Abstract:
:The sorption of volatile organic analytes from water samples by the Teflon septum surface used with standard glass 40-ml sample collection vials was investigated. Analytes tested included alkanes, isoalkanes, olefins, cycloalkanes, a cycloalkene, monoaromatics, a polynuclear aromatic, and two chloroethenes. Both laboratory prepared test mix solutions and petroleum contaminated groundwater from three field sites were tested. A rapid loss of n-alkane and isoalkane concentrations (>10%) was observed within 24 h when stored at room temperature. Aliphatic losses were also observed (>10%) over a 21-day holding period when samples were held at 4 degrees C. Loss of the less sorptive analytes was demonstrated by exposing analyte solutions to greater Teflon surface areas. The demonstrated sorption of aliphatics from water samples by Teflon-lined septa indicates that the accuracy of volatile petroleum hydrocarbon determinations may be reduced by the traditional storage method. An alternative storage protocol is reported combining a lead foil septum surface and 1% (w/w) tribasic sodium phosphate dodecahydrate (Na3PO4. 12H2O) preservative. This method prevented loss of the test analytes, including alkanes and isoalkanes for at least 21 days at room temperature.
journal_name
Arch Environ Contam Toxicoljournal_title
Archives of environmental contamination and toxicologyauthors
Kovacs DA,Kampbell DHdoi
10.1007/s002449900467subject
Has Abstractpub_date
1999-04-01 00:00:00pages
242-7issue
3eissn
0090-4341issn
1432-0703journal_volume
36pub_type
杂志文章abstract::This study was performed to determine and compare persistent organic pollutant (POP) levels in different matrices in a female population. A total of 96 serum and 46 adipose tissue samples were collected from infertile women (n = 101) attending Centers for Reproductive Medicine in Belgium from 1996 to 1998. Gas chromat...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002440010104
更新日期:2000-08-01 00:00:00
abstract::Earlier incubation and greenhouse studies in our laboratory confirmed the effectiveness of drinking-water treatment residual (WTR) in decreasing soil arsenic (As) bioaccessibility as determined with in vitro tests, which led us to hypothesize a similar outcome if animal studies were to be conducted. Our objective was ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-009-9318-7
更新日期:2009-11-01 00:00:00
abstract::To evaluate sources of PCBs in combined sewer overflows (CSOs) to the Buffalo River, New York, combined sewage, sanitary flow, atmospheric wet and dry depositions, and street dust samples were collected from the Babcock Street sewer district and analyzed. Total PCB concentrations (sum of the PCB congeners quantitated)...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900234
更新日期:1997-08-01 00:00:00
abstract::We have studied distribution of pentachlorophenol (PCP)--a major environmental pollutant--between egg-phosphatidylcholine (egg-PC) membranes and water. The objectives were (1) to compare the membrane-water partition of the un-ionized (HA) and ionized (A) PCP, and (2) to establish similarities and differences between t...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF00210732
更新日期:1993-09-01 00:00:00
abstract::2,3-Dibromo-1-propanol (DBP) was used as an active flame retardant in the 1970s. It was also used as an intermediate in the preparation of insecticide formulations, pharmaceuticals and the flame retardants tris(2,3-dibromopropyl) phosphate (Tris-BP) and tetrabromobisphenol A bis (2,3-dibromopropyl ether). DBP is also ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-006-0094-3
更新日期:2007-07-01 00:00:00
abstract::Toxicity tests were performed to assess the effect of tannery wastewater with different treatment levels on two wetland plants, Phragmites australis and Typha latifolia, which are frequently used in constructed wetlands (CWs) for water treatment, and thus deepen the knowledge on their capacity to withstand the applica...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-007-9087-0
更新日期:2008-10-01 00:00:00
abstract::The effects of dietary exposure to copper (Cu), lead (Pb), and zinc (Zn) on feeding activities, growth response, and mortality of Theba pisana snails were studied in 5-week feeding tests. Snails were fed on an artificial diet containing the following Cu, Pb, or Zn concentrations: 0, 50, 100, 500, 1000, 5000, 10,000, a...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-010-9542-1
更新日期:2011-02-01 00:00:00
abstract::Clothing affords harvesters considerable protection against the elements and can retain substantial amounts of pesticide residue from treated crops. Normal work clothing of female harvesters was supplemented with rubber latex gloves and facial scarves to determine whether those measures reduced exposure. Captan fungic...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449910053
更新日期:2000-04-01 00:00:00
abstract::The acute effects of both untreated and dispersant-treated Prudhoe Bay crude oil on the early life-stages of three marine species were investigated. Identification of which water-accommodated fraction (undispersed or chemically dispersed) was considered "more toxic" was dependent on species, time, and endpoint (and by...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900302
更新日期:1998-02-01 00:00:00
