Natural analcime zeolite modified with 2,3,5,6-tetra(2-pyridyl)pyrazine for preconcentration and determination of trace amounts of cadmium by flame atomic absorption spectrometry.

Abstract:

:An analytical method using natural analcime zeolite modified with tppz (2,3,5,6-tetra-pyridylpyrazine) for preconcentration of cadmium, in a column system, and their sequential determination by flame atomic absorption spectrometry (FAAS), was developed. In this work, cadmium was adsorbed onto natural analcime zeolite modified with tppz and then was recovered by nitric acid. Solutions of cadmium were passed through a glass column packed with 100 mg of the sorbent material, at pH 5.0, and cadmium was eluted with 2.0 M HNO(3) at a flow rate of 2.0 ml min(-1). The relative standard deviation (RSD) for eight replicate determinations at the 2.5 μg of cadmium was ±0.94%. The calibration curve using the preconcentration system was linear from 0.01 to 4 μg ml(-1) in final solution with a correlation coefficient of 0.9993. This method was successfully applied for the determination of cadmium in various samples.

journal_name

Toxicol Ind Health

authors

Saljooghi AS,Saljoghi ZS

doi

10.1177/0748233711422730

subject

Has Abstract

pub_date

2012-10-01 00:00:00

pages

771-8

issue

9

eissn

0748-2337

issn

1477-0393

pii

0748233711422730

journal_volume

28

pub_type

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