当前位置： SCI文献检索 > Nature Communications期刊下所有文献 > Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry.

Boosting lithium storage in covalent organic framework via activation of 14-electron redox chemistry.

Abstract：

:Conjugated polymeric molecules have been heralded as promising electrode materials for the next-generation energy-storage technologies owing to their chemical flexibility at the molecular level, environmental benefit, and cost advantage. However, before any practical implementation takes place, the low capacity, poor structural stability, and sluggish ion/electron diffusion kinetics remain the obstacles that have to be overcome. Here, we report the synthesis of a few-layered two-dimensional covalent organic framework trapped by carbon nanotubes as the anode of lithium-ion batteries. Remarkably, upon activation, this organic electrode delivers a large reversible capacity of 1536 mAh g-1 and can sustain 500 cycles at 100 mA g-1. Aided by theoretical calculations and electrochemical probing of the electrochemical behavior at different stages of cycling, the storage mechanism is revealed to be governed by 14-electron redox chemistry for a covalent organic framework monomer with one lithium ion per C=N group and six lithium ions per benzene ring. This work may pave the way to the development of high-capacity electrodes for organic rechargeable batteries.

journal_name

Nat Commun

journal_title

Nature communications

authors

Lei Z,Yang Q,Xu Y,Guo S,Sun W,Liu H,Lv LP,Zhang Y,Wang Y

doi

10.1038/s41467-018-02889-7

subject

Has Abstract

pub_date

2018-02-08 00:00:00

pages

576

issue

1

issn

2041-1723

pii

10.1038/s41467-018-02889-7

journal_volume

9

pub_type

杂志文章

相关文献

Nature Communications文献大全
  • Repeated quantum error correction on a continuously encoded qubit by real-time feedback.

    abstract：:Reliable quantum information processing in the face of errors is a major fundamental and technological challenge. Quantum error correction protects quantum states by encoding a logical quantum bit (qubit) in multiple physical qubits. To be compatible with universal fault-tolerant computations, it is essential that sta...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11526

    authors： Cramer J,Kalb N,Rol MA,Hensen B,Blok MS,Markham M,Twitchen DJ,Hanson R,Taminiau TH

    更新日期：2016-05-05 00:00:00

  • Full-field thermal imaging of quasiballistic crosstalk reduction in nanoscale devices.

    abstract：:Understanding nanoscale thermal transport is of substantial importance for designing contemporary semiconductor technologies. Heat removal from small sources is well established to be severely impeded compared to diffusive predictions due to the ballistic nature of the dominant heat carriers. Experimental observations...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-02652-4

    authors： Ziabari A,Torres P,Vermeersch B,Xuan Y,Cartoixà X,Torelló A,Bahk JH,Koh YR,Parsa M,Ye PD,Alvarez FX,Shakouri A

    更新日期：2018-01-17 00:00:00

  • Compensatory metabolic networks in pancreatic cancers upon perturbation of glutamine metabolism.

    abstract：:Pancreatic ductal adenocarcinoma is a notoriously difficult-to-treat cancer and patients are in need of novel therapies. We have shown previously that these tumours have altered metabolic requirements, making them highly reliant on a number of adaptations including a non-canonical glutamine (Gln) metabolic pathway and...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms15965

    authors： Biancur DE,Paulo JA,Małachowska B,Quiles Del Rey M,Sousa CM,Wang X,Sohn ASW,Chu GC,Gygi SP,Harper JW,Fendler W,Mancias JD,Kimmelman AC

    更新日期：2017-07-03 00:00:00

  • Pyruvate kinase type M2 promotes tumour cell exosome release via phosphorylating synaptosome-associated protein 23.

    abstract：:Tumour cells secrete exosomes that are involved in the remodelling of the tumour-stromal environment and promoting malignancy. The mechanisms governing tumour exosome release, however, remain incompletely understood. Here we show that tumour cell exosomes secretion is controlled by pyruvate kinase type M2 (PKM2), whic...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14041

    authors： Wei Y,Wang D,Jin F,Bian Z,Li L,Liang H,Li M,Shi L,Pan C,Zhu D,Chen X,Hu G,Liu Y,Zhang CY,Zen K

