Biosynthesis of tetrahydroanthraquinones in fungi.

abstract：:Eight sesquiterpenes, including four guaiane-types containing an interesting epoxy unit (1-4), a rare tricyclic carbon skeleton-type (5) and three eudesmane-types (6-8), along with five known compounds, were isolated from rhizomes of Atractylodes lancea. The structures and relative configurations of 1-8 were determine...

journal_title：Phytochemistry

authors： Wang HX,Liu CM,Liu Q,Gao K

更新日期：2008-07-01 00:00:00

abstract：:Two bromophenols, together with three known compounds, were isolated from the methanolic extract of the marine alga, Rhodomela confervoides. By means of MS and NMR spectroscopic analyses, they were identified as 3-bromo-4-[2,3-dibromo-4,5-dihydroxyphenyl] methyl-5-(hydroxymethyl) 1,2-benzenediol (1) and 3-bromo-4-[2,3...

journal_title：Phytochemistry

authors： Xu N,Fan X,Yan X,Li X,Niu R,Tseng CK

更新日期：2003-04-01 00:00:00

abstract：:Characteristic for cruciferous plants is the synthesis of a complex array of defence-related indolic compounds. In Arabidopsis, these include indol-3-ylmethyl glucosinolates (IMGs), as well as stress-inducible indole-3-carbaldehyde (ICHO)/indole-3-carboxylic acid (ICOOH) derivatives and camalexin. Key enzymes in the b...

journal_title：Phytochemistry

authors： Müller TM,Böttcher C,Glawischnig E

更新日期：2019-05-01 00:00:00

abstract：:A new bidesmosidic triterpenoidal saponin 3-O-[beta-D-glucopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->4)-alpha-L - arabinopyranosyl]-hederagenin-28-O-[alpha-L-rhamnopyranosyl- (1-->4)-beta-D- glucopyranosyl-(1-->6)-beta-D-glucopyranosyl] ester, was isolated from the roots of Symphytum officinale. The structure was a...

journal_title：Phytochemistry

authors： Mohammad FV,Noorwala M,Ahmad VU,Sener B

更新日期：1995-09-01 00:00:00

abstract：:Two unprecedented guaiane-type sesquiterpene glycosides (undulatumosides A and B) were isolated by bioassay-guided fractionation from the MeOH extract of Pittosporum undulatum fruits, along with six known compounds, including the guaiane isomers 5-guaien-11-ol and 4-guaien-11-ol. The structures of the compounds were e...

journal_title：Phytochemistry

authors： Mendes SA,Mansoor TA,Rodrigues A,Armas JB,Ferreira MJ

更新日期：2013-11-01 00:00:00

abstract：:Five novel polyphenols have been isolated from the air-dried herb of Cistus salvifolius; they were characterized as epigallocatechin-3-O-(4-hydroxybenzoate), epigallocatechin-(4 beta-->8)-epigallocatechin, epigallocatechin-3-O- gallate-(4 beta-->8)-epigallocatechin, epigallocatechin-(4 beta-->6)-epigallocatechin-3-O-g...

journal_title：Phytochemistry

authors： Danne A,Petereit F,Nahrstedt A

更新日期：1994-09-01 00:00:00

abstract：:While the myrosinase-glucosinolate system has been reviewed in recent years by a number of authors, little attention has been paid to the enzymic and non-enzymic degradation of glucosinolates. Non-enzymic degradation processes are particularly important in the processing of brassica vegetables with respect to both fla...

journal_title：Phytochemistry

authors： Bones AM,Rossiter JT

更新日期：2006-06-01 00:00:00

abstract：:Microbial transformation of psiadiarabin and its 6-desmethoxy analogue 5,3' dihydroxy-7,2',4'5'-tetramethoxyflavone by Cunninghamella elegans NRRL 1392 gave the 3'-glucoside conjugates of the two flavones. Structural elucidation of these two new metabolites was achieved using 1D and 2D NMR spectroscopy and CIMS. ...

journal_title：Phytochemistry

authors： Ibrahim AR,Galal AM,Mossa JS,el-Feraly FS

更新日期：1997-12-01 00:00:00

abstract：:Epoxide hydrolases (EH, EC 3.3.2.3) have been proposed to be key enzymes in the biosynthesis of polyether (PE) ladder compounds such as the brevetoxins which are produced by the dinoflagellate Karenia brevis. These enzymes have the potential to catalyze kinetically disfavored endo-tet cyclization reactions. Data minin...

journal_title：Phytochemistry

authors： Sun P,Leeson C,Zhi X,Leng F,Pierce RH,Henry MS,Rein KS

更新日期：2016-02-01 00:00:00

abstract：:The unusual chlorinated coumarinolignan, 5-chloropropacin, along with several other known compounds have been isolated from the roots of Mondia whitei. The structure of the chlorinated coumarinolignan was determined by NMR and mass spectroscopic analyses. ...

