28-Noroleanane-derived spirocyclic triterpenoids and iridoid glucosides from the roots of Phlomoides umbrosa (Turcz.) Kamelin & Makhm with their cytotoxic effects.

abstract：:Cyclization of methyl ent-8 alpha-hydroxylabd-13(16),14-dien-18-oate with m-chloroperbenzoic acid gave methyl (13S)-ent-16-hydroxy-8 alpha,13-epoxylabd-14-en-18-oate and its epimer at C-13. Biotransformation of the former (which exhibits antileishmania activity) with Rhizopus nigricans cultures produced the methyl (13...

journal_title：Phytochemistry

authors： García-Granados A,Liñán E,Martínez A,Onorato ME,Parra A,Arias JM

更新日期：1995-01-01 00:00:00

abstract：:Seven pairs of undescribed enantiomeric bis-coumarins, (±)-dievodialetins A-G, were separated from the roots of Evodia lepta Merr. Two coumarin nuclei were linked via a 1,4-dimethyl4-vinylcyclohexene moiety in (±)-dievodialetins C-G. The structures of the undescribed compounds, including their absolute configurations ...

journal_title：Phytochemistry

authors： Huang GY,Cui H,Lu XY,Zhang LD,Ding XY,Wu JJ,Duan LX,Zhang SJ,Liu Z,Zhang RR

更新日期：2021-02-01 00:00:00

abstract：:The hypersensitive response (HR), elicited when resistant hosts are infected by incompatible races of biotrophic fungi, has been researched extensively. New studies on host responses to necrotrophic fungi are beginning to show that when the HR occurs in hosts colonized by necrotrophs, fungal growth is accelerated rath...

journal_title：Phytochemistry

authors： Mayer AM,Staples RC,Gil-ad NL

更新日期：2001-09-01 00:00:00

abstract：:Thevetia cardiac glycosides can lead to intoxication, thus they are important indicators for forensic and pharmacologic surveys. Six thevetia cardiac glycosides, including two with unknown structures, were isolated from the seeds of the Yellow Oleander (Thevetia peruviana (Pers.) K. Shum., Apocynaceae). LC-ESI⁺-MS(/MS...

journal_title：Phytochemistry

authors： Kohls S,Scholz-Böttcher BM,Teske J,Zark P,Rullkötter J

更新日期：2012-03-01 00:00:00

abstract：:Seven pure flavonoids were isolated and identified from five moss species. The flavonoids were the flavones apigenin, apigenin-7-O-triglycoside, lucenin-2, luteolin-7-O-neohesperidoside, saponarine and vitexin; and the biflavonoid bartramiaflavone. Some of these flavonoids were shown to have pronounced antibacterial e...

journal_title：Phytochemistry

authors： Basile A,Giordano S,López-Sáez JA,Cobianchi RC

更新日期：1999-12-01 00:00:00

abstract：:A new bisdesmodic triterpenoid saponin, dulcin was isolated from the seeds of Pithecellobium dulce and was identified as 3-O-[beta-D-glucopyranosyl (1-->2)-alpha-L-arabinopyranosyl]- 28-O-[beta-D-xylopyranosyl (1-->6)-beta-D-glucopyranosyl]-echinocystic acid. The known oleanolic acid saponin PE, oleanolic acid 3-O-bet...

journal_title：Phytochemistry

authors： Sahu NP,Mahato SB

更新日期：1994-11-01 00:00:00

abstract：:Seven dammarane glycosides, gypenosides GC1 to GC7, together with ten known compounds, gypenosides V, XIV, XLII-XLVI, gynosaponins TN-1, -2, and gymnemaside VI, were isolated from the methanol extract of the aerial parts of Gynostemma pentaphyllum. Their structures were elucidated by both analysis of 1D and 2D NMR spe...

