Abstract:
:Artisanal and small-scale gold-mining activities performed in mountain areas of the Southern Ecuadorian Amazon have incorporated several heavy metals into the aquatic systems, thus increasing the risk of exposure in populations living in adjacent zones. Therefore, the objective of this study was to evaluate the contamination levels of mercury (Hg) and manganese (Mn) in several rivers of the Nangaritza River basin and assess the exposure in school-aged children residing near the gold-mining zones. River water and sediment samples were collected from a highly contaminated (HEx) and a moderately contaminated (MEx) zones. Hair Mn (MnH) and urinary Hg (HgU) levels were determined in school-aged children living in both zones. High concentrations of dissolved Mn were found in river waters of the HEx zone (between 2660 and 3990 µg l(-1)); however, Hg levels, in general, were lower than the detection limit (DL; <1.0 µg l(-1)). Similarly, Mn levels in sediments were also increased (3090 to 4086 µg g(-1)). Median values of MnH in children of the HEx and MEx zones were 5.5 and 3.4 µg g(-1), respectively, whereas the median values of HgU concentrations in children living in the HEx and MEx zones were 4.4 and 0.62 µg g-creat(-1), respectively. Statistically significant differences were observed between both biomarkers in children from the HEx and MEx zones. In addition, boys presented significantly greater MnH levels in both zones. The greater MnH values were found in children living in alluvial areas, whereas children living in the high mountain areas, where some ore-processing plants are located close to or inside houses and schools, had the greater HgU concentrations. In summary, the data reported in this paper highlights that artisanal and small-scale gold-mining activities can not only produce mercurial contamination, that can also release other heavy metals (such as Mn) that may pose a risk to human health.
journal_name
Arch Environ Contam Toxicoljournal_title
Archives of environmental contamination and toxicologyauthors
González-Merizalde MV,Menezes-Filho JA,Cruz-Erazo CT,Bermeo-Flores SA,Sánchez-Castillo MO,Hernández-Bonilla D,Mora Adoi
10.1007/s00244-016-0285-5subject
Has Abstractpub_date
2016-08-01 00:00:00pages
171-82issue
2eissn
0090-4341issn
1432-0703pii
10.1007/s00244-016-0285-5journal_volume
71pub_type
杂志文章abstract::Di-n-butyl phthalate (DBP) is one of the most ubiquitous plasticizers used worldwide. However, it has negatives effects on the soil, water, atmosphere, and other environmental media and can cause serious pollution. According to the artificial soil test and previous studies, this study was conducted to evaluate the tox...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-017-0451-4
更新日期:2018-05-01 00:00:00
abstract::Soil persistence and lateral movement of 2,4-D (2,4-dichlorophenoxy acetic acid) and picloram (4-amino-3,5,6-trichloropicolinic acid) were examined following their application as a stem-foliage spray for brush control on two power line rights-of-way. Ditches to collect runoff water were located 3, 10, 20, and 30 m dow...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01059077
更新日期:1990-07-01 00:00:00
abstract::Within their aquatic habitats, larval amphibians are often subjected to multiple natural and anthropic stressors. Among these, predation and waterborne pollution represent two types of stressing factor that frequently co-occur. In this connection, the present laboratory study was designed to investigate the effects of...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-006-0229-6
更新日期:2007-08-01 00:00:00
abstract::Metallothioneins with differing Cd/Zn ratios were prepared in vitro from rat liver zinc-thionein by replacing zinc with cadmium and were injected intraperitoneally to female rats. The distribution of cadmium, zinc, and copper in the kidney supernatant fraction was determined using a Sephadex G-75 column. The distribut...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01055143
更新日期:1979-01-01 00:00:00
abstract::Colonially nesting aquatic birds can indicate site-specific contamination because they are high-level predators and dependent upon local resources during the breeding season. We compared persistent organochlorine concentrations in black-crowned night heron (Nvcticorax nvcticorax) eggs collected in 1992-93 among areas ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-003-2265-9
更新日期:2004-02-01 00:00:00
abstract::Concentrations of six phenolic endocrine-disrupting chemicals [4-tert-octylphenol (OP), 4-t-nonylphenol (4-t-NP), 4-n-nonylphenol (4-n-NP), nonylphenol mono- to di-ethoxylates (NP1EO, NP2EO), and bisphenol A (BPA)] and five estrogens [estrone (E1), β-estradiol (E2), estriol (E3) 17α-ethynylestradiol (EE2), and diethyl...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-014-9998-5
更新日期:2014-04-01 00:00:00
