Quantification of the boron speciation in alkali borosilicate glasses by electron energy loss spectroscopy.

Abstract:

:Transmission electron microscopy and related analytical techniques have been widely used to study the microstructure of different materials. However, few research works have been performed in the field of glasses, possibly due to the electron-beam irradiation damage. In this paper, we have developed a method based on electron energy loss spectroscopy (EELS) data acquisition and analyses, which enables determination of the boron speciation in a series of ternary alkali borosilicate glasses with constant molar ratios. A script for the fast acquisition of EELS has been designed, from which the fraction of BO4 tetrahedra can be obtained by fitting the experimental data with linear combinations of the reference spectra. The BO4 fractions (N4) obtained by EELS are consistent with those from (11)B MAS NMR spectra, suggesting that EELS can be an alternative and convenient way to determine the N4 fraction in glasses. In addition, the boron speciation of a CeO2 doped potassium borosilicate glass has been analyzed by using the time-resolved EELS spectra. The results clearly demonstrate that the BO4 to BO3 transformation induced by the electron beam irradiation can be efficiently suppressed by doping CeO2 to the borosilicate glasses.

journal_name

Sci Rep

journal_title

Scientific reports

authors

Cheng S,Yang G,Zhao Y,Peng M,Skibsted J,Yue Y

doi

10.1038/srep17526

subject

Has Abstract

pub_date

2015-12-08 00:00:00

pages

17526

issn

2045-2322

pii

srep17526

journal_volume

5

pub_type

杂志文章
  • Time trends of esophageal and gastric cancer mortality in China, 1991-2009: an age-period-cohort analysis.

    abstract::Esophageal and gastric cancers share some risk factors. This study aimed to compare the long-term trends in mortality rates of esophageal and gastric cancers in China to provide evidence for cancer prevention and control. Mortality data were derived from 103 continuous points of the Disease Surveillance Points system ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-07071-5

    authors: Li M,Wan X,Wang Y,Sun Y,Yang G,Wang L

    更新日期:2017-07-28 00:00:00

  • Building early-larval sexing systems for genetic control of the Australian sheep blow fly Lucilia cuprina using two constitutive promoters.

    abstract::Transgenic sexing strains (TSS) that carry conditional female lethal genes are advantageous for genetic control programs based on the sterile insect technique (SIT). It is desirable if females die early in development as larval diet is a major cost for mass production facilities. This can be achieved by using a gene p...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-02763-4

    authors: Yan Y,Linger RJ,Scott MJ

    更新日期:2017-05-31 00:00:00

  • Inter-digital capacitors with aerosol-deposited high-K dielectric layer for highest capacitance value in capacitive super-sensing applications.

    abstract::Inter-digital capacitors (IDCs) with aerosol-deposition (AD) high-k dielectric layer were compared via simulation and measurements of bare IDCs and AD IDCs at room temperature and subjected to a post-annealing process for realizing capacitive super-sensing applications. IDCs with thin AD films can provide higher capac...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-37416-7

    authors: Kim ES,Liang JG,Wang C,Cho MY,Oh JM,Kim NY

    更新日期:2019-01-24 00:00:00

  • Efficient Blood-Brain Barrier Opening in Primates with Neuronavigation-Guided Ultrasound and Real-Time Acoustic Mapping.

    abstract::Brain diseases including neurological disorders and tumors remain under treated due to the challenge to access the brain, and blood-brain barrier (BBB) restricting drug delivery which, also profoundly limits the development of pharmacological treatment. Focused ultrasound (FUS) with microbubbles is the sole method to ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-25904-9

    authors: Wu SY,Aurup C,Sanchez CS,Grondin J,Zheng W,Kamimura H,Ferrera VP,Konofagou EE

    更新日期:2018-05-22 00:00:00

  • mTOR regulates neuroprotective effect of immunized CD4+Foxp3+ T cells in optic nerve ischemia.

    abstract::The therapeutic potential of targeting CD4+Foxp3+ regulatory T cells (Tregs) remains controversial under the condition of neuroinflammation. This study aims to explore the neuroprotective role of Tregs in optic nerve ischemia (ONI) and evaluate the therapeutic strategy of Tregs transfer with a focus on targeting the m...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep37805

    authors: Chen G,Tang L,Wei W,Li Z,Li Y,Duan X,Chen H

    更新日期:2016-11-25 00:00:00

  • Absorption of α-tocopheryl acetate is limited in mink kits (Mustela vison) during weaning.

