Steroidal glycosides from Tribulus terrestris.

Abstract:

:In addition to hecogenin 3-O-beta-D-glucopyranosyl(1--> 4)-beta-D-galactopyranoside, two new steroidal saponins were isolated from the aerial parts of Tribulus terrestris L. On the basis of chemical and spectroscopic evidence, especially 2D NMR spectroscopic techniques, the structures of the new saponins were established as 26-O-beta-D-glucopyranosyl-3-O-[-beta-D-xylopyranosyl(1--> 3)--beta-D-galactopyranosyl(1-->2)--beta-D-glucopyranosyl (1--> 4)-beta-D-glucopyranosyl]-5 alpha-furost-20(22)-en-12-one-3 beta,26-diol and 26-O-beta-D-glucopyranosyl-3-O-[{beta-D-xylopyranosyl (1-->3)--beta-D-galactopyranosyl(1-->2)--beta-D-glucopyranosyl(1 -->4)-beta-D-glucopyranosyl]-5 alpha-furostan-12-one-3 beta,22,26-triol.

journal_name

Phytochemistry

journal_title

Phytochemistry

authors

Wu G,Jiang S,Jiang F,Zhu D,Wu H,Jiang S

doi

10.1016/0031-9422(96)00182-3

subject

Has Abstract

pub_date

1996-08-01 00:00:00

pages

1677-81

issue

6

eissn

0031-9422

issn

1873-3700

pii

0031-9422(96)00182-3

journal_volume

42

pub_type

杂志文章
  • Composition of the epicuticular waxes coating the adaxial side of Phyllostachys aurea leaves: Identification of very-long-chain primary amides.

    abstract::The present study presents comprehensive chemical analyses of cuticular wax mixtures of the bamboo Phyllostachys aurea. The epicuticular and intracuticular waxes were sampled selectively from the adaxial side of leaves on young and old plants and investigated by gas chromatography-mass spectrometry and flame ionizatio...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2016.06.005

    authors: Racovita RC,Jetter R

    更新日期:2016-10-01 00:00:00

  • A lower content of de-methylesterified homogalacturonan improves enzymatic cell separation and isolation of mesophyll protoplasts in Arabidopsis.

    abstract::Cell adhesion occurs primarily at the level of middle lamella which is mainly composed by pectin polysaccharides. These can be degraded by cell wall degrading enzymes (CWDEs) during developmental processes to allow a controlled separation of plant cells. Extensive cell wall degradation by CWDEs with consequent cell se...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.07.025

    authors: Lionetti V,Cervone F,De Lorenzo G

    更新日期:2015-04-01 00:00:00

  • Isolation and synthesis of chalcones with different degrees of saturation.

    abstract::Crotaoprostrin, a chalcone not yet known as a plant constituent, was isolated from the aerial parts of the Indian medicinal plant Crotalaria prostrata. The structures of the chalcone polyarvin and the partially hydrogenated naturally occurring derivatives crotaramin, crotaramosmin, and crotin were confirmed by chemica...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00475-2

    authors: Krohn K,Steingröver K,Srinivasa Rao M

    更新日期:2002-12-01 00:00:00

  • Metabolic fate of 3α,5-cycloandrostanes in the endogenous lactonization pathway of Aspergillus tamarii KITA.

    abstract::A series of 3α,5-cycloandrostane analogues with a range of functionality (6α and 6β alcohols and ketone) at carbon 6 were tested in the endogenous lactonization pathway in Aspergillus tamarii KITA. This metabolic route converts progesterone to testololactone in high yield through a four step enzymatic pathway. To date...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2015.09.003

    authors: Hunter AC,Patel S,Dedi C,Dodd HT,Bryce RA

    更新日期:2015-11-01 00:00:00

  • Tetraoxygenated xanthones from the fruits of Garcinia cowa.