journal_title：Phytochemistry

authors： Patnam R,Kadali SS,Koumaglo KH,Roy R

更新日期：2005-03-01 00:00:00

abstract：:Two natural Diels-Alder type adducts, cathayanon A (1) and cathayanon B (2), resembling sanggenon C (4) and O (3), were isolated from the root bark of Morus cathayana. Their structures were elucidated on the basis of spectroscopic evidence. The structure of 1 was confirmed by the results of X-ray crystallographic anal...

journal_title：Phytochemistry

authors： Shen RC,Lin M

更新日期：2001-08-01 00:00:00

abstract：:Two aristololactams, aristololactam GI (1) and aristololactam GII (2), and three aporphines, fissistigamide A (3), fissistigamide B (4) and fissistigmine (5), together with nineteen known alkaloids, one flavone and one anthraquinone were isolated from the ethanol extracts of the stems of Fissistigma oldhamii (Annonace...

journal_title：Phytochemistry

authors： Ge YW,Zhu S,Shang MY,Zang XY,Wang X,Bai YJ,Li L,Komatsu K,Cai SQ

更新日期：2013-02-01 00:00:00

abstract：:Three-day-old soybean (Glycine max) seedlings were exposed to 0.4 M sorbitol solution for 4 h to induce amidinotransferase activity, with the corresponding enzyme being purified to homogeneity by chromatographic separation on DEAE-Sephacel, Sephacryl S-300 and L-arginine Sepharose 4B. The purified enzyme used L-argini...

journal_title：Phytochemistry

authors： Lee GT,Kim WJ,Cho YD

更新日期：2002-12-01 00:00:00

abstract：:Plant defensive serine proteinase inhibitors (PIs) are known to have negative impact on digestive physiology of herbivore insects and thus have a crucial role in plant protection. Here, we have assessed the efficacy and specificity of three previously characterized inhibitory repeat domain (IRD) variants from Capsicum...

journal_title：Phytochemistry

authors： Joshi RS,Gupta VS,Giri AP

更新日期：2014-05-01 00:00:00

abstract：:Soluble and microsomal glutathione S-transferase activities for five model xenobiotics (nitrobenzene derivatives), two pesticidal xenobiotics (atrazine and fluorodifen), and a natural substrate (cinnamic acid), were determined in 59 different plant species and four plant cell suspension cultures. These enzyme activiti...

journal_title：Phytochemistry

authors： Pflugmacher S,Schröder P,Sandermann H Jr

更新日期：2000-06-01 00:00:00

abstract：:Monoterpenoid indole alkaloids are a vast and structurally complex group of plant secondary compounds. In contrast to other groups of plant products which produce many glycosides, indole alkaloids rarely occur as glucosides. Plants of Rauvolfia serpentina accumulate ajmaline as a major alkaloid, whereas cell suspensio...

journal_title：Phytochemistry

authors： Warzecha H,Gerasimenko I,Kutchan TM,Stöckigt J

更新日期：2000-08-01 00:00:00

abstract：:From the mesocarp of Balanites aegyptiaca fruits, two pregnane glycosides were isolated. One is new and identified as pregn-5-ene-3 beta,16 beta,20(R)-triol 3-O-(2,6-di-O-alpha-L-rhamnopyranosyl)-beta-D-glucopyranoside (balagyptin), while the other is known and assigned as pregn-5-ene-3 beta,16 beta,20(R)-triol 3-O-be...

journal_title：Phytochemistry

authors： Kamel MS,Koskinen A

更新日期：1995-12-01 00:00:00

abstract：:The glucosinolate content of various organs of the model plant Arabidopsis thaliana (L.) Heynh., Columbia (Col-0) ecotype, was analyzed at different stages during its life cycle. Significant differences were noted among organs in both glucosinolate concentration and composition. Dormant and germinating seeds had the h...

journal_title：Phytochemistry

authors： Brown PD,Tokuhisa JG,Reichelt M,Gershenzon J

更新日期：2003-02-01 00:00:00

abstract：:In plant terpene biosynthesis, oxidation of the hydrocarbon backbone produced by terpene synthases is typically carried out by cytochrome P450 oxygenases (CYPs). The modifications introduced by CYPs include hydroxylations, sequential oxidations at one position and ring rearrangements and closures. These reactions sign...

journal_title：Phytochemistry

authors： Bathe U,Tissier A

更新日期：2019-05-01 00:00:00

abstract：:A new phenolic glycoside, asterbatanoside A [p-hydroxyacetophenone-4-O-beta-D-xylopyranosyl-(1-->6)-beta-D- glucopyranoside], and two new triterpenoid saponins, asterbatanoside B [2 alpha,3 beta,23-trihydroxyolean-12-en-28-oic acid-28-O-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranoside] and asterbatanoside C [3-O-b...

