当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Tailoring manganese oxide with atomic precision to increase surface site availability for oxygen reduction catalysis.

Tailoring manganese oxide with atomic precision to increase surface site availability for oxygen reduction catalysis.

Abstract：

:Controlling the structure of catalysts at the atomic level provides an opportunity to establish detailed understanding of the catalytic form-to-function and realize new, non-equilibrium catalytic structures. Here, advanced thin-film deposition is used to control the atomic structure of La2/3Sr1/3MnO3, a well-known catalyst for the oxygen reduction reaction. The surface and sub-surface is customized, whereas the overall composition and d-electron configuration of the oxide is kept constant. Although the addition of SrMnO3 benefits the oxygen reduction reaction via electronic structure and conductivity improvements, SrMnO3 can react with ambient air to reduce the surface site availability. Placing SrMnO3 in the sub-surface underneath a LaMnO3 overlayer allows the catalyst to maintain the surface site availability while benefiting from improved electronic effects. The results show the promise of advanced thin-film deposition for realizing atomically precise catalysts, in which the surface and sub-surface structure and stoichiometry are tailored for functionality, over controlling only bulk compositions.

journal_name

Nat Commun

journal_title

Nature communications

authors

Eom CJ,Kuo DY,Adamo C,Moon EJ,May SJ,Crumlin EJ,Schlom DG,Suntivich J

doi

10.1038/s41467-018-06503-8

subject

Has Abstract

pub_date

2018-10-02 00:00:00

pages

4034

issue

1

issn

2041-1723

pii

10.1038/s41467-018-06503-8

journal_volume

9

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Author Correction: The rapid electrochemical activation of MoTe2 for the hydrogen evolution reaction.

    abstract：:An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title：Nature communications

    pub_type： 已发布勘误

    doi：10.1038/s41467-019-13337-5

    authors： McGlynn JC,Dankwort T,Kienle L,Bandeira NAG,Fraser JP,Gibson EK,Cascallana-Matías I,Kamarás K,Symes MD,Miras HN,Ganin AY

    更新日期：2019-11-20 00:00:00

  • High transconductance organic electrochemical transistors.

    abstract：:The development of transistors with high gain is essential for applications ranging from switching elements and drivers to transducers for chemical and biological sensing. Organic transistors have become well-established based on their distinct advantages, including ease of fabrication, synthetic freedom for chemical ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms3133

    authors： Khodagholy D,Rivnay J,Sessolo M,Gurfinkel M,Leleux P,Jimison LH,Stavrinidou E,Herve T,Sanaur S,Owens RM,Malliaras GG

    更新日期：2013-01-01 00:00:00

  • Unique transcriptome signatures and GM-CSF expression in lymphocytes from patients with spondyloarthritis.

    abstract：:Spondyloarthritis encompasses a group of common inflammatory diseases thought to be driven by IL-17A-secreting type-17 lymphocytes. Here we show increased numbers of GM-CSF-producing CD4 and CD8 lymphocytes in the blood and joints of patients with spondyloarthritis, and increased numbers of IL-17A+GM-CSF+ double-produ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-01771-2

    authors： Al-Mossawi MH,Chen L,Fang H,Ridley A,de Wit J,Yager N,Hammitzsch A,Pulyakhina I,Fairfax BP,Simone D,Yi Y,Bandyopadhyay S,Doig K,Gundle R,Kendrick B,Powrie F,Knight JC,Bowness P

    更新日期：2017-11-15 00:00:00

  • Precise allele-specific genome editing by spatiotemporal control of CRISPR-Cas9 via pronuclear transplantation.

    abstract：:Gene-targeted animal models that are generated by injecting Cas9 and sgRNAs into zygotes are often accompanied by undesired double-strand break (DSB)-induced byproducts and random biallelic targeting due to uncontrollable Cas9 targeting activity. Here, we establish a parental allele-specific gene-targeting (Past-CRISP...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-18391-y

    authors： Li Y,Weng Y,Bai D,Jia Y,Liu Y,Zhang Y,Kou X,Zhao Y,Ruan J,Chen J,Yin J,Wang H,Teng X,Wang Z,Liu W,Gao S

    更新日期：2020-09-14 00:00:00

  • A comprehensive examination of Nanopore native RNA sequencing for characterization of complex transcriptomes.

    abstract：:A platform for highly parallel direct sequencing of native RNA strands was recently described by Oxford Nanopore Technologies, but despite initial efforts it remains crucial to further investigate the technology for quantification of complex transcriptomes. Here we undertake native RNA sequencing of polyA + RNA from t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-11272-z

    authors： Soneson C,Yao Y,Bratus-Neuenschwander A,Patrignani A,Robinson MD,Hussain S

    更新日期：2019-07-31 00:00:00

  • Binary tree-inspired digital dendrimer.