    abstract::Tetraoxygenated xanthones, cowaxanthones A-E, together with 10 previously reported tetraoxygenated xanthones, were isolated from the crude hexane extract of the fruits of Garcinia cowa. Cowaxanthone B has previously been reported as a synthetic xanthone. Their structures were elucidated by analysis of spectroscopic da...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.02.027

    authors: Panthong K,Pongcharoen W,Phongpaichit S,Taylor WC

    更新日期:2006-05-01 00:00:00

  • WITHDRAWN: Phytochemical Society of North America.

    abstract::This article has been withdrawn at the request of the author(s) and/or editor. The Publisher apologizes for any inconvenience this may cause. The full Elsevier Policy on Article Withdrawal can be found at http://www.elsevier.com/locate/withdrawalpolicy. ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2012.03.001

    authors: McIntosh C

    更新日期:2012-03-16 00:00:00

  • Limonoids from the fruits of Melia toosendan and their NF-κB modulating activities.

    abstract::Eight ring C-seco and ring-intact limonoids, and 25 known limonoids were isolated from the fruits of Melia toosendan (Meliaceae). Their structures were elucidated on the basis of extensive spectroscopic evidence including HRMS, 1D and 2D NMR spectroscopic data. A total of 29 isolated limonoids was evaluated for NF-κB ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.08.009

    authors: Zhu GY,Bai LP,Liu L,Jiang ZH

    更新日期:2014-11-01 00:00:00

  • Triterpenoid saponins from Mimusops elengi.

    abstract::A novel minor triterpenoid saponin mimusin (3-O-[beta-D-glucopyranosyl- (1-->6)-beta-D-glucopyranosyl]-2 beta,3 beta,6 beta,23-tetrahydroxyolean- 12-en-28-oic acid 28-O-alpha-L-rhamnopyranosyl-(1-->3)-beta-D-xylopyranosyl-(1-->4)-alpha- L- rhamnopyranosyl-(1-->2)-alpha-L-arabinopyranoside was isolated from the seeds o...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(96)00659-0

    authors: Sahu NP,Koike K,Jia Z,Nikaido T

    更新日期:1997-03-01 00:00:00

  • Triterpenoid saponins from Impatiens siculifer.

    abstract::Triterpenoid saponins, impatienosides A-G, together with 12 known saponins, were isolated from the whole plants of Impatiens siculifer. Their structures were established on the basis of extensive 1D and 2D NMR and MS analyses coupled with chemical degradation. Cytotoxic activities of the isolated saponins were evaluat...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2009.03.022

    authors: Li W,Bi X,Wang K,Li D,Satou T,Koike K

    更新日期:2009-04-01 00:00:00

  • Vacuolar uptake of the phytoalexin medicarpin by the glutathione conjugate pump.

    abstract::We have studied the uptake of [3H]-medicarpin and its glutathione conjugate(s) into vacuolar membrane vesicles from etiolated hypocotyls of mung bean (Vigna radiata). Unconjugated medicarpin is taken up at a low rate in the presence or absence of MgATP. However, [3H]-medicarpin-glutathione conjugate(s), prepared by in...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(97)00031-9

    authors: Li ZS,Alfenito M,Rea PA,Walbot V,Dixon RA

    更新日期:1997-06-01 00:00:00

  • Involvement of calcium in ACC-oxidase activity from Cicer arietinum seed embryonic axes.

    abstract::Both in vivo and in vitro ACC-oxidase activities as well as ethylene production from embryonic axes of chickpea seeds were strongly inhibited by EGTA, a selective extracellular Ca2+ ion chelator, indicating that the influx of Ca2+ is important for enzymatic activity. EGTA inhibition was restored by exogenous Ca2+. Tre...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(98)00591-3

    authors: Gallardo M,Gómez-Jiménez MC,Matilla A

    更新日期:1999-02-01 00:00:00

  • Properties of a polynucleotide synthesized by strain 74A of Neurospora crassa.

