Abstract:
:The geometry of metal nanoparticles greatly affects the properties of the localized surface plasmon resonance and surface-enhanced Raman scattering. The synthesis of metal nanoparticles with controllable geometry has thus attracted extensive attentions. In this work, we report a modified polyol synthesis approach of silver (Ag) nanocubes through tuning the concentration of bromide ions (Br(-) ions). We have systematically investigated the effect of Br(-) ions in the polyol process, and find that higher concentration of Br(-) ions can enhance oxidative etching effect, which is the dominative factor in determining nanostructure geometry. Therefore, one can realize control over nanostructure geometry by manipulating the concentration of Br(-) ions. Our work provides an effective approach to control the shape of metallic nanostructures for potential applications.
journal_name
Sci Repjournal_title
Scientific reportsauthors
Wu F,Wang W,Xu Z,Li Fdoi
10.1038/srep10772subject
Has Abstractpub_date
2015-06-09 00:00:00pages
10772issn
2045-2322pii
srep10772journal_volume
5pub_type
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