    abstract：:Digital polymers with precisely ordered units acting as the coded 0- or 1-bit, are introduced as a promising option for molecular data storage. However, the pursuit of better performance in terms of high storage capacity and useful functions never stops. Herein, we propose a concept of an information-coded 2D digital ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09957-6

    authors： Huang Z,Shi Q,Guo J,Meng F,Zhang Y,Lu Y,Qian Z,Li X,Zhou N,Zhang Z,Zhu X

    更新日期：2019-04-23 00:00:00

  • Methane stimulates massive nitrogen loss from freshwater reservoirs in India.

    abstract：:The fate of the enormous amount of reactive nitrogen released to the environment by human activities in India is unknown. Here we show occurrence of seasonal stratification and generally low concentrations of dissolved inorganic combined nitrogen, and high molecular nitrogen (N2) to argon ratio, thus suggesting season...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03607-z

    authors： Naqvi SWA,Lam P,Narvenkar G,Sarkar A,Naik H,Pratihary A,Shenoy DM,Gauns M,Kurian S,Damare S,Duret M,Lavik G,Kuypers MMM

    更新日期：2018-03-28 00:00:00

  • Efficient and tuneable photoluminescent boehmite hybrid nanoplates lacking metal activator centres for single-phase white LEDs.

    abstract：:White light-emitting diodes (WLEDs) are candidates to revolutionize the lighting industry towards energy efficient and environmental friendly lighting and displays. The current challenges in WLEDs encompass high luminous efficiency, chromatic stability, high colour-rending index and price competitiveness. Recently, th...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms6702

    authors： Bai X,Caputo G,Hao Z,Freitas VT,Zhang J,Longo RL,Malta OL,Ferreira RA,Pinna N

    更新日期：2014-12-08 00:00:00

  • Discovery of cationic nonribosomal peptides as Gram-negative antibiotics through global genome mining.

    abstract：:The worldwide prevalence of infections caused by antibiotic-resistant Gram-negative bacteria poses a serious threat to public health due to the limited therapeutic alternatives. Cationic peptides represent a large family of antibiotics and have attracted interest due to their diverse chemical structures and potential ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-05781-6

    authors： Li YX,Zhong Z,Zhang WP,Qian PY

    更新日期：2018-08-16 00:00:00

  • Exploiting genetic variation to uncover rules of transcription factor binding and chromatin accessibility.

    abstract：:Single-nucleotide variants that underlie phenotypic variation can affect chromatin occupancy of transcription factors (TFs). To delineate determinants of in vivo TF binding and chromatin accessibility, we introduce an approach that compares ChIP-seq and DNase-seq data sets from genetically divergent murine erythroid c...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-03082-6

    authors： Behera V,Evans P,Face CJ,Hamagami N,Sankaranarayanan L,Keller CA,Giardine B,Tan K,Hardison RC,Shi J,Blobel GA

    更新日期：2018-02-22 00:00:00

  • Author Correction: Phylogenomic analysis sheds light on the evolutionary pathways towards acoustic communication in Orthoptera.

    abstract：:An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title：Nature communications

    pub_type： 已发布勘误

    doi：10.1038/s41467-020-19626-8

    authors： Song H,Béthoux O,Shin S,Donath A,Letsch H,Liu S,McKenna DD,Meng G,Misof B,Podsiadlowski L,Zhou X,Wipfler B,Simon S

    更新日期：2020-11-03 00:00:00

  • Electron energy-loss spectroscopy of branched gap plasmon resonators.

    abstract：:The miniaturization of integrated optical circuits below the diffraction limit for high-speed manipulation of information is one of the cornerstones in plasmonics research. By coupling to surface plasmons supported on nanostructured metallic surfaces, light can be confined to the nanoscale, enabling the potential inte...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms13790

    authors： Raza S,Esfandyarpour M,Koh AL,Mortensen NA,Brongersma ML,Bozhevolnyi SI

    更新日期：2016-12-16 00:00:00

  • Disruptive mutations in TANC2 define a neurodevelopmental syndrome associated with psychiatric disorders.

    abstract：:Postsynaptic density (PSD) proteins have been implicated in the pathophysiology of neurodevelopmental and psychiatric disorders. Here, we present detailed clinical and genetic data for 20 patients with likely gene-disrupting mutations in TANC2-whose protein product interacts with multiple PSD proteins. Pediatric patie...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12435-8

    authors： Guo H,Bettella E,Marcogliese PC,Zhao R,Andrews JC,Nowakowski TJ,Gillentine MA,Hoekzema K,Wang T,Wu H,Jangam S,Liu C,Ni H,Willemsen MH,van Bon BW,Rinne T,Stevens SJC,Kleefstra T,Brunner HG,Yntema HG,Long M,Zhao W

