Determination of trace elements in biological materials by inductively coupled plasma spectroscopy with novel chelating resins.

Abstract:

:Although substantial progress has been achieved in inductovely coupled plasma (ICP) spectroscopy, placing it among the principal spectroscopic tools in analytical chemistry research and applications laboratories, some limitations exist especially for the analysis of ultratrace concentration levels in biological materials. The application of chemical and instrumental techniques to increase the concentration levels of analytes is practical, but complicated by the requirements of maintaining the multielement nature of ICP spectroscopy. Two novel chelating resins [poly(dithiocarbamate) and poly(acrylamidoxime)] have been synthesized and applied with ICP spectrometry to enhance the practical sensitivity for ultratrace concentration determinations in biological and other materials. The determination of a number of trace elements in bone, dialysis solutions, serum, and urine is improved using the resin ICP approach. In addition, speciation of inorganic forms of As, Cr, Se, and Te is possible with the poly(dithiocarbamate) resin, and determination of the chemical forms of these elements in urine was performed.

journal_name

Biol Trace Elem Res

authors

Barnes RM

doi

10.1007/BF02918324

subject

Has Abstract

pub_date

1984-02-01 00:00:00

pages

93-103

issue

1

eissn

0163-4984

issn

1559-0720

journal_volume

6

pub_type

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