abstract::The retention and distribution of eight polybrominated biphenyl (PBB) congeners were studied by roasting beef sirloin tip samples to an internal temperature of 65 degrees C, braising and broiling adductor and semimembranosus steaks to an internal temperature of 77 degrees C, broiling ground round and hamburger patties...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01055540
更新日期:1980-01-01 00:00:00
abstract::Human natural killer (NK) cells are lymphocytes that destroy tumor and virally infected cells. Previous studies have shown that exposure of NK cells to tributyltin (TBT) greatly diminishes their ability to destroy tumor cells (lytic function) while activating mitogen-activated protein kinases (MAPK) (p44/42, p38, and ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-010-9520-7
更新日期:2010-11-01 00:00:00
abstract::The effect of pyrene on the regulation of the gene expression of cytochrome P4501A ( CYP1A) was studied in tilapia (Oreochromis niloticus), a tropical fish of great ecological and economical importance. To evaluate CYP1A mRNA, tilapia CYP1A cDNA was cloned, sequenced, and compared with those CYP1A reported sequences i...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-001-0018-1
更新日期:2002-05-01 00:00:00
abstract::Metal pollution in the river Godavari in India, due to discharges of liquid wastes from a paper mill, has been studied for a period of two years. At the discharge point and 1 km from the point of discharge, iron, manganese, and zinc were recorded in high concentrations, whereas cadmium and chromium were observed in lo...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01183878
更新日期:1991-11-01 00:00:00
abstract::The 70-kDa stress protein family (HSP70) plays important roles in a variety of physiological processes, including protein chaperoning, protection against apoptosis, steroidogenesis, and general cellular stress responses in vertebrate organisms, and has also been proposed as a biochemical marker of environmental stress...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-002-0109-7
更新日期:2003-07-01 00:00:00
abstract::This study investigated the contribution of two biomarkers, bile polycyclic aromatic hydrocarbon (PAH) metabolites and 7-ethoxyresorufin O-deethylase (EROD), activity in the assessment of PAH contaminated sites. European eels (Anguilla anguilla) were caged in a freshwater stream upstream and downstream from local indu...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-005-0064-1
更新日期:2006-08-01 00:00:00
abstract::Red-backed salamanders (Plethodon cinereus) were exposed to four different concentrations of 1,3,5-trinitrohexahydro-1,3,5-triazine (RDX) in soil under controlled laboratory conditions for 28 days. Wild-caught P. cinereus (N = 20/treatment) were exposed to target concentrations of 5,000, 1000, 100, 10, and 0 mg RDX/kg...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-004-3242-7
更新日期:2004-11-01 00:00:00
abstract::The present study could serve as a multidisciplinary approach for the assessment of river surface water quality with the use of chemical and biological methods. Specifically, physicochemical parameters, heavy metals, and pesticides were measured in water samples from three different stations (sampling station S1, S2, ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-015-0152-9
更新日期:2015-08-01 00:00:00
abstract::Perchlorate is a potent thyroid hormone-disrupting compound. Drinking water is one of the major sources of human exposure to perchlorate. Little is known about the occurrence of perchlorate in waters from China. In this study, water samples (n = 300) collected from 15 locations in 13 provinces and municipalities were ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-010-9485-6
更新日期:2010-04-01 00:00:00
abstract::Intoxication with an acute dose of carbofuran (1.5 mg/kg, sc) in male Sprague-Dawley rats evoked severe toxic manifestations characteristic of hypercholinergic preponderance with profound muscle fasciculations and convulsions during 30-60 min, lasting for about 2 h. Lactate dehydrogenase, a "biomarker" cytoplasmic enz...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF01055345
更新日期:1991-08-01 00:00:00
abstract::Cerium has been demonstrated to damage liver of mice, but very little is known about the molecular mechanisms underlying the mouse liver apoptosis. In order to understand the liver injury induced by intragastric administration of cerium chloride (CeCl3) for 60 consecutive days, the hepatocyte ultrasrtucture, various o...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-011-9672-0
更新日期:2012-01-01 00:00:00
abstract::A battery of in vitro bioassays, including a Neutral Red (NR) assay using MCF-7 cells for predicting cytotoxic chemicals, an ethoxy resorufin-O-deethylase (EROD) activity assay using H4IIE cells to check for dioxin-like chemicals, and a recombinant gene yeast assay for screening estrogenic chemicals, was conducted to ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-004-0204-z
更新日期:2005-11-01 00:00:00
abstract::Lake Oubeira has been used as the main source of drinking water for many communities in the East of Algeria. In this lake, nutrient loading coupled with year-round warm weather favors the growth of cyanobacteria, several of which can produce cyanotoxins, especially the potent liver toxins called microcystins (MCYSTs)....