    更新日期：2017-01-09 00:00:00

  • Metabolic potential of uncultured bacteria and archaea associated with petroleum seepage in deep-sea sediments.

    abstract：:The lack of microbial genomes and isolates from the deep seabed means that very little is known about the ecology of this vast habitat. Here, we investigate energy and carbon acquisition strategies of microbial communities from three deep seabed petroleum seeps (3 km water depth) in the Eastern Gulf of Mexico. Shotgun...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-09747-0

    authors： Dong X,Greening C,Rattray JE,Chakraborty A,Chuvochina M,Mayumi D,Dolfing J,Li C,Brooks JM,Bernard BB,Groves RA,Lewis IA,Hubert CRJ

    更新日期：2019-04-18 00:00:00

  • The viral protein corona directs viral pathogenesis and amyloid aggregation.

    abstract：:Artificial nanoparticles accumulate a protein corona layer in biological fluids, which significantly influences their bioactivity. As nanosized obligate intracellular parasites, viruses share many biophysical properties with artificial nanoparticles in extracellular environments and here we show that respiratory syncy...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-10192-2

    authors： Ezzat K,Pernemalm M,Pålsson S,Roberts TC,Järver P,Dondalska A,Bestas B,Sobkowiak MJ,Levänen B,Sköld M,Thompson EA,Saher O,Kari OK,Lajunen T,Sverremark Ekström E,Nilsson C,Ishchenko Y,Malm T,Wood MJA,Power UF,Masic

    更新日期：2019-05-27 00:00:00

  • Self-assembly of free-standing RNA membranes.

    abstract：:RNA has emerged as a promising material for nanostructure and microstructure engineering. Although rare, some macroscopic RNA structures have also been constructed using lipid or polymer materials. Here, we report the first example of an enzymatically generated RNA membrane. This robust and free-standing RNA membrane ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5367

    authors： Han D,Park Y,Kim H,Lee JB

    更新日期：2014-07-04 00:00:00

  • CRISPR/Cas9-mediated glycolate oxidase disruption is an efficacious and safe treatment for primary hyperoxaluria type I.

    abstract：:CRISPR/Cas9 technology offers novel approaches for the development of new therapies for many unmet clinical needs, including a significant number of inherited monogenic diseases. However, in vivo correction of disease-causing genes is still inefficient, especially for those diseases without selective advantage for cor...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-07827-1

    authors： Zabaleta N,Barberia M,Martin-Higueras C,Zapata-Linares N,Betancor I,Rodriguez S,Martinez-Turrillas R,Torella L,Vales A,Olagüe C,Vilas-Zornoza A,Castro-Labrador L,Lara-Astiaso D,Prosper F,Salido E,Gonzalez-Aseguinolaza G,R

    更新日期：2018-12-21 00:00:00

  • Plasmonic tunnel junctions for single-molecule redox chemistry.

    abstract：:Nanoparticles attached just above a flat metallic surface can trap optical fields in the nanoscale gap. This enables local spectroscopy of a few molecules within each coupled plasmonic hotspot, with near thousand-fold enhancement of the incident fields. As a result of non-radiative relaxation pathways, the plasmons in...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00819-7

    authors： de Nijs B,Benz F,Barrow SJ,Sigle DO,Chikkaraddy R,Palma A,Carnegie C,Kamp M,Sundararaman R,Narang P,Scherman OA,Baumberg JJ

    更新日期：2017-10-20 00:00:00

  • Methylglyoxal couples metabolic and translational control of Notch signalling in mammalian neural stem cells.

    abstract：:Gene regulation and metabolism are two fundamental processes that coordinate the self-renewal and differentiation of neural precursor cells (NPCs) in the developing mammalian brain. However, little is known about how metabolic signals instruct gene expression to control NPC homeostasis. Here, we show that methylglyoxa...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15941-2

    authors： Rodrigues DC,Harvey EM,Suraj R,Erickson SL,Mohammad L,Ren M,Liu H,He G,Kaplan DR,Ellis J,Yang G

    更新日期：2020-04-24 00:00:00

  • Integrin α7 is a functional cancer stem cell surface marker in oesophageal squamous cell carcinoma.