    abstract::Bioavailability of α-tocopherol varies with source, dose and duration of supplementation. The effect of source and dose of α-tocopherol on response of α-tocopherol stereoisomers in plasma and tissues of mink kits during the weaning period was studied. Twelve mink kits were euthanised in CO2 at the beginning of the exp...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-80902-0

    authors: Lashkari S,Clausen TN,Foldager L,Jensen SK

    更新日期:2021-01-29 00:00:00

  • Interaction of Src and Alpha-V Integrin Regulates Fibroblast Migration and Modulates Lung Fibrosis in A Preclinical Model of Lung Fibrosis.

    abstract::Src kinase is known to regulate fibroblast migration. However, the contribution of integrin and Src kinase interaction to lung fibrosis has not been mechanistically investigated. Our data demonstrate that integrin alpha v (αV) recruited Src kinase and that leads to subsequent Src activation in fibroblasts plated on fi...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep46357

    authors: Lu YY,Zhao XK,Yu L,Qi F,Zhai B,Gao CQ,Ding Q

    更新日期:2017-04-11 00:00:00

  • MALDI-Imaging Mass Spectrometry: a step forward in the anatomopathological characterization of stenotic aortic valve tissue.

    abstract::Aortic stenosis (AS) is the most common form of valve disease. Once symptoms develop, there is an inexorable deterioration with a poor prognosis; currently there are no therapies capable of modifying disease progression, and aortic valve replacement is the only available treatment. Our goal is to study the progression...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep27106

    authors: Mourino-Alvarez L,Iloro I,de la Cuesta F,Azkargorta M,Sastre-Oliva T,Escobes I,Lopez-Almodovar LF,Sanchez PL,Urreta H,Fernandez-Aviles F,Pinto A,Padial LR,Akerström F,Elortza F,Barderas MG

    更新日期:2016-06-03 00:00:00

  • Physiological demands of a swimming-based video game: Influence of gender, swimming background, and exergame experience.

    abstract::Active video games (exergames) may provide short-term increase in energy expenditure. We explored the effects of gender and prior experience on aerobic and anaerobic energy systems contributions, and the activity profiles of 40 participants playing with a swimming exergame. We recorded oxygen consumption and assessed ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-05583-8

    authors: Soltani P,Figueiredo P,Ribeiro J,Fernandes RJ,Vilas-Boas JP

    更新日期:2017-07-12 00:00:00

  • Electrochemical analysis of anionic analytes in weakly supported media using electron transfer promotion effect: a case study on nitrite.

    abstract::In this study, a simple technique was developed for the electrochemical detection of anionic analytes in weakly supported media. This was conducted by the use of electrochemical paper-based analytical devices (ePADs). A sensing platform was modified with nereistoxin and used to determine nitrite as a case study. The e...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-71365-4

    authors: Khoshroo A,Fattahi A

    更新日期:2020-09-03 00:00:00

  • Chromatin Compaction by Small RNAs and the Nuclear RNAi Machinery in C. elegans.

    abstract::DNA is organized and compacted into higher-order structures in order to fit within nuclei and to facilitate gene regulation. Mechanisms by which higher order chromatin structures are established and maintained are poorly understood. In C. elegans, nuclear-localized small RNAs engage the nuclear RNAi machinery to regul...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-45052-y

    authors: Fields BD,Kennedy S

    更新日期:2019-06-21 00:00:00

  • Genetic aetiology of self-harm ideation and behaviour.

    abstract::Family studies have identified a heritable component to self-harm that is partially independent from comorbid psychiatric disorders. However, the genetic aetiology of broad sense (non-suicidal and suicidal) self-harm has not been characterised on the molecular level. In addition, controversy exists about the degree to...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-66737-9

    authors: Campos AI,Verweij KJH,Statham DJ,Madden PAF,Maciejewski DF,Davis KAS,John A,Hotopf M,Heath AC,Martin NG,Rentería ME

    更新日期:2020-06-16 00:00:00

  • The zebrafish ventricle: A hub of cardiac endothelial cells for in vitro cell behavior studies.

    abstract::Despite our increasing understanding of zebrafish heart development and regeneration, there is limited information about the distribution of endothelial cells (ECs) in the adult zebrafish heart. Here, we investigate and compare the distribution of cardiac ECs (cECs) in adult mouse and zebrafish ventricles. Surprisingl...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-02461-1

    authors: Patra C,Kontarakis Z,Kaur H,Rayrikar A,Mukherjee D,Stainier DYR

    更新日期:2017-06-02 00:00:00

  • Delivery of subunit influenza vaccine to skin with microneedles improves immunogenicity and long-lived protection.

    abstract::Influenza infection represents a major socio-economic burden worldwide. Novel delivery methods can render influenza vaccination easier and more acceptable by the public, and importantly confer protection equal or superior to that induced by conventional systemic administration. An attractive target for vaccine deliver...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep00357

    authors: Koutsonanos DG,Vassilieva EV,Stavropoulou A,Zarnitsyn VG,Esser ES,Taherbhai MT,Prausnitz MR,Compans RW,Skountzou I

