsis vegetative storage proteins (VSPs) and acid phosphatase (AP) was identified among genes strongly expressed during the poplar herbivore defense respo...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.01.001

    authors: Veljanovski V,Major IT,Patton JJ,Bol E,Louvet S,Hawkins BJ,Constabel CP

    更新日期:2010-04-01 00:00:00

  • Terpenoids in transformed root culture of Tripterygium wilfordii.

    abstract::Investigation of a hairy root culture of Tripterygium wilfordii var. regelii transformed with Agrobacterium rhizogenes resulted in the isolation of new diterpenoid and sesquiterpenoid together with known triterpenoids. These structures were determined by spectroscopic analyses. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(98)00300-8

    authors: Nakano K,Yoshida C,Furukawa W,Takaishi Y,Shishido K

    更新日期:1998-11-20 00:00:00

  • The biosynthesis of monolignols: a "metabolic grid", or independent pathways to guaiacyl and syringyl units?

    abstract::Lignin is a complex polymer formed by the oxidative polymerization of hydroxycinnamyl alcohol derivatives termed monolignols. The major monolignols in dicotyledonous angiosperm lignin are monomethylated guaiacyl (G) units derived from coniferyl alcohol, and dimethylated syringyl (S) units derived from sinapyl alcohol....

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/s0031-9422(01)00092-9

    authors: Dixon RA,Chen F,Guo D,Parvathi K

    更新日期:2001-08-01 00:00:00

  • Flower color-flower scent associations in polymorphic Hesperis matronalis (Brassicaceae).

    abstract::Floral scent emission rate and composition of purple and white flower color morphs of Hesperis matronalis (Brassicaceae) were determined for two populations and, for each, at two times of day using dynamic headspace collection and GC-MS. The floral volatile compounds identified for this species fell into two main cate...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.12.009

    authors: Majetic CJ,Raguso RA,Tonsor SJ,Ashman TL

    更新日期:2007-03-01 00:00:00

  • Purification and partial sequences of Aralia cordata cinnamyl alcohol dehydrogenase.

    abstract::Cinnamyl alcohol dehydrogenase (CAD) (EC 1.1.1.195) from a dicot, Aralia cordata, was purified to homogeneity and its properties were characterized. The enzyme shows a preference for cinnamyl alcohols and cinnamyl aldehydes as substrates. The M(r) is estimated at 72,000. The enzyme is composed of two heterogeneous sub...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)95137-9

    authors: Hibino T,Shibata D,Umezawa T,Higuchi T

    更新日期:1993-02-01 00:00:00

  • Cyanogenic and non-cyanogenic glycosides from Manihot esculenta.

    abstract::In addition to lotaustralin and linamarin, a novel cyanogenic glycoside, 2-((6-O-(beta-D-apiofuranosyl)-beta-D-glucopyranosyl)oxy)-2-met hylbutanenitrile , two novel non-cyanogenic glycosides, (2S)-((6-O-(beta-D-apiofuranosyl)-beta-D- glucopyranosyl)oxy)butane and 2-((6-O-(beta-D-apiofuranosyl)-beta-D-glucopyranosyl)o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00398-q

    authors: Prawat H,Mahidol C,Ruchirawat S,Prawat U,Tuntiwachwut-tikul P,Tooptakong U,Taylor WC,Pakawatchai C,Skeleton BW,White AH

    更新日期:1995-11-01 00:00:00

  • Phytochemistry and pharmacology of the genus Leonurus: The herb to benefit the mothers and more.

    abstract::Plants belonging to the genus Leonurus, also named motherwort, are traditionally used for anti-gynecological disorder in East Asia, and for sedative in Europe. Chemical investigation of the genus Leonurus not only enriched the natural products library, but also enlarged the pharmacological application of this traditio...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2017.12.016

    authors: Zhang RH,Liu ZK,Yang DS,Zhang XJ,Sun HD,Xiao WL

    更新日期:2018-03-01 00:00:00

  • Polyketide derivatives from a marine-sponge-associated fungus Pestalotiopsis heterocornis.

