Elemental and Molecular Segregation in Oil Paintings due to Lead Soap Degradation.

Abstract:

:The formation of Pb, Zn, and Cu carboxylates (soaps) has caused visible deterioration in hundreds of oil paintings dating from the 15th century to the present. Through transport phenomena not yet understood, free fatty acids in the oil binding medium migrate through the paint and react with pigments containing heavy metals to form soaps. To investigate the complex correlation among the elemental segregation, types of chemical compounds formed, and possible mechanisms of the reactions, a paint sample cross-section from a 15th century oil painting was examined by synchrotron X-ray techniques. X-ray fluorescence (XRF) microscopy, quantified with elemental correlation density distribution, showed Pb and Sn segregation in the soap-affected areas. X-ray absorption near edge structure (XANES) around the Pb-L3 absorption edge showed that Pb pigments and Pb soaps can be distinguished while micro-XANES gave further information on the chemical heterogeneity in the paint film. The advantages and limitations of these synchrotron-based techniques are discussed and compared to those of methods routinely used to analyze paint samples. The results presented set the stage for improving the information extracted from samples removed from works of art and for correlating observations in model paint samples to those in the naturally aged samples, to shed light onto the mechanism of soap formation.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Chen-Wiegart YK,Catalano J,Williams GJ,Murphy A,Yao Y,Zumbulyadis N,Centeno SA,Dybowski C,Thieme J

doi

10.1038/s41598-017-11525-1

subject

Has Abstract

pub_date

2017-09-14 00:00:00

pages

11656

issue

1

issn

2045-2322

pii

10.1038/s41598-017-11525-1

journal_volume

7

pub_type

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