A bidesmosidic hederagenin hexasaccharide from the roots of Symphytum officinale.

Abstract:

:A new bidesmosidic triterpenoidal saponin 3-O-[beta-D-glucopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->4)-alpha-L - arabinopyranosyl]-hederagenin-28-O-[alpha-L-rhamnopyranosyl- (1-->4)-beta-D- glucopyranosyl-(1-->6)-beta-D-glucopyranosyl] ester, was isolated from the roots of Symphytum officinale. The structure was assigned by chemical methods and spectral analysis (1H, 13C, DEPT, NMR, EI-MS and FAB-MS) including 1H-1H COSY, 1H-13C COSY and HOHAHA. The prosapogenin of this saponin is also a new compound.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Mohammad FV,Noorwala M,Ahmad VU,Sener B

doi

10.1016/0031-9422(95)00246-4

subject

Has Abstract

pub_date

1995-09-01 00:00:00

pages

213-8

issue

1

eissn

0031-9422

issn

1873-3700

pii

0031942295002464

journal_volume

40

pub_type

杂志文章
  • Polyacetylene glycosides from Pratia nummularia cultures.

    abstract::Two polyacetylene glycosides, lobetyol 9-O-glc(6)-(1)rha (pratialin-A) and lobetyol 9-O-glc(6)-(1)glc(6)-(1)glc (pratialin-B), were isolated from Pratia nummularia (Campanulaceae) callus and hairy root cultures and their chemical structures were determined by analysis of spectroscopic data. From the methanol extract o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00669-6

    authors: Ishimaru K,Osabe M,Yan L,Fujioka T,Mihashi K,Tanaka N

    更新日期:2003-02-01 00:00:00

  • Steroidal saponins from the leaves of Beaucarnea recurvata.

    abstract::Thirteen steroidal saponins were isolated from the leaves of Beaucarnea recurvata Lem. Their structures were established using one- and two-dimensional NMR spectroscopy and mass spectrometry. Six of them were identified as: 26-O-β-D-glucopyranosyl (25S)-furosta-5,20(22)-diene 1β,3β,26-triol 1-O-α-L-rhamnopyranosyl-(1→...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2011.03.004

    authors: Eskander J,Lavaud C,Harakat D

    更新日期:2011-06-01 00:00:00

  • 5-Lipoxygenase-derived oxylipins from the red alga Rhodymenia pertusa.

    abstract::The lipid extract of the temperate red alga Rhodymenia pertusa has yielded four eicosanoid metabolites, three of which are new natural products. Using principally NMR and MS techniques, their structures were deduced as 5R,6S-dihydroxy-7(E),9(E),11(Z),14(Z)-eicosatetraenoic acid (5R,6S-diHETE), 5R*,6S*-dihydroxy-7(E),9...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00445-8

    authors: Jiang ZD,Ketchum SO,Gerwick WH

    更新日期:2000-01-01 00:00:00

  • Glutathione reductase activity and isoforms in leaves and roots of wheat plants subjected to cadmium stress.

    abstract::The behavior of glutathione reductase (GR, EC 1.6.4.2) activity and isoforms were analyzed in wheat (Triticum aestivum L.) leaves and roots exposed to a chronic treatment with a toxic cadmium (Cd) concentration. A significant growth inhibition (up to 55%) was found in leaves at 7, 14 and 21 days, whereas roots were af...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.11.016

    authors: Yannarelli GG,Fernández-Alvarez AJ,Santa-Cruz DM,Tomaro ML

    更新日期:2007-02-01 00:00:00

  • Occurrence and characterization of oils rich in gamma-linolenic acid (III): the taxonomical value of the fatty acids in Echium (Boraginaceae).

    abstract::Fourteen species of the genus Echium (Fam. Boraginaceae) collected in the Macaronesia were surveyed in a search for high levels of gamma-linolenic acid (GLA, 18:3omega6) in the seed oil. High amounts of this fatty acid were found in all of them, ranging from 18.85% (E. pitardii var. pitardii) to 27.42% (E. gentianoide...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00184-4

    authors: Guil-Guerrero JL,Gómez-Mercado F,Rodríguez-García I,Campra-Madrid P,García-Maroto F

    更新日期:2001-09-01 00:00:00

  • Annosenegalin and annogalene: two cytotoxic mono-tetrahydrofuran acetogenins from Annona senegalensis and Annona cherimolia.

    abstract::Two new cytotoxic mono-tetrahydrofuran acetongenins, annosenegalin and annogalene, have been isolated from the cytotoxic methanolic extract of Annona senegalensis and A. cherimolia seeds. Their structures were established on the basis of 1D and 2D NMR spectroscopic techniques. Annosenegalin belongs to the rare type of...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00891-8

    authors: Sahpaz S,González MC,Hocquemiller R,Zafra-Polo MC,Cortes D

    更新日期:1996-05-01 00:00:00

  • Exudation of fluorescent beta-carbolines from Oxalis tuberosa L roots.