    abstract::Twelve previously undescribed polyketide derivatives, heterocornols A-L, and seven known analogues were isolated from a culture of the fungus Pestalotiopsis heterocornis associated with sponge. Their structures were elucidated by a comprehensive spectroscopic data analysis and CD Cotton effects. These compounds were e...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.06.009

    authors: Lei H,Lin X,Han L,Ma J,Dong K,Wang X,Zhong J,Mu Y,Liu Y,Huang X

    更新日期:2017-10-01 00:00:00

  • Determination of hydroxycinnamic acids present in Rhododendron species.

    abstract::Hydroxycinnamates including free hydroxycinnamic acids and their chlorogenic acid derivatives and glycosides have been profiled in leaf extracts of 98 Rhododendron species using LC-MS techniques. In total, 69 hydroxycinnamic acid derivatives were identified in the leaves of 98 Rhododendron species. Some derivatives se...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.09.018

    authors: Shrestha A,Hakeem Said I,Grimbs A,Thielen N,Lansing L,Schepker H,Kuhnert N

    更新日期:2017-12-01 00:00:00

  • A galloylated cyanogenic glycoside from the Australian endemic rainforest tree Elaeocarpus sericopetalus (Elaeocarpaceae).

    abstract::A cyanogenic glycoside - 6'-O-galloylsambunigrin - has been isolated from the foliage of the Australian tropical rainforest tree species Elaeocarpus sericopetalus F. Muell. (Elaeocarpaceae). This is the first formal characterisation of a cyanogenic constituent in the Elaeocarpaceae family, and only the second in the o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.03.022

    authors: Miller RE,Stewart M,Capon RJ,Woodrow IE

    更新日期:2006-07-01 00:00:00

  • The alpine violet, Viola biflora, is a rich source of cyclotides with potent cytotoxicity.

    abstract::The cyclotides are currently the largest known family of head-to-tail cyclic proteins. The complex structure of these small plant proteins, which consist of approximately 30 amino acid residues, contains both a circular peptide backbone and a cystine knot, the combination of which produces the cyclic cystine knot moti...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2007.10.023

    authors: Herrmann A,Burman R,Mylne JS,Karlsson G,Gullbo J,Craik DJ,Clark RJ,Göransson U

    更新日期:2008-02-01 00:00:00

  • Antioxidant dehydrotocopherols as a new chemical character of Stemona species.

    abstract::From the roots of various Stemona species four new dehydrotocopherols (chromenols) were isolated and their structures and stereochemistry elucidated by spectroscopic methods. The double bond between C-3 and C-4 proved to be a typical chemical character of the genus found in most of the species. Various C-methylations ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.08.023

    authors: Brem B,Seger C,Pacher T,Hartl M,Hadacek F,Hofer O,Vajrodaya S,Greger H

    更新日期:2004-10-01 00:00:00

  • A bidesmosidic hederagenin hexasaccharide from the roots of Symphytum officinale.

    abstract::A new bidesmosidic triterpenoidal saponin 3-O-[beta-D-glucopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->4)-alpha-L - arabinopyranosyl]-hederagenin-28-O-[alpha-L-rhamnopyranosyl- (1-->4)-beta-D- glucopyranosyl-(1-->6)-beta-D-glucopyranosyl] ester, was isolated from the roots of Symphytum officinale. The structure was a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00246-4

    authors: Mohammad FV,Noorwala M,Ahmad VU,Sener B

    更新日期:1995-09-01 00:00:00

  • Xanthones from Hypericum roeperanum.

    abstract::Four new xanthones have been isolated from the roots of Hypericum roeperanum. Their structures have been established by a combination of spectroscopic and chemical methods as 1,6-dihydroxy-5-methoxy-4',5'-dihydro-4',4',5'-trimethylfurano- (2',3':3,4)-xanthone (5-O-methyl-2-deprenylrheediaxanthone B), 1,6-dihydroxy-5-m...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(96)00284-1

    authors: Rath G,Potterat O,Mavi S,Hostettmann K

    更新日期:1996-09-01 00:00:00

  • Fatty acid profiles and their chemotaxonomy in planktonic species of Anabaena (Cyanobacteria) with straight trichomes.

