Photoelectrochemical effects in the electrolyte-pigment-metal system. II. Metal-free phthalocyanine film action spectra of short-circuit photocurrents with increase of the film thickness.

Abstract:

:The electrolyte-pigment-metal system can be described as analogous to a photosensitive junction region. When the thickness of the pigment film is increased, the action spectra of the maximum short-circuit photo-current under continuous illumination differ from the absorption spectra both in direct illumination (pigment-electrolyte) and in back illumination (metal-pigment). One is led to believe that there exist two photoactive regions in the system for the production of the short-circuit photocurrent; these two active regions are associated respectively with each interface. When the metallic semitransparent electrode is made of aluminum the two interfaces have opposite sign contributions to the photocurrent; this allows the determination of conditions in which one can observe specifically the contribution of the pigment-electrolyte interface, that is the interactions between excited pigment molecules and the redox system in the electrolyte.

journal_name

J Bioenerg Biomembr

authors

Villar JG

doi

10.1007/BF00750283

subject

Has Abstract

pub_date

1976-08-01 00:00:00

pages

189-98

issue

4

eissn

0145-479X

issn

1573-6881

journal_volume

8

pub_type

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