Chemotaxonomy of Portuguese Ulex: quinolizidine alkaloids as taxonomical markers.

Abstract:

:Six species of Portuguese Ulex L. in a total of nineteen populations were studied by GC-EIMS as to their content in quinolizidine alkaloids. Sparteine, beta-isosparteine, jussiaeiine A, N-methylcytisine, cytisine, 5,6-dehydrolupanine, rhombifoline, lupanine, jussiaeiine B, N-formylcytisine, N-acetylcytisine, anagyrine, jussiaeiine C, jussiaeiine D, pohakuline, baptifoline, and epibaptifoline were detected. Analysis of the chromatograms showed that the chemical profile of all species was mainly composed of N-methylcytisine, cytisine, anagyrine, and jussiaeiines A, B, C and D. Therefore a quantification study of these alkaloids in all the populations studied was done by GC. These data were then submitted to cluster analysis and principal component analysis, which allowed the definition of five chemotypes and the recognition of hybrids. N-methylcytisine, cytisine, and jussiaeiines A, C and D are recognized as markers of this genus in Portugal.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Máximo P,Lourenço A,Tei A,Wink M

doi

10.1016/j.phytochem.2006.05.037

subject

Has Abstract

pub_date

2006-09-01 00:00:00

pages

1943-9

issue

17

eissn

0031-9422

issn

1873-3700

pii

S0031-9422(06)00312-8

journal_volume

67

pub_type

杂志文章
  • Actinidin, a protease from kiwifruit, induces changes in morphology and adhesion of T84 intestinal epithelial cells.

    abstract::Actinidin belongs to the papain-like family of cysteine proteases and is a major kiwifruit allergen. In this study, the effect of actinidin on cellular morphology and adhesion of T84 intestinal cells was investigated. Both rounding and detachment of T84 cells were observed upon actinidin treatment. The morphological c...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2011.12.014

    authors: Čavić M,Grozdanović M,Bajić A,Srdić-Rajić T,Anđjus PR,Gavrović-Jankulović M

    更新日期:2012-05-01 00:00:00

  • 14-Decarboxyquinovic and quinovic acid glycosides from Zygophyllum album.

    abstract::Further investigation of the leaves and stems of Zygophyllum album afforded four triterpene glycosides which were characterized as 14-decarboxyquinovic acid-3 beta-O-beta-D-quinovopyranosyl (1-->4)-quinovopyranoside, quinovic acid 28-O-beta-D-glucopyranosyl (2-->1)beta-D-glucopyranosyl ester, quinovic acid 27-O-beta-D...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(93)85470-c

    authors: Hassanean HA,el-Hamouly MM,el-Moghazy SA,Bishay DW

    更新日期:1993-06-01 00:00:00

  • Plant metabolomics: large-scale phytochemistry in the functional genomics era.

    abstract::Metabolomics or the large-scale phytochemical analysis of plants is reviewed in relation to functional genomics and systems biology. A historical account of the introduction and evolution of metabolite profiling into today's modern comprehensive metabolomics approach is provided. Many of the technologies used in metab...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/s0031-9422(02)00708-2

    authors: Sumner LW,Mendes P,Dixon RA

    更新日期:2003-03-01 00:00:00

  • Acylated flavonol glycosides from leaves of Planchonia grandis.

    abstract::Three acylated flavonol glycosides have been identified from leaves of Planchonia grandis Ridley. They possess kaempferol as aglycone and two triglycosidic chains substituting hydroxyl groups at the 3- and 7-positions. The first glycosidic unit of each chain is esterified by a cis or trans p-coumaric acid. Structural ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(03)00215-2

    authors: Crublet ML,Long C,Sévenet T,Hadi HA,Lavaud C

    更新日期:2003-09-01 00:00:00

  • Dietary phytoestrogens and health.

    abstract::The interest in the potential health effects of dietary phytoestrogens has increased with the findings that hormone replacement therapy is not as safe or effective as previously thought. This review summarizes the dietary sources of the phytoestrogens; isoflavonoids, stilbenes, coumestans and lignans. It also examines...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2004.03.005

    authors: Cornwell T,Cohick W,Raskin I

    更新日期:2004-04-01 00:00:00

  • Flavanone glycosides from Alhagi pseudalhagi.

    abstract::Two new flavanone glycosides, alhagitin and alhagidin, have been isolated from the whole plant of Alhagi pseudalhagi and their structures established respectively as naringenin 5-methyl ether 4'-glucoside and hesperitin 7-galactosyl(1-->2)[rhamnosyl(1-->6)]glucoside by chemical and spectroscopic methods. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00010-2

    authors: Singh VP,Yadav B,Pandey VB

    更新日期:1999-06-01 00:00:00

  • Malate. Jack of all trades or master of a few?