abstract::Concentrations of booster antifouling compounds in the port of Osaka, Japan were assessed. Concentrations of Sea-Nine 211 (4,5-dichloro-2-n-octyl-3-isothiazolone), thiabendazole (2-(4-thiazolyl)-benzimidazole), IPBC (3-iodo-2-propynyl butylcarbamate), Diuron (3,4-dichlorophenyl-N, N-dimethylurea), Irgarol 1051 (2-meth...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-004-0084-2
更新日期:2005-04-01 00:00:00
abstract::Adult intermolt Gammarus pulex were exposed to a range of cadmium concentrations in an artificial stream water containing 20 mg calcium 1(-1). 96 hr and 48 hr LC-50 values obtained were 0.12 and 0.68 mg Cd 1(-1), respectively. The influence of external calcium level on cadmium toxicity was investigated at a cadmium co...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01055633
更新日期:1981-01-01 00:00:00
abstract::White blood cell (WBC) phagocytosis was investigated as a potential immunological indicator of methylmercury (MeHg) exposure in birds. The assay was first assessed using chicken WBCs dosed with MeHg in vitro either in whole blood or as isolated cells and later using blood of wild common loons exposed in vivo to a rang...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-002-2095-1
更新日期:2003-05-01 00:00:00
abstract::High levels of perfluoroalkyl substances (PFASs) were observed in rural areas near a fluorochemical industrial park (FCIP) in the Yangtze River Delta region. The concentrations of total PFAS (∑PFASs) in soil, surface water, groundwater, and rainwater were in the range of 0.6-64.6 ng/g dry weight, 15.6-480.9, 4.8-614.6...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-017-0458-x
更新日期:2018-04-01 00:00:00
abstract::The effects of insecticidal control programs for grasshoppers on the population density of birds were assessed under operational conditions in two rangeland sites in Wyoming during an outbreak (19 to 56 grasshoppers m(-2) on >1,500 ha). Malathion, carbaryl, and fipronil were evaluated using large-scale (>/=260 ha) red...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900547
更新日期:1999-11-01 00:00:00
abstract::In this study, we examined heavy-metal concentrations in feathers of nestling great tits Parus major and blue tits Cyanistes caeruleus at two different sites (urban parkland vs. deciduous forest) located in the Łódź agglomeration in relation to interyear variation. We found that tit species did not differ significantl...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-014-0028-4
更新日期:2014-11-01 00:00:00
abstract::The organochlorine insecticide endosulfan is extensively used in Australia and can often contaminate aquatic environments. However, its effects on Australian frog species are unknown. We exposed tadpoles of the Australian treefrog Litoria frevcineti to endosulfan for 96 hours. Tadpoles exposed to 0.03 or 1.3 microg/L ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-003-0172-8
更新日期:2003-08-01 00:00:00
abstract::The effects of sediment-bound toxicants to aquatic invertebrates may vary due to differences in bioavailability, food quality, or food structure. The equilibrium partitioning theory (EPT) assumes that organic matter content of sediments and not structure of organic matter is relevant for biological effects of polycycl...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002440010109
更新日期:2000-10-01 00:00:00
abstract::Mercury (Hg) biomonitoring of pinnipeds increasingly utilizes nonlethally collected tissues such as hair and blood. The relationship between total Hg concentrations ([THg]) in these tissues is not well understood for marine mammals, but it can be important for interpretation of tissue concentrations with respect to ec...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-015-0174-3
更新日期:2016-01-01 00:00:00
abstract::The changes in the acute toxicity of 16 phenols toward Selenastrum capricornutum and Daphnia magna were examined as a function of their physical/chemical properties. The results demonstrated that phenols with a higher octanol-water partition coefficient (K(ow)) had a higher toxicity toward aquatic organisms. The toxic...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-004-1259-6
更新日期:2006-02-01 00:00:00
abstract::Soil organisms play a crucial role in the terrestrial ecosystem. Plant protection products (PPPs) are known to affect soil organisms and might have negative impacts on soil functions influenced by these organisms. Little research has been performed to date on the impact of PPPs on tropical soil ecosystems. Therefore, ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-006-0219-8
更新日期:2007-11-01 00:00:00
abstract::There is continuing concern that release of certain chemicals into the environment leads to human exposure to toxins, particularly through contaminated ground and surface waters. The triazine herbicide atrazine (2-chloro-4-ethylamine-6-isopropylamino-S-triazine) is routinely found as a contaminant in many surface and ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-003-3087-5
更新日期:2004-05-01 00:00:00
