Abstract:
:Tetraarylporphyrins substituted with nitro groups at beta-pyrrolic positions are potential candidates for electron-accepting pigments in model systems for photosynthesis. The photophysics of 2-nitro-5,10,15,20-tetra-p-tolylporphyrin and its zinc analog have been studied in order to evaluate this potential. The ground state absorption spectrum, the triplet-triplet absorption spectrum, the fluorescence emission spectrum, and associated photophysical parameters have been determined. The molecules have short singlet lifetimes and anomalous temperature- and solvent-dependent emission spectra which are consistent with the formation of an intramolecular charge transfer state of the type P+.-NO2-. in which the nitro group is twisted about its bond to the porphyrin, relative to the ground state conformation.
journal_name
Photochem Photobioljournal_title
Photochemistry and photobiologyauthors
Gust D,Moore TA,Luttrull DK,Seely GR,Bittersmann E,Bensasson RV,Rougée M,Land EJ,De Schryver FC,Van der Auweraer Mdoi
10.1111/j.1751-1097.1990.tb01733.xsubject
Has Abstractpub_date
1990-04-01 00:00:00pages
419-26issue
4eissn
0031-8655issn
1751-1097journal_volume
51pub_type
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