    abstract::Root fluorescence is a phenomenon in which roots of seedlings fluoresce when irradiated with ultraviolet (UV) light. Soybean (Glycine max) and rye grass (Elymus glaucus) are the only plant species that have been reported to exhibit this occurrence in germinating seedling roots. The trait has been useful as a marker in...

    journal_title:Phytochemistry

    pub_type: 杂志文章,收录出版

    doi:10.1016/s0031-9422(02)00235-2

    authors: Bais HP,Park SW,Stermitz FR,Halligan KM,Vivanco JM

    更新日期:2002-11-01 00:00:00

  • A lipase inhibitor monoterpene and monoterpene glycosides from Monarda punctata.

    abstract::An 80% acetone extract of Monarda punctata showed an inhibitory effect on lipase activity in isolated mouse plasma in vitro and carvacrol was obtained as the active constituent. It had an IC₅₀ value of 4.07 mM invitro and suppressed elevations in blood triacylglycerol levels in olive oil-loaded mice. Furthermore, from...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.08.009

    authors: Yamada K,Murata T,Kobayashi K,Miyase T,Yoshizaki F

    更新日期:2010-11-01 00:00:00

  • Dietary phytoestrogens and health.

    abstract::The interest in the potential health effects of dietary phytoestrogens has increased with the findings that hormone replacement therapy is not as safe or effective as previously thought. This review summarizes the dietary sources of the phytoestrogens; isoflavonoids, stilbenes, coumestans and lignans. It also examines...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2004.03.005

    authors: Cornwell T,Cohick W,Raskin I

    更新日期:2004-04-01 00:00:00

  • Ginsenosides from American ginseng: chemical and pharmacological diversity.

    abstract::Ginseng occupies a prominent position in the list of best-selling natural products in the world. Compared to the long history of use and widespread research on Asian ginseng, the study of American ginseng is relatively limited. In the past decade, some promising advances have been achieved in understanding the chemist...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2011.02.012

    authors: Qi LW,Wang CZ,Yuan CS

    更新日期:2011-06-01 00:00:00

  • Dimeric antioxidant and cytotoxic triterpenoid saponins from Terminalia ivorensis A. Chev.

    abstract::Three saponins, including two dimeric triterpenoid glucosides possessing an unusual skeleton, ivorenosides A and B, and a monomeric triterpenoid saponin (ivorenoside C), together with the known sericoside, were isolated from the bark of Terminalia ivorensis. Their structures were established on the basis of 1D and 2D ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.08.020

    authors: Ponou BK,Teponno RB,Ricciutelli M,Quassinti L,Bramucci M,Lupidi G,Barboni L,Tapondjou LA

    更新日期:2010-12-01 00:00:00

  • Tetrahydroisoquinoline-monoterpene and iridoid glycosides from Alangium lamarckii.

    abstract::From the water soluble fraction of the dried fruits of Alangium lamrckii, four tetrahydroisoquinoline-monoterpene glycosides, 6-O-methyl-N-deacetylisoipecosidic acid, 7-O-methyl-N-deacetylisoipecosidic acid, 6,7-di-O-methyl-N-deacetylisoipecosidic acid and 6"-O-alpha-D-glucopyranosyl-6-O-methyl-N-deacetylisoipecosidic...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00417-9

    authors: Itoh A,Tanahashi T,Tabata M,Shikata M,Kakite M,Nagai M,Nagakura N

    更新日期:2001-03-01 00:00:00

  • Isolation and identification of lateral bud growth inhibitor, indole-3-aldehyde, involved in apical dominance of pea seedlings.

    abstract::A lateral bud growth inhibitor was isolated from etiolated pea seedlings and identified as indole-3-aldehyde. The indole-3-aldehyde content was significantly higher in the diffusates from explants with apical bud and indole-3-acetic acid treated decapitated explants, in which apical dominance is maintained, than in th...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00400-4

    authors: Nakajima E,Nakano H,Yamada K,Shigemori H,Hasegawa K

    更新日期:2002-12-01 00:00:00

  • Purification, sequencing and characterization of phospholipase D from Indian mustard seeds.

    abstract::Phospholipase D (PLD; E.C. 3.1.4.4) is widespread in plants where it fulfills diverse functions in growth and in the response to stresses. The enzyme occurs in multiple forms that differ in their biochemical properties. In the present paper PLD from medicinally relevant Indian mustard seeds was purified by Ca(2+)-medi...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2015.05.022

    authors: Khatoon H,Mansfeld J,Schierhorn A,Ulbrich-Hofmann R

    更新日期:2015-09-01 00:00:00

  • Acylated triterpene saponins from Silene jenisseensis.