    abstract：:Non-CG methylation has been associated with stemness regulation in embryonic stem cells. By comparing differentially expressed genes affected by non-CG methylation between tumour and corresponding non-tumour tissues in oesophageal squamous cell carcinoma (OSCC), we find that Integrin α7 (ITGA7) is characterized as a p...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms13568

    authors： Ming XY,Fu L,Zhang LY,Qin YR,Cao TT,Chan KW,Ma S,Xie D,Guan XY

    更新日期：2016-12-07 00:00:00

  • The low-affinity complex of cytochrome c and its peroxidase.

    abstract：:The complex of yeast cytochrome c peroxidase and cytochrome c is a paradigm of the biological electron transfer (ET). Building on seven decades of research, two different models have been proposed to explain its functional redox activity. One postulates that the intermolecular ET occurs only in the dominant, high-affi...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms8073

    authors： Van de Water K,Sterckx YG,Volkov AN

    更新日期：2015-05-06 00:00:00

  • Olfactory specificity regulates lipid metabolism through neuroendocrine signaling in Caenorhabditis elegans.

    abstract：:Olfactory and metabolic dysfunctions are intertwined phenomena associated with obesity and neurodegenerative diseases; yet how mechanistically olfaction regulates metabolic homeostasis remains unclear. Specificity of olfactory perception integrates diverse environmental odors and olfactory neurons expressing different...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15296-8

    authors： Mutlu AS,Gao SM,Zhang H,Wang MC

    更新日期：2020-03-19 00:00:00

  • Deficient Wnt signalling triggers striatal synaptic degeneration and impaired motor behaviour in adult mice.

    abstract：:Synapse degeneration is an early and invariant feature of neurodegenerative diseases. Indeed, synapse loss occurs prior to neuronal degeneration and correlates with the symptom severity of these diseases. However, the molecular mechanisms that trigger synaptic loss remain poorly understood. Here we demonstrate that de...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5992

    authors： Galli S,Lopes DM,Ammari R,Kopra J,Millar SE,Gibb A,Salinas PC

    更新日期：2014-10-16 00:00:00

  • δ and φ back-donation in AnIV metallacycles.

    abstract：:In all known examples of metal-ligand (M-L) δ and φ bonds, the metal orbitals are aligned to the ligand orbitals in a "head-to-head" or "side-to-head" fashion. Here, we report two fundamentally new types of M-L δ and φ interactions; "head-to-side" δ and "side-to-side" φ back-bonding, found in complexes of metallacyclo...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-020-15197-w

    authors： Kelley MP,Popov IA,Jung J,Batista ER,Yang P

    更新日期：2020-03-25 00:00:00

  • Modulation-doped growth of mosaic graphene with single-crystalline p-n junctions for efficient photocurrent generation.

    abstract：:Device applications of graphene such as ultrafast transistors and photodetectors benefit from the combination of both high-quality p- and n-doped components prepared in a large-scale manner with spatial control and seamless connection. Here we develop a well-controlled chemical vapour deposition process for direct gro...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2286

    authors： Yan K,Wu D,Peng H,Jin L,Fu Q,Bao X,Liu Z

    更新日期：2012-01-01 00:00:00

  • Imprintable membranes from incomplete chiral coalescence.

    abstract：:Coalescence is an essential phenomenon that governs the equilibrium behaviour in a variety of systems from intercellular transport to planetary formation. In this report, we study coalescence pathways of circularly shaped two-dimensional colloidal membranes, which are one rod-length-thick liquid-like monolayers of ali...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms4063

    authors： Zakhary MJ,Gibaud T,Kaplan CN,Barry E,Oldenbourg R,Meyer RB,Dogic Z

    更新日期：2014-01-01 00:00:00

  • Obligatory and facilitative allelic variation in the DNA methylome within common disease-associated loci.

    abstract：:Integrating epigenetic data with genome-wide association study (GWAS) results can reveal disease mechanisms. The genome sequence itself also shapes the epigenome, with CpG density and transcription factor binding sites (TFBSs) strongly encoding the DNA methylome. Therefore, genetic polymorphism impacts on the observed...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-01586-1

    authors： Bell CG,Gao F,Yuan W,Roos L,Acton RJ,Xia Y,Bell J,Ward K,Mangino M,Hysi PG,Wang J,Spector TD