    更新日期：2019-10-15 00:00:00

  • Quantifying climate sensitivity and climate-driven change in North American amphibian communities.

    abstract：:Changing climate will impact species' ranges only when environmental variability directly impacts the demography of local populations. However, measurement of demographic responses to climate change has largely been limited to single species and locations. Here we show that amphibian communities are responsive to clim...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06157-6

    authors： Miller DAW,Grant EHC,Muths E,Amburgey SM,Adams MJ,Joseph MB,Waddle JH,Johnson PTJ,Ryan ME,Schmidt BR,Calhoun DL,Davis CL,Fisher RN,Green DM,Hossack BR,Rittenhouse TAG,Walls SC,Bailey LL,Cruickshank SS,Fellers GM,G

    更新日期：2018-09-25 00:00:00

  • Elevated levels of TRF2 induce telomeric ultrafine anaphase bridges and rapid telomere deletions.

    abstract：:The shelterin protein TRF2 is essential for chromosome-end protection. Depletion of TRF2 causes chromosome end-to-end fusions, initiating genomic instability that can be cancer promoting. Paradoxically, significant increased levels of TRF2 are observed in a subset of human cancers. Experimental overexpression of TRF2 ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms10132

    authors： Nera B,Huang HS,Lai T,Xu L

    更新日期：2015-12-07 00:00:00

  • Loss of IP3R-dependent Ca2+ signalling in thymocytes leads to aberrant development and acute lymphoblastic leukemia.

    abstract：:Calcium ions (Ca(2+)) function as universal second messengers in eukaryotic cells, including immune cells. Ca(2+) is crucial for peripheral T-lymphocyte activation and effector functions, and influences thymocyte selection and motility in the developing thymus. However, the role of Ca(2+) signalling in early T-lymphoc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5814

    authors： Ouyang K,Leandro Gomez-Amaro R,Stachura DL,Tang H,Peng X,Fang X,Traver D,Evans SM,Chen J

    更新日期：2014-09-12 00:00:00

  • Edge and confinement effects allow in situ measurement of size and thickness of liquid-exfoliated nanosheets.

    abstract：:Two-dimensional nanomaterials such as MoS2 are of great interest both because of their novel physical properties and their applications potential. Liquid exfoliation, an important production method, is limited by our inability to quickly and easily measure nanosheet size, thickness or concentration. Here we demonstrat...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5576

    authors： Backes C,Smith RJ,McEvoy N,Berner NC,McCloskey D,Nerl HC,O'Neill A,King PJ,Higgins T,Hanlon D,Scheuschner N,Maultzsch J,Houben L,Duesberg GS,Donegan JF,Nicolosi V,Coleman JN

    更新日期：2014-08-07 00:00:00

  • The Shine-Dalgarno sequence of riboswitch-regulated single mRNAs shows ligand-dependent accessibility bursts.

    abstract：:In response to intracellular signals in Gram--negative bacteria, translational riboswitches--commonly embedded in messenger RNAs (mRNAs)-regulate gene expression through inhibition of translation initiation. It is generally thought that this regulation originates from occlusion of the Shine-Dalgarno (SD) sequence upon...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms9976

    authors： Rinaldi AJ,Lund PE,Blanco MR,Walter NG

    更新日期：2016-01-19 00:00:00

  • Virus-borne mini-CRISPR arrays are involved in interviral conflicts.

    abstract：:CRISPR-Cas immunity is at the forefront of antivirus defense in bacteria and archaea and specifically targets viruses carrying protospacers matching the spacers catalogued in the CRISPR arrays. Here, we perform deep sequencing of the CRISPRome-all spacers contained in a microbiome-associated with hyperthermophilic arc...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-13205-2

    authors： Medvedeva S,Liu Y,Koonin EV,Severinov K,Prangishvili D,Krupovic M

    更新日期：2019-11-15 00:00:00

  • Microwave spectroscopic observation of distinct electron solid phases in wide quantum wells.

    abstract：:In high magnetic fields, two-dimensional electron systems can form a number of phases in which interelectron repulsion plays the central role, since the kinetic energy is frozen out by Landau quantization. These phases include the well-known liquids of the fractional quantum Hall effect, as well as solid phases with b...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5154

    authors： Hatke AT,Liu Y,Magill BA,Moon BH,Engel LW,Shayegan M,Pfeiffer LN,West KW,Baldwin KW

    更新日期：2014-06-20 00:00:00

  • Slab morphology and deformation beneath Izu-Bonin.

    abstract：:Seismic tomography provides unique constraints on the morphology, the deformation, and (indirectly) the rheology of subducting slabs. We use teleseismic double-difference P-wave tomography to image with unprecedented clarity the structural complexity of the Izu-Bonin slab. We resolve a tear in the slab in the mantle t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09279-7

    authors： Zhang H,Wang F,Myhill R,Guo H

    更新日期：2019-03-21 00:00:00

  • Temporal dynamics of gene expression and histone marks at the Arabidopsis shoot meristem during flowering.