    abstract::From the roots of Silene jenisseensis a new trans-p-methoxycinnamoyl triterpene saponin has been isolated along with its cis-p-methoxycinnamoyl isomer as an inseparable mixture. Their structures were established by chemical means and spectroscopic methods including 1D- and 2D-homonuclear and heteronuclear correlation ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00222-s

    authors: Lacaille-Dubois MA,Hanquet B,Cui ZH,Lou ZC,Wagner H

    更新日期:1995-09-01 00:00:00

  • Functional characterisation of a tropine-forming reductase gene from Brugmansia arborea, a woody plant species producing tropane alkaloids.

    abstract::Brugmansia arborea is a woody plant species that produces tropane alkaloids (TAs). The gene encoding tropine-forming reductase or tropinone reductase I (BaTRI) in this plant species was functionally characterised. The full-length cDNA of BaTRI encoded a 272-amino-acid polypeptide that was highly similar to tropinone r...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2016.03.008

    authors: Qiang W,Xia K,Zhang Q,Zeng J,Huang Y,Yang C,Chen M,Liu X,Lan X,Liao Z

    更新日期:2016-07-01 00:00:00

  • Glucosinolates, flea beetle resistance, and leaf pubescence as taxonomic characters in the genus Barbarea (Brassicaceae).

    abstract::Glucosinolate content of leaves and roots, diversity in leaf pubescence, and resistance to two near-isogenic lines of the flea beetle Phyllotreta nemorum with or without an R-gene, were determined for 27 accessions of 7 Barbarea taxa, i.e. B. stricta, B. orthoceras, B. intermedia, B. verna, B. vulgaris var. vulgaris, ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00750-1

    authors: Agerbirk N,Ørgaard M,Nielsen JK

    更新日期:2003-05-01 00:00:00

  • Polygalasaponins XLII-XLVI from roots of Polygala glomerata.

    abstract::Five new oleanane-type saponins, polygalasaponins XLII-XLVI, along with two known saponins were isolated from the roots of Polygala glomerata Lour. The structures of polygalasaponins XLII-XLVI were elucidated as 3-O-beta-D-glucopyranosyl presenegenin 28-O-beta-D-xylopyranosyl-(1-->4)-alpha-L-rhamnopyranosyl- (1-->2)-{...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(97)00439-1

    authors: Zhang D,Miyase T,Kuroyanagi M,Umehara K,Noguchi H

    更新日期:1998-02-01 00:00:00

  • Glycolipid composition of Hevea brasiliensis latex.

    abstract::Glycolipids of fresh latex from three clones of Hevea brasiliensis were characterized and quantified by HPLC/ESI-MS. Their fatty acyl and sterol components were further confirmed by GC/MS after saponification. The four detected glycolipid classes were steryl glucosides (SG), esterified steryl glucosides (ESG), monogal...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2011.04.023

    authors: Liengprayoon S,Sriroth K,Dubreucq E,Vaysse L

    更新日期:2011-10-01 00:00:00

  • Triumphalone, a diketone from the volatile oil of the leaves of Melaleuca triumphalis, and its spontaneous conversion into isotriumphalone.

    abstract::The major component (35-65%) of the volatile oil obtained by steam distillation of the leaves of Melaleuca triumphalis has been identified as (rel)-1beta-pentyl-1alpha,6alpha-dihydroxy-3,3,5,5-tetramethylcyclohexa-2,4-dione (trivial name triumphalone). Relative stereochemistry was established by nuclear Overhauser exp...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.06.003

    authors: Brophy JJ,Craig DC,Goldsack RJ,Fookes CJ,Leach DN,Waterman PG

    更新日期:2006-09-01 00:00:00

  • Biosynthesis of andrographolide in Andrographis paniculata.

    abstract::Andrographolide, a diterpene lactone, is isolated from Andrographis paniculata which is well known for its medicinal properties. The biosynthetic route to andrographolide was studied using [1-(13)C]acetate, [2-(13)C]acetate and [1,6-(13)C(2)]glucose. The peak enrichment of eight carbon atoms in the (13)C NMR spectra o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2010.05.022

    authors: Srivastava N,Akhila A

    更新日期:2010-08-01 00:00:00

  • Bio-active maneonenes and isomaneonene from the red alga Laurencia obtusa.

    abstract::Three previously undescribed compounds, maneonenes and isomaneonene derivatives; in addition to five known compounds, two cuparene, one chamigrene, and two cis-maneonenes were isolated from the Red Sea red alga Laurencia obtusa. The chemical structures of all unknown metabolites were characterized employing spectrosco...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.08.001

    authors: Bawakid NO,Alarif WM,Ismail AI,El-Hefnawy ME,Al-Footy KO,Al-Lihaibi SS

    更新日期:2017-11-01 00:00:00

  • Neolignan and flavonoid glycosides in Juniperus communis var. depressa.