    更新日期:2012-01-01 00:00:00

  • Acupuncture elicits neuroprotective effect by inhibiting NAPDH oxidase-mediated reactive oxygen species production in cerebral ischaemia.

    abstract::In the current study, we aimed to investigate whether NADPH oxidase, a major ROS-producing enzyme, was involved in the antioxidant effect of acupuncture on cognitive impairment after cerebral ischaemia. The cognitive function, infract size, neuron cell loss, level of superoxide anion and expression of NADPH oxidase su...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep17981

    authors: Shi GX,Wang XR,Yan CQ,He T,Yang JW,Zeng XH,Xu Q,Zhu W,Du SQ,Liu CZ

    更新日期:2015-12-10 00:00:00

  • ATF4 overexpression induces early onset of hyperlipidaemia and hepatic steatosis and enhances adipogenesis in zebrafish.

    abstract::Activating transcription factor 4 (ATF4) is constitutively expressed in a variety of tissues, and regulates several pathological features associated with metabolic diseases such as non-alcoholic fatty liver diseases (NAFLD) and obesity. However, the role of ATF4 in animal model systems is poorly understood. To investi...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-16587-9

    authors: Yeh KY,Lai CY,Lin CY,Hsu CC,Lo CP,Her GM

    更新日期:2017-11-27 00:00:00

  • The Charging Events in Contact-Separation Electrification.

    abstract::Contact electrification (CE)-charging of surfaces that are contacted and separated, is a common phenomenon, however it is not completely understood yet. Recent studies using surface imaging techniques and chemical analysis revealed a 'spatial' bipolar distribution of charges at the nano dimension, which made a paradig...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-20413-1

    authors: Musa UG,Cezan SD,Baytekin B,Baytekin HT

    更新日期:2018-02-06 00:00:00

  • Characterisation and pharmacological analysis of a crustacean G protein-coupled receptor: the red pigment-concentrating hormone receptor of Daphnia pulex.

    abstract::This is the first pharmacological characterisation of a neuropeptide G protein-coupled receptor (GPCR) in a crustacean. We cloned the ORF of the red pigment-concentrating hormone from a German strain of Daphnia pulex (Dappu-RPCH), as well as that of the cognate receptor (Dappu-RPCHR). Dappu-RPCHR has the hallmarks of ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-06805-9

    authors: Marco HG,Verlinden H,Vanden Broeck J,Gäde G

    更新日期:2017-07-31 00:00:00

  • Genetic Variations of NLR family genes in Behcet's Disease.

    abstract::This study aimed to investigate whether single nucleotide polymorphisms (SNPs) of five NLR family genes (NOD1, NOD2, NLRP1, NLRP3 and CIITA) are associated with Behcet's disease (BD) in a Chinese Han population. The study was carried out in 950 BD patients and 1440 controls for 19 SNPs in the selected NLR genes. In th...

    journal_title:Scientific reports

    pub_type: 临床试验,杂志文章,多中心研究

    doi:10.1038/srep20098

    authors: Li L,Yu H,Jiang Y,Deng B,Bai L,Kijlstra A,Yang P

    更新日期:2016-02-01 00:00:00

  • Swimming of peritrichous bacteria is enabled by an elastohydrodynamic instability.

    abstract::Peritrichously-flagellated bacteria, such as Escherichia coli, self-propel in fluids by using specialised motors to rotate multiple helical filaments. The rotation of each motor is transmitted to a short flexible segment called the hook which in turn transmits it to a flagellar filament, enabling swimming of the whole...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-28319-8

    authors: Riley EE,Das D,Lauga E

    更新日期:2018-07-16 00:00:00

  • Highly flexible dye-sensitized solar cells produced by sewing textile electrodes on cloth.

    abstract::Textile forms of solar cells possess special advantages over other types of solar cells, including their light weight, high flexibility, and mechanical robustness. Recent demand for wearable devices has promoted interest in the development of high-efficiency textile-based solar cells for energy suppliers. However, the...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep05322

    authors: Yun MJ,Cha SI,Seo SH,Lee DY

    更新日期:2014-06-24 00:00:00

  • Human Defensin-5 Blocks Ethanol and Colitis-Induced Dysbiosis, Tight Junction Disruption and Inflammation in Mouse Intestine.