    abstract::A polynucleotide (or a fragment of RNA) was purified to apparent homogeneity by HPLC from mycelium of the wild strain 74A of the mould Neurospora crassa, after growth on sucrose and in the presence of saturating amounts of inorganic phosphate (Pi) for 72 hr at 30 degrees. The M(r) was ca 20,000 as determined by HPLC a...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/0031-9422(95)00531-5

    authors: Carmona EC,Han SW,Palma MS,Rossi A

    更新日期:1996-02-01 00:00:00

  • Chromenes of polyketide origin from Peperomia villipetiola.

    abstract::An extract of leaves and stems of Peperomia villipetiola has been found to contain myristicin (3-methoxy-4,5-methylenedioxy-allylbenzene) and seven chromenes, whose structures are methyl 5-hydroxy-7-methyl-2,2-dimethyl-2H-1-chromene-6-carboxylate (1), methyl 5-methoxy-7-methyl-2,2-dimethyl-2H-1-chromene-8-carboxylate ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2005.01.003

    authors: Malquichagua Salazar KJ,Delgado Paredes GE,Lluncor LR,Young MC,Kato MJ

    更新日期:2005-03-01 00:00:00

  • α,β-Unsaturated monoterpene acid glucose esters: structural diversity, bioactivities and functional roles.

    abstract::The glycosylation of lipophilic small molecules produces many important plant secondary metabolites. The majority of these are O-glycosides with relatively fewer occurring as glucose esters of aromatic or aliphatic acids. In particular, monoterpene acid glucose esters have much lower structural diversity and distribut...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/j.phytochem.2011.08.026

    authors: Goodger JQ,Woodrow IE

    更新日期:2011-12-01 00:00:00

  • Biosynthesis of tetrahydroanthraquinones in fungi.

    abstract::The tetrahydroanthraquinones (1S,3S)-austrocortilutein (4) and (1S,3S)-austrocortirubin (7) are octaketides formed in the fruit bodies of the fungus Dermocybe splendida via the gentiobioside 2 of the dihydroanthracenone (S)-torosachrysone (1). ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00181-3

    authors: Elsworth C,Gill M,Saubern S

    更新日期:2000-09-01 00:00:00

  • Metabolomic analysis applied to chemosystematics and evolution of megadiverse Brazilian Vernonieae (Asteraceae).

    abstract::Vernonia sensu lato is the largest and most complex genus of the tribe Vernonieae (Asteraceae). The tribe is chemically characterized by the presence of sesquiterpene lactones and flavonoids. Over the years, several taxonomic classifications have been proposed for Vernonia s.l. and for the tribe; however, there has be...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2018.03.007

    authors: Gallon ME,Monge M,Casoti R,Da Costa FB,Semir J,Gobbo-Neto L

    更新日期:2018-06-01 00:00:00

  • Neogrifolin derivatives possessing anti-oxidative activity from the mushroom Albatrellus ovinus.

    abstract::Three neogrifolin derivatives, 3-hydroxyneogrifolin, 1-formylneogrifolin and 1-formyl-3-hydroxyneogrifolin along with grifolin and neogrifolin were isolated from the Japanese mushroom Albatrellus ovinus belonging to Scutigeraceae. Their structures were established by a combination of two-dimensional NMR spectroscopic ...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00050-x

    authors: Nukata M,Hashimoto T,Yamamoto I,Iwasaki N,Tanaka M,Asakawa Y

    更新日期:2002-04-01 00:00:00

  • Study of sesquiterpene lactones from Milleria quinqueflora on their anti-inflammatory activity using the transcription factor NF-kappa B as molecular target.