    abstract::The dicarboxylic acid malate has long been thought to play important roles in plant physiology. In addition to being a major photosynthate in C4 and CAM plants and an intermediate of the tricarboxylic acid cycle it has been proposed to play essential roles in pH regulation and important roles in pathogen response, as ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2009.04.023

    authors: Fernie AR,Martinoia E

    更新日期:2009-05-01 00:00:00

  • Anti-inflammatory triterpene saponins of Pithecellobium dulce: characterization of an echinocystic acid bisdesmoside.

    abstract::A new bisdesmodic triterpenoid saponin, dulcin was isolated from the seeds of Pithecellobium dulce and was identified as 3-O-[beta-D-glucopyranosyl (1-->2)-alpha-L-arabinopyranosyl]- 28-O-[beta-D-xylopyranosyl (1-->6)-beta-D-glucopyranosyl]-echinocystic acid. The known oleanolic acid saponin PE, oleanolic acid 3-O-bet...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)90425-4

    authors: Sahu NP,Mahato SB

    更新日期:1994-11-01 00:00:00

  • Diterpenoid glucosides from Salvia greggii.

    abstract::The structure of four diterpenoid glucosides, designated as salvigresides A-D (1-4), isolated from the aerial parts of Salvia greggii, have been confirmed by spectroscopic and chemical investigation. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.08.012

    authors: Kawahara N,Tamura T,Inoue M,Hosoe T,Kawai K,Sekita S,Satake M,Goda Y

    更新日期:2004-09-01 00:00:00

  • Sesquiterpenoids and iridoid glycosides from Valeriana fauriei.

    abstract::A new guaiane sesquiterpenoid glycoside together with known sesquiterpenoids and iridoid glycosides have been isolated from the rhizomes and roots of Valeriana fauriei. The 13C NMR assignments of the isolated compounds are presented. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(92)83718-e

    authors: Nishiya K,Kimura T,Takeya K,Itokawa H

    更新日期:1992-10-01 00:00:00

  • Photo-induced synthesis of tomatidenol-based glycoalkaloids in Solanum phureja tubers.

    abstract::The effect of light exposure on the steroidal glycoalkaloid content of Solanum phureja tubers has been investigated and compared with that in domesticated potato (Solanum tuberosum) tubers. The results indicated that the increase in the concentration of solanidine-based glycoalkaloids, alpha-solanine and alpha-chaconi...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00023-6

    authors: Griffiths DW,Bain H,Deighton N,Robertson GW,Finlay M,Dale B

    更新日期:2000-04-01 00:00:00

  • Dichapetalins from Dichapetalum species and their cytotoxic properties.

    abstract::Six dichapetalins named dichapetalins N-S were isolated from Dichapetalum mombuttense, Dichapetalum zenkeri and Dichapetalum leucosia. They were accompanied in the same plants by the known dichapetalins A, B, C, I, L and M. The structures of the compounds were elucidated by 1D and 2D NMR experiments and mass spectrome...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2013.03.023

    authors: Long C,Aussagues Y,Molinier N,Marcourt L,Vendier L,Samson A,Poughon V,Chalo Mutiso PB,Ausseil F,Sautel F,Arimondo PB,Massiot G

    更新日期:2013-10-01 00:00:00

  • (+/-)-Dievodialetins A-G: Seven pairs of enantiomeric coumarin dimers with anti-acetylcholinesterase activity from the roots of Evodia lepta Merr.

    abstract::Seven pairs of undescribed enantiomeric bis-coumarins, (±)-dievodialetins A-G, were separated from the roots of Evodia lepta Merr. Two coumarin nuclei were linked via a 1,4-dimethyl4-vinylcyclohexene moiety in (±)-dievodialetins C-G. The structures of the undescribed compounds, including their absolute configurations ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2020.112597

    authors: Huang GY,Cui H,Lu XY,Zhang LD,Ding XY,Wu JJ,Duan LX,Zhang SJ,Liu Z,Zhang RR

    更新日期:2021-02-01 00:00:00

  • Identification of galloylated propelargonidins and procyanidins in buckwheat grain and quantification of rutin and flavanols from homostylous hybrids originating from F. esculentumxF. homotropicum.

    abstract::The flavonoid rich grain of buckwheat (Fagopyrum esculentum Moench, Fam. Polygonaceae) is of high nutritional value. With the aim to improve its agronomic productivity, cultivars were crossed with the wild species F. homotropicum which, however, differs in its flavonoid content. The intention of this work was to deter...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2008.01.001

    authors: Olschläger C,Regos I,Zeller FJ,Treutter D

    更新日期:2008-04-01 00:00:00

  • Polyoxygenated cyclohexene derivatives from Ellipeiopsis cherrevensis.