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-003-2283-7
更新日期:2004-02-01 00:00:00
abstract::This is the first study to investigate the rate of mercury (Hg) biomagnification in the aquaculture pond ecosystem of the Pearl River Delta (PRD), China, by analyzing total mercury (THg) and methyl mercury (MeHg) concentrations in various species of fish at different trophic levels (TLs). Species representing a gradie...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-010-9641-z
更新日期:2011-10-01 00:00:00
abstract::Heavy metals present in the soil get differently accumulated in organisms and show different rates of toxicity at different stages of the life cycle of any organism living there. To see whether such toxicants get accumulated during the embryonic development and/or change the normal developmental processes of organisms...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/pl00006613
更新日期:1999-05-01 00:00:00
abstract::The magnitude of between-strain differences in the sensitivity of algal species to toxicants is not well known. Yet, informations obtained with a single strain are used for ecotoxicological assessment and for interspecific comparisons. Using 12 strains, we determined whether intraspecific variability occurs in the gre...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s002449900487
更新日期:1999-07-01 00:00:00
abstract::The fluctuations of mercury levels (Hg) in fish consumed by sport fishers in North-Eastern America depend upon a plethora of interrelated biological and abiological factors. To identify the dominant factors ultimately controlling fish Hg concentrations, we compiled mercury levels (Hg) during the 1976-2010 period in 90...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-016-0261-0
更新日期:2016-05-01 00:00:00
abstract::Heavy metal genotoxicity was evaluated by using different microbial tests. Four genotoxicity assays were employed: the Ames test, the E. coli WP2 test, the Mutatox test detecting mutagenicity, and the SOS assay with E. coli-detecting enzyme induction. All the metals tested (cadmium, chromium, copper, mercury, nickel, ...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/BF00212978
更新日期:1995-08-01 00:00:00
abstract::Juvenile rainbow trout (Oncorhynchus mykiss) were exposed to 0, 10, 30, and 70% (v/v) of a secondary-treated, integrated thermomechanical-bleached kraft pulp and paper mill effluent. The immunological parameters oxidative burst and phagocytosis of head kidney macrophages and total and differential circulating leukocyt...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-004-0093-1
更新日期:2005-05-01 00:00:00
abstract::Single-point Tenax extractions (SPTEs) of hydrophobic organic contaminants provide estimates of bioaccessibility through consistent measures of the chemical concentration initially in the rapidly desorbing fraction in sediment (C rapT0), such that a constant ratio is expected between SPTE and C rapT0 (C T /C rapT0, wh...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-017-0395-8
更新日期:2017-05-01 00:00:00
abstract::Chronic arsenic intoxication is known to cause multisystem impairment and is still a major threat to public health in many countries. In Toroku, a small village in Japan, arsenic mines operated from 1920 to 1962, and residents suffered serious sequelae of arsenic intoxication. We have performed annual medical examinat...
journal_title:Archives of environmental contamination and toxicology
pub_type: 杂志文章
doi:10.1007/s00244-018-0544-8
更新日期:2018-11-01 00:00:00