    abstract::In Central America aerial parts of the Asteraceae Milleria quinqueflora are used in traditional medicine as a remedy for skin infections. Reinvestigation of this plant afforded thirteen sesquiterpene lactones (Sls), three of them are new. All isolated Sls were studied for their anti-inflammatory activity using the tra...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(99)00510-5

    authors: Castro V,Rüngeler P,Murillo R,Hernandez E,Mora G,Pahl HL,Merfort I

    更新日期:2000-01-01 00:00:00

  • Variation of glucosinolate accumulation among different organs and developmental stages of Arabidopsis thaliana.

    abstract::The glucosinolate content of various organs of the model plant Arabidopsis thaliana (L.) Heynh., Columbia (Col-0) ecotype, was analyzed at different stages during its life cycle. Significant differences were noted among organs in both glucosinolate concentration and composition. Dormant and germinating seeds had the h...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00549-6

    authors: Brown PD,Tokuhisa JG,Reichelt M,Gershenzon J

    更新日期:2003-02-01 00:00:00

  • Chemotaxonomy of the Oleaceae: iridoids as taxonomic markers.

    abstract::The distribution and biosynthesis of iridoid glucosides in the Oleaceae is reviewed and five distinct biosynthetic pathways to iridoids have been identified in the family, deoxyloganic acid apparently being a common intermediate. Likewise, the distributions of caffeoyl phenylethanoid glycosides (CPGs), i.e. verbascosi...

    journal_title:Phytochemistry

    pub_type: 杂志文章,评审

    doi:10.1016/s0031-9422(02)00102-4

    authors: Jensen SR,Franzyk H,Wallander E

    更新日期:2002-06-01 00:00:00

  • Corynanthean, eburnan, secoleuconoxine, and pauciflorine alkaloids from Kopsia pauciflora.

    abstract::Eleven indole alkaloids, comprising four corynanthean, two eburnane, one aspidofractinine, one secoleuconoxine, one andranginine, and two pauciflorine type alkaloids were isolated from the stem-bark and leaf extracts of Kopsia pauciflora. Their structures were determined using NMR and MS analyses. The catharinensine t...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2014.09.014

    authors: Gan CY,Yoganathan K,Sim KS,Low YY,Lim SH,Kam TS

    更新日期:2014-12-01 00:00:00

  • Flavonoids, including an unusual flavonoid-Mg2+ salt, from roots of Cudrania cochinchinensis.

    abstract::Four flavonoids with 2',4'-di-oxygenated B-rings, cochinchinol A (1), cochinchinol B (2), (2R,3R)-4',7-dihydroxy-2',5-dimethoxydihydroflavonol (3), 4',7-dihydroxy-2',5-dimethoxyflavonol (4), along with 11 known compounds, were isolated from an ethanolic extract of the roots of Cudrania cochinchinensis. Their structure...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2005.09.015

    authors: Zhang P,Feng Z,Wang Y

    更新日期:2005-12-01 00:00:00

  • Essential oils from New Zealand manuka: triketone and other chemotypes of Leptospermum scoparium.

    abstract::The triketone chemotype of manuka, Leptospermum scoparium (Myrtaceae), is commercially important because of its antimicrobial activity. Oils from 36 individual plants on the East Cape of New Zealand all showed similar high triketone contents (>20% total triketones) with little seasonal variation. Analyses of oils from...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2004.03.019

    authors: Douglas MH,van Klink JW,Smallfield BM,Perry NB,Anderson RE,Johnstone P,Weavers RT

    更新日期:2004-05-01 00:00:00

  • A sesquiterpene drimane with antinociceptive activity from Drimys winteri bark.

    abstract::Along with three known drimanes, polygodial. 1-beta-(p-methoxycinnamoyl) polygodial and mukaadial, the sesquiterpene drimane named drimanial was isolated from the bark of Drimys winteri (Winteraceae). Its structure was elucidated based on spectroscopic evidence. Drimanial exhibited antinociceptive action against aceti...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(00)00515-x

    authors: Malheiros A,Filho VC,Schmitt CB,Santos ARS,Scheidt C,Calixto JB,Monache FD,Yunes RA