    abstract::Aerial parts of Ellipeiopsis cherrevensis contained the polyoxygenated cyclohexenes zeylenol, ferrudiol and three analogs, ellipeiopsols A, B and C. The C-1 stereochemistry of ferrudiol has been revised. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00465-4

    authors: Kijjoa A,Bessa J,Pinto MM,Anatachoke C,Silva AM,Eaton G,Herz W

    更新日期:2002-03-01 00:00:00

  • Phytotoxic naphthopyranone derivatives from the coprophilous fungus Guanomyces polythrix.

    abstract::Reinvestigation of the fermentation broth and mycelium of the coprophilous fungus Guanomyces polythrix, grown in static conditions, led to the isolation of several phytotoxic compounds, including two new naphthopyranone derivatives, namely (2S, 3R)-5-hydroxy-6,8-dimethoxy-2,3-dimethyl-2,3-dihydro-4H-naphtho[2,3-b]-pyr...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00278-3

    authors: Macías M,Gamboa A,Ulloa M,Toscano RA,Mata R

    更新日期:2001-11-01 00:00:00

  • Dermatolactone, a cytotoxic fungal sesquiterpene with a novel skeleton.

    abstract::The nematicidal 5-pentyl-2-furaldehyde and the cytotoxic sesquiterpene dermatolactone were isolated from the extracts of an Ascomycete belonging to the Dermateaceae. The furan has previously been reported from the Basidiomycete Irpex lacteus, while dermatolactone is a new compound the structure of which was determined...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(96)00326-3

    authors: Mayer A,Köpke B,Anke H,Sterner O

    更新日期:1996-09-01 00:00:00

  • Identification of fermented tea (Camellia sinensis) polyphenols and their inhibitory activities against amyloid-beta aggregation.

    abstract::Thirty-three phenolic compounds were identified from the extract of fermented tea (Camellia sinensis L.), including three undescribed flavonoids, namely quamoreokchaside I-II and kamoreokchaside I, along with thirty known compounds. All isolates were tested to evaluate their inhibitory effects against amyloid-beta (Aβ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.12.013

    authors: Rho T,Choi MS,Jung M,Kil HW,Hong YD,Yoon KD

    更新日期:2019-04-01 00:00:00

  • Characterisation of triterpenes and new phenolic lipids in Cameroonian propolis.

    abstract::Chemical investigation of a sample of propolis originating from North-Western Cameroon led to the isolation of thirteen alk(en)ylphenols (1-13) (inseparable mixture) along with α-amyrin (14), β-amyrin (15), lupeol (16), cycloartenol (17), mangiferonic acid (18), ambonic acid (19), mangiferolic acid (20), ambolic acid ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.07.016

    authors: Kardar MN,Zhang T,Coxon GD,Watson DG,Fearnley J,Seidel V

    更新日期:2014-10-01 00:00:00

  • Antibacterial activity of pure flavonoids isolated from mosses.

    abstract::Seven pure flavonoids were isolated and identified from five moss species. The flavonoids were the flavones apigenin, apigenin-7-O-triglycoside, lucenin-2, luteolin-7-O-neohesperidoside, saponarine and vitexin; and the biflavonoid bartramiaflavone. Some of these flavonoids were shown to have pronounced antibacterial e...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00286-1

    authors: Basile A,Giordano S,López-Sáez JA,Cobianchi RC

    更新日期:1999-12-01 00:00:00

  • The bio-transformation of ent-19-hydroxykaur-16-en-15-one by Cephalosporium aphidicola.

    abstract::ent-19-Hydroxykaur-16-en-15-one is transformed to ent-3 beta,16 beta,19-trihydroxykauran-15-one by Cephalosporium aphidicola. The structure of this metabolite was established by X-ray crystallography. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(94)85065-8

    authors: Boaventura MA,Hanson JR,Hitchcock PB,Takahashi JA

    更新日期:1994-09-01 00:00:00

  • Oleanane-type triterpene oligoglycosides with pancreatic lipase inhibitory activity from the pericarps of Sapindus rarak.

    abstract::The methanolic extract from the pericarps of Sapindus rarak DC. was found to show pancreatic lipase inhibitory activity (IC50=ca. 614 microg/mL). From the extract, oleanane-type triterpene oligoglycosides, rarasaponins I-III (1-3), and raraoside A (4), were isolated together with 13 known saponins and four known sesqu...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2009.06.015

    authors: Morikawa T,Xie Y,Asao Y,Okamoto M,Yamashita C,Muraoka O,Matsuda H,Pongpiriyadacha Y,Yuan D,Yoshikawa M

    更新日期:2009-06-01 00:00:00

  • Indole alkaloids from the leaves of Philippine Alstonia scholaris.