    abstract：:Plants can produce organs throughout their entire life from pluripotent stem cells located at their growing tip, the shoot apical meristem (SAM). At the time of flowering, the SAM of Arabidopsis thaliana switches fate and starts producing flowers instead of leaves. Correct timing of flowering in part determines reprod...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15120

    authors： You Y,Sawikowska A,Neumann M,Posé D,Capovilla G,Langenecker T,Neher RA,Krajewski P,Schmid M

    更新日期：2017-05-17 00:00:00

  • Mutualism supports biodiversity when the direct competition is weak.

    abstract：:A key question of theoretical ecology is which properties of ecosystems favour their stability and help maintaining biodiversity. This question recently reconsidered mutualistic systems, generating intense controversy about the role of mutualistic interactions and their network architecture. Here we show analytically ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14326

    authors： Pascual-García A,Bastolla U

    更新日期：2017-02-24 00:00:00

  • Experimental generation of an eight-photon Greenberger-Horne-Zeilinger state.

    abstract：:Multi-partite entangled states are important for developing studies of quantum networking and quantum computation. To date, the largest number of particles that have been successfully manipulated is 14 trapped ions. Yet in quantum information science, photons have partic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms1556

    authors： Huang YF,Liu BH,Peng L,Li YH,Li L,Li CF,Guo GC

    更新日期：2011-11-22 00:00:00

  • Type-specific dendritic integration in mouse retinal ganglion cells.

    abstract：:Neural computation relies on the integration of synaptic inputs across a neuron's dendritic arbour. However, it is far from understood how different cell types tune this process to establish cell-type specific computations. Here, using two-photon imaging of dendritic Ca2+ signals, electrical recordings of somatic volt...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15867-9

    authors： Ran Y,Huang Z,Baden T,Schubert T,Baayen H,Berens P,Franke K,Euler T

    更新日期：2020-04-30 00:00:00

  • Electrical appliances moderate households' water demand response to heat.

    abstract：:Analysis of potentially interconnected residential water and energy demand is sparse. In a 1-in-10 random sample of Singapore households living in apartments, water use per capita declines over the socioeconomic distribution, whereas electricity use rises. Here I show that in this leading Asian city and tropical clima...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07833-3

    authors： Salvo A

    更新日期：2018-12-20 00:00:00

  • Dereplication of microbial metabolites through database search of mass spectra.

    abstract：:Natural products have traditionally been rich sources for drug discovery. In order to clear the road toward the discovery of unknown natural products, biologists need dereplication strategies that identify known ones. Here we report DEREPLICATOR+, an algorithm that improves on the previous approaches for identifying p...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06082-8

    authors： Mohimani H,Gurevich A,Shlemov A,Mikheenko A,Korobeynikov A,Cao L,Shcherbin E,Nothias LF,Dorrestein PC,Pevzner PA

    更新日期：2018-10-02 00:00:00

  • Implementing a strand of a scalable fault-tolerant quantum computing fabric.

    abstract：:With favourable error thresholds and requiring only nearest-neighbour interactions on a lattice, the surface code is an error-correcting code that has garnered considerable attention. At the heart of this code is the ability to perform a low-weight parity measurement of local code qubits. Here we demonstrate high-fide...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5015

    authors： Chow JM,Gambetta JM,Magesan E,Abraham DW,Cross AW,Johnson BR,Masluk NA,Ryan CA,Smolin JA,Srinivasan SJ,Steffen M

    更新日期：2014-06-24 00:00:00

  • Essential role of FBXL5-mediated cellular iron homeostasis in maintenance of hematopoietic stem cells.

    abstract：:Hematopoietic stem cells (HSCs) are maintained in a hypoxic niche to limit oxidative stress. Although iron elicits oxidative stress, the importance of iron homeostasis in HSCs has been unknown. Here we show that iron regulation by the F-box protein FBXL5 is required for HSC self-renewal. Conditional deletion of Fbxl5 ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms16114

    authors： Muto Y,Nishiyama M,Nita A,Moroishi T,Nakayama KI

    更新日期：2017-07-17 00:00:00

  • Allosteric cross-talk in chromatin can mediate drug-drug synergy.

    abstract：:Exploitation of drug-drug synergism and allostery could yield superior therapies by capitalizing on the immensely diverse, but highly specific, potential associated with the biological macromolecular landscape. Here we describe a drug-drug synergy mediated by allosteric cross-talk in chromatin, whereby the binding of ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14860

    authors： Adhireksan Z,Palermo G,Riedel T,Ma Z,Muhammad R,Rothlisberger U,Dyson PJ,Davey CA

    更新日期：2017-03-30 00:00:00