    abstract::Twenty-four axenic strains of planktonic Anabaena with straight trichomes, assigned to 7 species, were investigated by analyzing the pattern and content of their fatty acid composition and comparing their fatty acid composition with their morphological properties. In general, the fatty acids in planktonic Anabaena con...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00082-6

    authors: Li R,Watanabe MM

    更新日期:2001-07-01 00:00:00

  • Withanolides from aerial parts of Nicandra physalodes.

    abstract::Twenty withanolides, including previously unknown nicanlodes A-M, were isolated from aerial parts of Nicandra physalodes. Their structural elucidations were unambiguously achieved through interpretation of extensive spectroscopic data (NMR and HRMS) and by comparison with literature data. Nicanlodes A and B have an un...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.02.009

    authors: Yu MY,Zhao GT,Liu JQ,Khan A,Peng XR,Zhou L,Dong JR,Li HZ,Qiu MH

    更新日期:2017-05-01 00:00:00

  • Leishmanicidal effect of LLD-3 (1), a nor-triterpene isolated from Lophanthera lactescens.

    abstract::Leishmanicidal activity of 6alpha, 7alpha, 15beta, 16beta, 24-pentacetoxy-22alpha-carbometoxy-21beta,22beta-epoxy-18beta-hydroxy-27,30-bisnor-3,4-secofriedela-1,20 (29)-dien-3,4 R-olide (LLD-3 (1)) isolated from Lophanthera lactescens Ducke, a member of the Malpighiaceae, was demonstrated against intramacrophage amast...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2009.03.009

    authors: Danelli MG,Soares DC,Abreu HS,Peçanha LM,Saraiva EM

    更新日期:2009-03-01 00:00:00

  • Comparative analysis of CYP93E proteins for improved microbial synthesis of plant triterpenoids.

    abstract::Cytochrome P450-dependent monooxygenases (P450s) belonging to the CYP93E subfamily catalyze the C-24 oxidation of the triterpene backbone during the biosynthesis of triterpenoid saponins, which are bioactive plant natural products. In our attempts to produce plant triterpenoids in the yeast Saccharomyces cerevisiae, w...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.10.002

    authors: Moses T,Thevelein JM,Goossens A,Pollier J

    更新日期:2014-12-01 00:00:00

  • Hypoglycemic activity of withanolides and elicitated Withania somnifera.

    abstract::Withania somnifera, known in India as Asghawhanda, is used traditionally to treat many medical problems including diabetes and has demonstrated therapeutic activity in various animal models as well as in diabetic patients. While much of W. somnifera's therapeutic activity is attributed to withanolides, their role in t...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2015.02.029

    authors: Gorelick J,Rosenberg R,Smotrich A,Hanuš L,Bernstein N

    更新日期:2015-08-01 00:00:00

  • Limonoids from the fruits of Melia toosendan and their NF-κB modulating activities.

    abstract::Eight ring C-seco and ring-intact limonoids, and 25 known limonoids were isolated from the fruits of Melia toosendan (Meliaceae). Their structures were elucidated on the basis of extensive spectroscopic evidence including HRMS, 1D and 2D NMR spectroscopic data. A total of 29 isolated limonoids was evaluated for NF-κB ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.08.009

    authors: Zhu GY,Bai LP,Liu L,Jiang ZH

    更新日期:2014-11-01 00:00:00

  • Triterpene saponins from Eryngium kotschyi.

    abstract::Four new oleanane-type saponins 3-O-α-L-rhamnopyranosyl-(1 → 4)-β-D-glucuronopyranosyl-22-O-β,β-dimethylacryloylA1-barrigenol (1), 3-O-α-L-rhamnopyranosyl-(1 → 4)-β-D-glucuronopyranosyl-22-O-angeloylA1-barrigenol (2), 3-O-β-D-glucopyranosyl-(1 → 2)-[β-D-glucopyranosyl-(1 → 6)]-β-D-glucopyranosyl-21,22,28-O-triacetyl-(...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.11.017

    authors: Aslan Erdem S,Mitaine-Offer AC,Miyamoto T,Kartal M,Lacaille-Dubois MA

    更新日期:2015-02-01 00:00:00