    更新日期：2018-01-02 00:00:00

  • Purified F-ATP synthase forms a Ca2+-dependent high-conductance channel matching the mitochondrial permeability transition pore.

    abstract：:The molecular identity of the mitochondrial megachannel (MMC)/permeability transition pore (PTP), a key effector of cell death, remains controversial. By combining highly purified, fully active bovine F-ATP synthase with preformed liposomes we show that Ca2+ dissipates the H+ gradient generated by ATP hydrolysis. Afte...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12331-1

    authors： Urbani A,Giorgio V,Carrer A,Franchin C,Arrigoni G,Jiko C,Abe K,Maeda S,Shinzawa-Itoh K,Bogers JFM,McMillan DGG,Gerle C,Szabò I,Bernardi P

    更新日期：2019-09-25 00:00:00

  • Higher levels of multiple ecosystem services are found in forests with more tree species.

    abstract：:Forests are of major importance to human society, contributing several crucial ecosystem services. Biodiversity is suggested to positively influence multiple services but evidence from natural systems at scales relevant to management is scarce. Here, across a scale of 400,000 km(2), we report that tree species richnes...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms2328

    authors： Gamfeldt L,Snäll T,Bagchi R,Jonsson M,Gustafsson L,Kjellander P,Ruiz-Jaen MC,Fröberg M,Stendahl J,Philipson CD,Mikusiński G,Andersson E,Westerlund B,Andrén H,Moberg F,Moen J,Bengtsson J

    更新日期：2013-01-01 00:00:00

  • Synchronous precessional motion of multiple domain walls in a ferromagnetic nanowire by perpendicular field pulses.

    abstract：:Magnetic storage and logic devices based on magnetic domain wall motion rely on the precise and synchronous displacement of multiple domain walls. The conventional approach using magnetic fields does not allow for the synchronous motion of multiple domains. As an alternative method, synchronous current-induced domain ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms4429

    authors： Kim JS,Mawass MA,Bisig A,Krüger B,Reeve RM,Schulz T,Büttner F,Yoon J,You CY,Weigand M,Stoll H,Schütz G,Swagten HJ,Koopmans B,Eisebitt S,Kläui M

    更新日期：2014-03-24 00:00:00

  • Freestanding three-dimensional core-shell nanoarrays for lithium-ion battery anodes.

    abstract：:Structural degradation and low conductivity of transition-metal oxides lead to severe capacity fading in lithium-ion batteries. Recent efforts to solve this issue have mainly focused on using nanocomposites or hybrids by integrating nanosized metal oxides with conducting additives. Here we design specific hierarchical...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms11774

    authors： Tan G,Wu F,Yuan Y,Chen R,Zhao T,Yao Y,Qian J,Liu J,Ye Y,Shahbazian-Yassar R,Lu J,Amine K

    更新日期：2016-06-03 00:00:00

  • Unconventionally secreted effectors of two filamentous pathogens target plant salicylate biosynthesis.

    abstract：:Plant diseases caused by fungi and oomycetes pose an increasing threat to food security and ecosystem health worldwide. These filamentous pathogens, while taxonomically distinct, modulate host defense responses by secreting effectors, which are typically identified based on the presence of signal peptides. Here we sho...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms5686

    authors： Liu T,Song T,Zhang X,Yuan H,Su L,Li W,Xu J,Liu S,Chen L,Chen T,Zhang M,Gu L,Zhang B,Dou D

    更新日期：2014-08-26 00:00:00

  • Microglial dopamine receptor elimination defines sex-specific nucleus accumbens development and social behavior in adolescent rats.

    abstract：:Adolescence is a developmental period in which the mesolimbic dopaminergic "reward" circuitry of the brain, including the nucleus accumbens (NAc), undergoes significant plasticity. Dopamine D1 receptors (D1rs) in the NAc are critical for social behavior, but how these receptors are regulated during adolescence is not ...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-018-06118-z

    authors： Kopec AM,Smith CJ,Ayre NR,Sweat SC,Bilbo SD

    更新日期：2018-09-25 00:00:00

  • Publisher Correction: Genome-wide association of polycystic ovary syndrome implicates alterations in gonadotropin secretion in European ancestry populations.