    abstract::Alcohol consumption has been shown to cause dysbiosis, but the mechanism involved in it is unknown. Recurrent colitis is known to induce expression of α-defensins in the colon, but the effect of alcohol consumption on it is not known. We investigated the effect of ethanol on α-defensin expression in the small intestin...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-018-34263-4

    authors: Shukla PK,Meena AS,Rao V,Rao RG,Balazs L,Rao R

    更新日期:2018-11-02 00:00:00

  • First estimates of Greenland shark (Somniosus microcephalus) local abundances in Arctic waters.

    abstract::Baited remote underwater video cameras were deployed in the Eastern Canadian Arctic, for the purpose of estimating local densities of the long-lived Greenland shark within five deep-water, data-poor regions of interest for fisheries development and marine conservation in Nunavut, Canada. A total of 31 camera deploymen...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-017-19115-x

    authors: Devine BM,Wheeland LJ,Fisher JAD

    更新日期:2018-01-17 00:00:00

  • Reconstruction of thermotolerant yeast by one-point mutation identified through whole-genome analyses of adaptively-evolved strains.

    abstract::Saccharomyces cerevisiae is used as a host strain in bioproduction, because of its rapid growth, ease of genetic manipulation, and high reducing capacity. However, the heat produced during the fermentation processes inhibits the biological activities and growth of the yeast cells. We performed whole-genome sequencing ...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep23157

    authors: Satomura A,Miura N,Kuroda K,Ueda M

    更新日期:2016-03-17 00:00:00

  • Development of a lateral flow test for bed bug detection.

    abstract::Lateral flow strip tests are a cost-effective method for detecting specific proteins in biological samples, which can be performed in the field without specialized expertise. While most recognizable in the pregnancy tests, there are many other applications for lateral flow strip technology. The pest control industry h...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-70200-0

    authors: Ko A,Choe DH

    更新日期:2020-08-07 00:00:00

  • Sodium-activated potassium channels shape peripheral auditory function and activity of the primary auditory neurons in mice.

    abstract::Potassium (K+) channels shape the response properties of neurons. Although enormous progress has been made to characterize K+ channels in the primary auditory neurons, the molecular identities of many of these channels and their contributions to hearing in vivo remain unknown. Using a combination of RNA sequencing and...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-39119-z

    authors: Reijntjes DOJ,Lee JH,Park S,Schubert NMA,van Tuinen M,Vijayakumar S,Jones TA,Jones SM,Gratton MA,Xia XM,Yamoah EN,Pyott SJ

    更新日期:2019-02-22 00:00:00

  • Low blood cell counts in wild Japanese monkeys after the Fukushima Daiichi nuclear disaster.

    abstract::In April 2012 we carried out a 1-year hematological study on a population of wild Japanese monkeys inhabiting the forest area of Fukushima City. This area is located 70 km from the Fukushima Daiichi Nuclear Power Plant (NPP), which released a large amount of radioactive material into the environment following the Grea...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/srep05793

    authors: Ochiai K,Hayama S,Nakiri S,Nakanishi S,Ishii N,Uno T,Kato T,Konno F,Kawamoto Y,Tsuchida S,Omi T

    更新日期:2014-07-24 00:00:00

  • Cluster radioactivity of neutron-deficient nuclei in trans-tin region.

    abstract::The possibility of cluster radioactivity (CR) of the neutron-deficient nuclei in the trans-tin region is explored by using the effective liquid drop model (ELDM), generalized liquid drop model (GLDM), and several sets of analytic formulas. It is found that the minimal half-lives are at Nd = 50 (Nd is the neutron numbe...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-65585-x

    authors: Gao Y,Cui J,Wang Y,Gu J

    更新日期:2020-06-04 00:00:00

  • Coating Cutting Blades with Thin-Film Metallic Glass to Enhance Sharpness.

    abstract::In this study, we sought to enhance the cutting properties of the various blades by coating them with Zr- and Fe-based thin film metallic glasses (TFMGs) to a thickness of 234-255 nm via sputter deposition. In oil-repellency/sliding tests on kitchen blades, the sliding angle and friction forces were as follows: bare b...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-019-52054-3

    authors: Chu JP,Diyatmika W,Tseng YJ,Liu YK,Liao WC,Chang SH,Chen MJ,Lee JW,Jang JSC

    更新日期:2019-10-29 00:00:00

  • Self-similar transport, spin polarization and thermoelectricity in complex silicene structures.

    abstract::2D materials open the possibility to study Dirac electrons in complex self-similar geometries. The two-dimensional nature of materials like graphene, silicene, phosphorene and transition-metal dichalcogenides allow the nanostructuration of complex geometries through metallic electrodes, interacting substrates, strain,...

    journal_title:Scientific reports

    pub_type: 杂志文章

    doi:10.1038/s41598-020-71697-1

    authors: Rodríguez-González R,Gaggero-Sager LM,Rodríguez-Vargas I

    更新日期:2020-09-07 00:00:00