Abstract:
:Alditol bearing chitosans have shown the ability to reduce silver ions in mild conditions and without addition of exogenous reducing agents. The ion reduction induces the formation of a lactone moiety on the polysaccharide (Fetizon reaction) without causing C-C bond cleavage on the polyol. The close and multivalent arrangement of the endogenous reducing agent (alditols) on the polysaccharide backbone resulted in the formation of silver nanoparticles (phi < 10 nm), which induced a considerable SERS effect and led to hydrogel formation.
journal_name
Biomacromoleculesjournal_title
Biomacromoleculesauthors
Donati I,Travan A,Pelillo C,Scarpa T,Coslovi A,Bonifacio A,Sergo V,Paoletti Sdoi
10.1021/bm801253csubject
Has Abstractpub_date
2009-02-09 00:00:00pages
210-3issue
2eissn
1525-7797issn
1526-4602pii
10.1021/bm801253cjournal_volume
10pub_type
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