journal_title：Phytochemistry

authors： Shao Y,Li YL,Zhou BN

更新日期：1996-04-01 00:00:00

abstract：:Destruxins, secondary metabolites first reported in 1961, are cyclic hexadepsipeptides composed of an alpha-hydroxy acid and five amino acid residues. The name "destruxin" is derived from "destructor" from the species Oospora destructor, the entomopathogenic fungus from which these metabolites were first isolated. Ind...

journal_title：Phytochemistry

authors： Pedras MS,Irina Zaharia L,Ward DE

更新日期：2002-03-01 00:00:00

abstract：:[(3)H](+)-delta-Cadinene and its 8-hydroxy derivative, prepared from (1RS)-[1-(3)H]FPP by the action of one and two recombinant enzymes, respectively, were infiltrated into cotyledons of bacterial blight-resistant cotton plants as they biosynthesized sesquiterpene phytoalexins in response to infection by Xanthomonas c...

journal_title：Phytochemistry

authors： Wang YH,Davila-Huerta G,Essenberg M

更新日期：2003-09-01 00:00:00

abstract：:The compositions of the essential oils obtained from ten populations of Thymus caespititius grown on S. Jorge (Azores) were studied by GC and GC-MS. All the oils analysed were dominated by their monoterpene fraction (69-9%). The sesquiterpene fraction was rather small (4-17%) and consisted mainly of oxygen-containing ...

journal_title：Phytochemistry

authors： Pereira SI,Santos PA,Barroso JG,Figueiredo AC,Pedro LG,Salgueiro LR,Deans SG,Scheffer JJ

更新日期：2000-10-01 00:00:00

abstract：:A method for the global analysis of yeast intracellular metabolites, based on electrospray mass spectrometry (ES-MS), has been developed. This has involved the optimization of methods for quenching metabolism in Saccharomyces cerevisiae and extracting the metabolites for analysis by positive-ion electrospray mass spec...

journal_title：Phytochemistry

authors： Castrillo JI,Hayes A,Mohammed S,Gaskell SJ,Oliver SG

更新日期：2003-03-01 00:00:00

abstract：:Chemical investigation of a sample of propolis originating from North-Western Cameroon led to the isolation of thirteen alk(en)ylphenols (1-13) (inseparable mixture) along with α-amyrin (14), β-amyrin (15), lupeol (16), cycloartenol (17), mangiferonic acid (18), ambonic acid (19), mangiferolic acid (20), ambolic acid ...

journal_title：Phytochemistry

authors： Kardar MN,Zhang T,Coxon GD,Watson DG,Fearnley J,Seidel V

更新日期：2014-10-01 00:00:00

abstract：:A new anthraquinone glycoside, emodin-6-O-beta-D-glucopyranoside, and a new simple halogenated flavan-3-ol, 6-chlorocatechin, have been isolated from the roots of Rumex patientia L. together with seven known phenolic compounds. Their structures were elucidated on the basis of spectroscopic methods. Cytotoxic effects a...

journal_title：Phytochemistry

authors： Demirezer LO,Kuruüzüm-Uz A,Bergere I,Schiewe HJ,Zeeck A

更新日期：2001-12-01 00:00:00

abstract：:The chemical investigation of leaves of Bridelia glauca f. balansae afforded six megastigmane glucosides, named bridelionosides A-F, along with seven known megastigmane glucosides. Their structures were determined by a combination of spectroscopic analyses and by application of the modified Mosher's method. ...

journal_title：Phytochemistry

authors： Sueyoshi E,Liu H,Matsunami K,Otsuka H,Shinzato T,Aramoto M,Takeda Y

更新日期：2006-11-01 00:00:00

abstract：:The metabolism of (R,S)-N-methylanabasine and (R,S)-N-methylanatabine has been studied in a cell suspension culture of Nicotiana plumbaginifolia. Both substrates are effectively demethylated, anabasine or anatabine, respectively, accumulating in the medium. Similarly, there is strong stereoselectivity for the (R)-isom...

journal_title：Phytochemistry

authors： Bartholomeusz TA,Molinié R,Roscher A,Felpin FX,Gillet F,Lebreton J,Mesnard F,Robins RJ

更新日期：2005-08-01 00:00:00

abstract：:Six eudesmane-type sesquiterpene lactones, named chlorantholides A-F, were isolated from the ethanol extract of Chloranthus elatior (Chloranthaceae) together with 12 known compounds. Their structures were elucidated on the basis of extensive spectroscopic analysis, and their absolute configurations were studied by the...

journal_title：Phytochemistry

authors： Wang F,Zhou DS,Wei GZ,Ren FC,Liu JK

更新日期：2012-05-01 00:00:00

abstract：:From the ethanolic extract of the aerial parts of Centaurea scoparia four new sesquiterpene lactones, belonging to the guaiane class, were isolated and identified, together with a known germacranolide. The structures were elucidated by spectroscopic methods including one- and two-dimensional NMR studies. The relative ...

journal_title：Phytochemistry

authors： Youssef DT

更新日期：1998-11-20 00:00:00