    abstract::The first seco-uleine alkaloids, manilamine (1) (18-hydroxy-19,20-dehydro-7,21-seco-uleine) and N4-methyl angustilobine B (2), were isolated from the (pH 5) alkaloid extract of Philippine Alstonia scholaris leaves together with the known indole alkaloids 19,20-(E)-vallesamine (3), angustilobine B N4-oxide (4), 20(S)-t...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2005.02.018

    authors: Macabeo AP,Krohn K,Gehle D,Read RW,Brophy JJ,Cordell GA,Franzblau SG,Aguinaldo AM

    更新日期:2005-05-01 00:00:00

  • Indole alkaloids from Gelsemium elegans.

    abstract::Five previously undescribed monoterpenoid indole alkaloids were isolated from the roots of Gelsemium elegans. Their structures with absolute configurations were elucidated by HRESIMS, X-ray diffraction, ECD spectra, and molecular modeling. 19,20-Epoxyhumantenine is a humantenine-type alkaloid with an epoxypropyl group...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2019.03.016

    authors: Sun MX,Cui Y,Li Y,Meng WQ,Xu QQ,Zhao J,Lu JC,Xiao K

    更新日期:2019-06-01 00:00:00

  • Three isoflavones from Derris scandens (Roxb.) Benth and their cancer chemopreventive activity and in vitro antiproliferative effects.

    abstract::Three undescribed isoflavones, derriscandenon A, B, and C, together with seven known isoflavones were isolated and structurally characterized during a study of the chemical constituents in the leaves of Derris scandens (Roxb.) Benth (Leguminosae, Fabaceae) collected in Bangladesh. The inhibitory activity of the compou...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2020.112376

    authors: Ito C,Matsui T,Miyabe K,Hasan CM,Rashid MA,Tokuda H,Itoigawa M

    更新日期:2020-07-01 00:00:00

  • Iodus 40, salicylic acid, heptanoyl salicylic acid and trehalose exhibit different efficacies and defence targets during a wheat/powdery mildew interaction.

    abstract::Prophylactic efficacies of Iodus 40 and salicylic acid (SA) against wheat powdery mildew caused by Blumeria graminis f. sp. tritici have been shown and compared with those of heptanoyl salicylic acid (HSA) and trehalose. Plantlets treated once exhibited 55%, 50%, 95%, and 38% protection levels, respectively. Two spray...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2007.02.011

    authors: Renard-Merlier D,Randoux B,Nowak E,Farcy F,Durand R,Reignault P

    更新日期:2007-04-01 00:00:00

  • Phenylpropanoid glucosides from Chrozophora obliqua.

    abstract::From the aerial parts of Chrozophora obliqua, two phenylpropanoid glucosides: 4-O-methyl guaiacylglycerol 9-O-beta-glucopyranoside (1) and 4-O-methyl guaiacylglycerol 8-O-beta-glucopyranoside (2) together with syringin, benzyl alcohol glucoside, isorhamnetin-3-O-beta-glucopyranoside-7-O-alpha-rhamnopyranoside and quer...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00262-x

    authors: Mohamed KM

    更新日期:2001-10-01 00:00:00

  • The biotransformation of the diterpene 2beta-hydroxy-ent-13-epi-manoyl oxide by Gibberella fujikuroi.

    abstract::Incubation of the diterpene 2beta-hydroxy-ent-13-epi-manoyl oxide with Gibberella fujikuroi afforded in good yield 2beta,6beta-dihydroxy-ent-13-epi-manoyl oxide, 2beta,12beta-dihydroxy-ent-13-epi-manoyl oxide and 2beta,20-dihydroxy-ent-13-epi-manoyl oxide, confirming that although ent-13-epi-manoyl oxide is a final me...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00436-3

    authors: Fraga BM,González P,Hernández MG,Suárez S

    更新日期:2003-01-01 00:00:00

  • The blue anthocyanin pigments from the blue flowers of Heliophila coronopifolia L. (Brassicaceae).

    abstract::Six acylated delphinidin glycosides (pigments 1-6) and one acylated kaempferol glycoside (pigment 9) were isolated from the blue flowers of cape stock (Heliophila coronopifolia) in Brassicaceae along with two known acylated cyanidin glycosides (pigments 7 and 8). Pigments 1-8, based on 3-sambubioside-5-glucosides of d...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2011.07.020

    authors: Saito N,Tatsuzawa F,Toki K,Shinoda K,Shigihara A,Honda T

    更新日期:2011-12-01 00:00:00

  • Characterization of bispecific caffeic acid/5-hydroxyferulic acid O-methyltransferase from aspen.

    abstract::Bispecific O-methyltransferase (OMT, EC 2.1.1.68) which catalyses the meta-specific methylation of caffeic acid and 5-hydroxyferulic acid was purified to homogeneity from the developing secondary xylem of aspen (Populus tremuloides). The enzyme was purified by conventional techniques and affinity chromatography on S-a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(92)83093-e

    authors: Bugos RC,Chiang VL,Campbell WH

    更新日期:1992-05-01 00:00:00