abstract::Aflatoxin B(1) (AFB(1)) is a potent mutagenic and carcinogenic agent found in numerous agricultural and dairy products consumed by humans. Therefore, we evaluated the capacity of mannan to cope with its genotoxic potential. We prepared a diet constituted of corn (90%) plus the recommended amount of other nutrients, as...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-006-0074-7
更新日期:2007-10-01 00:00:00
abstract::The pattern of spatial distribution of polycyclic aromatic hydrocarbons (PAHs) in seawater, sediment, and mussels, potential toxicity of different matrices, and mussel anoxic survival from six sampling sites of the Gulf of Rijeka, the Adriatic Sea, Croatia was examined. The total concentrations of 10 PAHs vary from be...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-005-0259-5
更新日期:2007-04-01 00:00:00
abstract::The sorption of volatile organic analytes from water samples by the Teflon septum surface used with standard glass 40-ml sample collection vials was investigated. Analytes tested included alkanes, isoalkanes, olefins, cycloalkanes, a cycloalkene, monoaromatics, a polynuclear aromatic, and two chloroethenes. Both labor...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900467
更新日期:1999-04-01 00:00:00
abstract::Genetically modified (GM) maize expressing the Bt-toxin Cry1Ab (Bt-maize) was tested for effects on survival, growth, and reproduction of the water flea Daphnia magna, a crustacean arthropod commonly used as a model organism in ecotoxicological studies. In three repeated experiments, D. magna were fed 100% ground maiz...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-008-9150-5
更新日期:2008-11-01 00:00:00
abstract::We investigated mutagenicity, genotoxicity, and estrogenic activity in the porewaters of two river basins in southern Italy that had different features. Three samples from each site were collected in different seasons from 7 sites for a total of 21 samples. Mutagenicity was measured with the Ames test with and without...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-013-9928-y
更新日期:2013-10-01 00:00:00
abstract::The effects of both parathion and methyl parathion on the inhibition of plasma cholinesterase were elaborated in a rat model employing a modified isocratic reverse-phase HPLC method coupled with UV detection for the determination of the urinary metabolite p-nitrophenol (U-4NP). A linearity of r2 > 0.995 was found for ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900207
更新日期:1997-05-01 00:00:00
abstract::Both in-field chemical investigation and in the laboratory toxic tests were carried out to systematically understand the pollution status of cadmium (Cd) and zinc (Zn) in Bohai Bay. Samples collected from surface seawater were determined to describe the distributions of Cd and Zn in Bohai Bay. The average values in ou...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-009-9461-1
更新日期:2010-07-01 00:00:00
abstract::Dissipation processes are described for a combination of commonly used pesticides-atrazine (6-chloro-4-ethylamino-6-isopropylamino- s-triazine), metolachlor (2-chloro- N-[2-ethyl-6-methyl-phenyl]- N-[2-methoxy-1-methylethyl] acetamide), and chlorpyrifos ( O-O diethyl O-[3,5,6-trichloro-2-pyridinyl] phosphorothioate)-i...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-002-1259-3
更新日期:2003-01-01 00:00:00
abstract::Benzene (Bz) is an important industrial chemical, a petroleum by-product, a component of unleaded gas, and thus a ubiquitous environmental pollutant. It is well established that this organic solvent possesses neurotoxic and behavioral effects. However, the neurochemical mechanism of the solvent action remains obscure....
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF00212097
更新日期:1992-04-01 00:00:00
abstract::A series of eleven nitrogen-containing heterocyclic compounds, which may be potentially associated with aqueous effluents from coal conversion technologies, were examined to determine the relationships between their n-octanol/H2O partition coefficients, molecular weights, boiling points, and their toxicity monitored a...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01056938
更新日期:1980-01-01 00:00:00
abstract::Data from Mixed Flask Culture (MFC) microcosms and fish single species toxicity tests were used to select treatment concentrations for littoral enclosure studies. Selected concentrations were evaluated by comparing the predicted responses to those observed in littoral enclosure studies with a pyrethroid pesticide, esf...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF00211627
更新日期:1995-05-01 00:00:00
abstract::The concentrations of polychlorinated dibenzo-p-dioxins (PCDD) and polychlorinated dibenzofurans (PCDF) were determined in soil samples taken from 24 sites in the vicinity of a municipal solid waste incinerator (Montcada, Barcelona, Spain). Samples were collected within a radius of 3 km in each of the three main direc...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900249
更新日期:1997-10-01 00:00:00