    abstract：:An amendment to this paper has been published and can be accessed via a link at the top of the paper. ...

    journal_title：Nature communications

    pub_type： 杂志文章,已发布勘误

    doi：10.1038/s41467-020-15793-w

    authors： Hayes MG,Urbanek M,Ehrmann DA,Armstrong LL,Lee JY,Sisk R,Karaderi T,Barber TM,McCarthy MI,Franks S,Lindgren CM,Welt CK,Diamanti-Kandarakis E,Panidis D,Goodarzi MO,Azziz R,Zhang Y,James RG,Olivier M,Kissebah AH,Rep

    更新日期：2020-04-28 00:00:00

  • Targeted activation of diverse CRISPR-Cas systems for mammalian genome editing via proximal CRISPR targeting.

    abstract：:Bacterial CRISPR-Cas systems comprise diverse effector endonucleases with different targeting ranges, specificities and enzymatic properties, but many of them are inactive in mammalian cells and are thus precluded from genome-editing applications. Here we show that the type II-B FnCas9 from Francisella novicida posses...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/ncomms14958

    authors： Chen F,Ding X,Feng Y,Seebeck T,Jiang Y,Davis GD

    更新日期：2017-04-07 00:00:00

  • PreDicta chip-based high resolution diagnosis of rhinovirus-induced wheeze.

    abstract：:Rhinovirus (RV) infections are major triggers of acute exacerbations of severe respiratory diseases such as pre-school wheeze, asthma and chronic obstructive pulmonary disease (COPD). The occurrence of numerous RV types is a major challenge for the identification of the culprit virus types and for the improvement of v...

    journal_title：Nature communications

    pub_type： 临床试验,杂志文章

    doi：10.1038/s41467-018-04591-0

    authors： Niespodziana K,Stenberg-Hammar K,Megremis S,Cabauatan CR,Napora-Wijata K,Vacal PC,Gallerano D,Lupinek C,Ebner D,Schlederer T,Harwanegg C,Söderhäll C,van Hage M,Hedlin G,Papadopoulos NG,Valenta R

    更新日期：2018-06-18 00:00:00

  • Bacterial MgrB peptide activates chemoreceptor Fpr3 in mouse accessory olfactory system and drives avoidance behaviour.

    abstract：:Innate immune chemoreceptors of the formyl peptide receptor (Fpr) family are expressed by vomeronasal sensory neurons (VSNs) in the accessory olfactory system. Their biological function and coding mechanisms remain unknown. We show that mouse Fpr3 (Fpr-rs1) recognizes the core peptide motif f-MKKFRW that is predominan...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-019-12842-x

    authors： Bufe B,Teuchert Y,Schmid A,Pyrski M,Pérez-Gómez A,Eisenbeis J,Timm T,Ishii T,Lochnit G,Bischoff M,Mombaerts P,Leinders-Zufall T,Zufall F

    更新日期：2019-10-25 00:00:00

  • Synchronized conductivity modulation to realize broadband lossless magnetic-free non-reciprocity.

    abstract：:Recent research has explored the spatiotemporal modulation of permittivity to break Lorentz reciprocity in a manner compatible with integrated-circuit fabrication. However, permittivity modulation is inherently weak and accompanied by loss due to carrier injection, particularly at higher frequencies, resulting in larg...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-00798-9

    authors： Dinc T,Tymchenko M,Nagulu A,Sounas D,Alu A,Krishnaswamy H

    更新日期：2017-10-06 00:00:00

  • Switchable photovoltaic windows enabled by reversible photothermal complex dissociation from methylammonium lead iodide.

    abstract：:Materials with switchable absorption properties have been widely used for smart window applications to reduce energy consumption and enhance occupant comfort in buildings. In this work, we combine the benefits of smart windows with energy conversion by producing a photovoltaic device with a switchable absorber layer t...

    journal_title：Nature communications

    pub_type： 杂志文章

    doi：10.1038/s41467-017-01842-4

    authors： Wheeler LM,Moore DT,Ihly R,Stanton NJ,Miller EM,Tenent RC,Blackburn JL,Neale NR

    更新日期：2017-11-23 00:00:00