A gas-plastic elastomer that quickly self-heals damage with the aid of CO2 gas.

Abstract:

:Self-healing materials are highly desirable because they allow products to maintain their performance. Typical stimuli used for self-healing are heat and light, despite being unsuitable for materials used in certain products as heat can damage other components, and light cannot reach materials located within a product or device. To address these issues, here we show a gas-plastic elastomer with an ionically crosslinked silicone network that quickly self-heals damage in the presence of CO2 gas at normal pressures and room temperature. While a strong elastomer generally exhibits slow self-healing properties, CO2 effectively softened ionic crosslinks in the proposed elastomer, and network rearrangement was promoted. Consequently, self-healing was dramatically accelerated by ~10-fold. Moreover, self-healing was achieved even at -20 °C in the presence of CO2 and the original mechanical strength was quickly re-established during the exchange of CO2 with air.

journal_name

Nat Commun

journal_title

Nature communications

authors

Miwa Y,Taira K,Kurachi J,Udagawa T,Kutsumizu S

doi

10.1038/s41467-019-09826-2

subject

Has Abstract

pub_date

2019-04-23 00:00:00

pages

1828

issue

1

issn

2041-1723

pii

10.1038/s41467-019-09826-2

journal_volume

10

pub_type

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