    abstract::Two neolignan glycosides (junipercomnosides A and B) were isolated from aerial parts of Juniperus communis var. depressa along with two known neolignan glycosides and seven flavonoid glycosides. The structures of the isolated compounds were determined by spectral analysis, in particular by 2D-NMR analysis. The signifi...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2003.10.025

    authors: Nakanishi T,Iida N,Inatomi Y,Murata H,Inada A,Murata J,Lang FA,Iinuma M,Tanaka T

    更新日期:2004-01-01 00:00:00

  • Effects of exogenous auxin and ethylene on the Arabidopsis root proteome.

    abstract::The phytohormones, auxin and ethylene, together control a wide range of physiological and developmental processes in plants. The lack of knowledge regarding how the underlying signaling processes are reflected at the protein level represents a major gap in understanding phytohormone signaling, including that mediated ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2012.08.007

    authors: Slade WO,Ray WK,Williams PM,Winkel BS,Helm RF

    更新日期:2012-12-01 00:00:00

  • Salvia verticillata: Linking glandular trichomes, volatiles and pollinators.

    abstract::Plants have developed a plethora of signals to interact with other organisms, finally building up a sophisticate language for communication. In this context, we investigated Salvia verticillata L. (Lamiaceae), with the primary goal to link secondary metabolites and actual biotic relationships. We specifically analysed...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.07.016

    authors: Giuliani C,Ascrizzi R,Lupi D,Tassera G,Santagostini L,Giovanetti M,Flamini G,Fico G

    更新日期:2018-11-01 00:00:00

  • The structures of antioxidant and cytotoxic agents from natural source: anthraquinones and tannins from roots of Rumex patientia.

    abstract::A new anthraquinone glycoside, emodin-6-O-beta-D-glucopyranoside, and a new simple halogenated flavan-3-ol, 6-chlorocatechin, have been isolated from the roots of Rumex patientia L. together with seven known phenolic compounds. Their structures were elucidated on the basis of spectroscopic methods. Cytotoxic effects a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00337-5

    authors: Demirezer LO,Kuruüzüm-Uz A,Bergere I,Schiewe HJ,Zeeck A

    更新日期:2001-12-01 00:00:00

  • Hemicellulosic polysaccharides from bamboo shoot cell-walls.

    abstract::Cell-wall polysaccharides of bamboo shoots were extracted with chelating reagent (CDTA, trans-1,2-cyclohexanediamine-N,N,N',N'-tetraacetic acid), Na(2)CO(3) and KOH solutions. Glycosyl composition and glycosyl linkage analyses showed that the hemicellulose was composed of arabinoxylan, (1-->3, 1-->4)-beta-D-glucan, xy...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(98)00237-4

    authors: Edashige Y,Ishii T

    更新日期:1998-11-20 00:00:00

  • Phytochemical genomics of the Madagascar periwinkle: Unravelling the last twists of the alkaloid engine.

    abstract::The Madagascar periwinkle produces a large palette of Monoterpenoid Indole Alkaloids (MIAs), a class of complex alkaloids including some of the most valuable plant natural products with precious therapeutical values. Evolutionary pressure on one of the hotspots of biodiversity has obviously turned this endemic Malagas...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2014.07.023

    authors: Dugé de Bernonville T,Clastre M,Besseau S,Oudin A,Burlat V,Glévarec G,Lanoue A,Papon N,Giglioli-Guivarc'h N,St-Pierre B,Courdavault V

    更新日期:2015-05-01 00:00:00

  • Mulinane-type diterpenoids from Azorella compacta display antiplasmodial activity.

    abstract::Two mulinane-type diterpenoids were isolated from Azorella compacta; namely 20-hydroxymulin-11,13-dienyl acetate and 13,14-dihydroxymulin-11-en-20-oic acid. The structures were elucidated by analysis of their spectroscopic data. These compounds, as well as three previously isolated diterpenes, were evaluated as potent...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.06.011

    authors: Loyola LA,Bórquez J,Morales G,San-Martín A,Darias J,Flores N,Giménez A

    更新日期:2004-07-01 00:00:00

  • PTP1B inhibitory and cytotoxic C-24 epimers of Δ28-24-hydroxy stigmastane-type steroids from the brown alga Dictyopteris undulata Holmes.

    abstract::Ten stigmastane-type steroids bearing unusual Δ28-24-hydroxy side chains, dictyopterisins A-J, including three pairs of C-24 epimers, dictyopterisins B/C, F/G, and I/J, were isolated from the brown alga Dictyopteris undulata Holmes, together with two previously reported analogues, (24S)- and (24R)-saringosterol. Their...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2017.11.013

    authors: Feng MT,Wang T,Liu AH,Li J,Yao LG,Wang B,Guo YW,Mao SC

    更新日期:2018-02-01 00:00:00