    更新日期:2001-05-01 00:00:00

  • Three isoflavones from Derris scandens (Roxb.) Benth and their cancer chemopreventive activity and in vitro antiproliferative effects.

    abstract::Three undescribed isoflavones, derriscandenon A, B, and C, together with seven known isoflavones were isolated and structurally characterized during a study of the chemical constituents in the leaves of Derris scandens (Roxb.) Benth (Leguminosae, Fabaceae) collected in Bangladesh. The inhibitory activity of the compou...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2020.112376

    authors: Ito C,Matsui T,Miyabe K,Hasan CM,Rashid MA,Tokuda H,Itoigawa M

    更新日期:2020-07-01 00:00:00

  • Identification and functional expression of a type 2 acyl-CoA:diacylglycerol acyltransferase (DGAT2) in developing castor bean seeds which has high homology to the major triglyceride biosynthetic enzyme of fungi and animals.

    abstract::Seed oil from castor bean (Ricinus communis) contains high amounts of hydroxy fatty acid rich triacylglycerols (TAGs) that can serve as raw material for production of bio-based products such as nylon, cosmetics, lubricants, foams, and surfactants. Diacylglycerol acyltransferase (DGAT) catalyses the terminal reaction i...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2006.09.020

    authors: Kroon JT,Wei W,Simon WJ,Slabas AR

    更新日期:2006-12-01 00:00:00

  • Phenylpropanoid glucosides from Chrozophora obliqua.

    abstract::From the aerial parts of Chrozophora obliqua, two phenylpropanoid glucosides: 4-O-methyl guaiacylglycerol 9-O-beta-glucopyranoside (1) and 4-O-methyl guaiacylglycerol 8-O-beta-glucopyranoside (2) together with syringin, benzyl alcohol glucoside, isorhamnetin-3-O-beta-glucopyranoside-7-O-alpha-rhamnopyranoside and quer...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(01)00262-x

    authors: Mohamed KM

    更新日期:2001-10-01 00:00:00

  • Flavanone 3-hydroxylase expression in Citrus paradisi and Petunia hybrida seedlings.

    abstract::Petunia hybrida and Citrus paradisi have significantly different flavonoid accumulation patterns. Petunia sp. tend to accumulate flavonol glycosides and anthocyanins while Citrus paradisi is known for its accumulation of flavanone diglycosides. One possible point of regulation of flavanone metabolism is flavanone 3-hy...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(03)00341-8

    authors: Pelt JL,Downes WA,Schoborg RV,McIntosh CA

    更新日期:2003-09-01 00:00:00

  • Antiplasmodial and antimycobacterial cyclopeptide alkaloids from the root of Ziziphus mauritiana.

    abstract::Investigation of the MeOH extract obtained from the root of the Ziziphus mauritiana grown in Thailand resulted in the isolation of two 14- and 13-membered cyclic alkaloids, mauritine L (1) and mauritine M (2), and three known cyclopeptide alkaloids, nummularines H (3), B (4) and hemsine A (5). Their structures were el...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/j.phytochem.2011.03.003

    authors: Panseeta P,Lomchoey K,Prabpai S,Kongsaeree P,Suksamrarn A,Ruchirawat S,Suksamrarn S

    更新日期:2011-06-01 00:00:00

  • Taxol content in the bark of Himalayan Yew in relation to tree age and sex.

    abstract::Taxol content in the bark of Taxus baccata trees growing in a homogenous (uniform) environment at Jageshwar, District Almora in Central Himalaya has been quantified. The average taxol concentration in the bark of sampled trees was 0.0558+/-0.008% (of dry wt.) and was about 64% higher for male plants (averaged across t...

    journal_title:Phytochemistry

    pub_type: 杂志文章

    doi:10.1016/s0031-9422(02)00115-2

    authors: Nadeem M,Rikhari HC,Kumar A,Palni LM,Nandi SK

    更新日期:2002-07-01 00:00:00