Polyol synthesis of silver nanoparticles: mechanism of reduction by alditol bearing polysaccharides.

Abstract:

:Alditol bearing chitosans have shown the ability to reduce silver ions in mild conditions and without addition of exogenous reducing agents. The ion reduction induces the formation of a lactone moiety on the polysaccharide (Fetizon reaction) without causing C-C bond cleavage on the polyol. The close and multivalent arrangement of the endogenous reducing agent (alditols) on the polysaccharide backbone resulted in the formation of silver nanoparticles (phi < 10 nm), which induced a considerable SERS effect and led to hydrogel formation.

journal_name

Biomacromolecules

journal_title

Biomacromolecules

authors

Donati I,Travan A,Pelillo C,Scarpa T,Coslovi A,Bonifacio A,Sergo V,Paoletti S

doi

10.1021/bm801253c

subject

Has Abstract

pub_date

2009-02-09 00:00:00

pages

210-3

issue

2

eissn

1525-7797

issn

1526-4602

pii

10.1021/bm801253c

journal_volume

10

pub_type

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