journal_title：Phytochemistry

authors： Kim JH,Han YN

更新日期：2011-08-01 00:00:00

abstract：:Nine cycloartane triterpenoids, including two new derivatives 22,25-dihydroxy-cycloart-23E-en-3-one and 24-methylenecycloartane-3 beta,22-diol have been isolated from leaves of Guarea macrophylla. The structures were elucidated by interpretation of spectral data, mainly 1H and 13C NMR, including bidimensional analysis...

journal_title：Phytochemistry

authors： Lago JH,Roque NF

更新日期：2002-06-01 00:00:00

abstract：:We have previously reported the purification and partial characterization of two cationic peroxidases from the cell walls of seeds and seedlings of the South American conifer, Araucaria araucana. In this work, we have studied the amino acid composition and NH2-terminal sequences of both enzymes. We also compare the da...

journal_title：Phytochemistry

authors： Riquelme A,Cardemil L

更新日期：1995-05-01 00:00:00

abstract：:A new highly oxygenated triterpene named ganoderic acid alpha has been isolated from a methanol extract of the fruiting bodies of Ganoderma lucidum together with twelve known compounds. The structures of the isolated compounds were determined by spectroscopic means including 2D-NMR. Ganoderiol F and ganodermanontriol ...

journal_title：Phytochemistry

authors： el-Mekkawy S,Meselhy MR,Nakamura N,Tezuka Y,Hattori M,Kakiuchi N,Shimotohno K,Kawahata T,Otake T

更新日期：1998-11-01 00:00:00

abstract：:In a chemotaxonomic survey of 57 Pelargonium species, leaf exudate flavonoids were detected in 35% of the sample, mostly in trace amounts. However, chrysin and a related C-methylflavanone were identified as major leaf surface constituents of P. crispum, and a mixture of quercetin and kaempferol mono-, and di- and trim...

journal_title：Phytochemistry

authors： Williams CA,Harborne JB,Newman M,Greenham J,Eagles J

更新日期：1997-12-01 00:00:00

abstract：:Activity guided fractionations led to the isolation of two antitumor compounds 5 alpha,8 alpha-epidioxy-24(R)-methylcholesta-6,22-dien-3 beta-D-glucopyranoside and 5,6-epoxy-24(R)-methylcholesta-7,22-dien-3 beta-ol from the methanol extract of Cordyceps sinensis. Two previously known compounds, ergosteryl-3-O-beta-D-g...

journal_title：Phytochemistry

authors： Bok JW,Lermer L,Chilton J,Klingeman HG,Towers GH

更新日期：1999-08-01 00:00:00

abstract：:The inhibition of wheat Ca(2+)-dependent protein kinase (CDPK) by substituted acridines and substituted 5-, 6-, 7- and 8-azaacridines (5-AA, 6-AA, 7-AA and 8-AA) was examined. Of a total of 71 substituted acridines and azaacridines examined, only 20 have IC50 values for wheat CDPK of less than 200 microM. Of these, ef...

journal_title：Phytochemistry

authors： Chen Q,Deady LW,Polya GM

更新日期：1994-07-01 00:00:00

abstract：:The allene oxide cyclase (AOC) catalyzes the formation of cis-(+)-12-oxophytodienoic acid, an intermediate in jasmonate biosynthesis and is encoded by a single copy gene in tomato. The full length AOC promoter isolated by genome walk contains 3600 bp. Transgenic tomato lines carrying a 1000 bp promoter fragment and th...

journal_title：Phytochemistry

authors： Stenzel I,Hause B,Proels R,Miersch O,Oka M,Roitsch T,Wasternack C

更新日期：2008-06-01 00:00:00

abstract：:A bioassay-guided fractionation of Agave offoyana leaves led to the isolation of five steroidal saponins (1-5) along with six known saponins (6-11). The compounds were identified as (25R)-spirost-5-en-2α,3β-diol-12-one 3-O-{α-l-rhamnopyranosyl-(1→3)-O-β-d-glucopyranosyl-(1→2)-O-[β-d-xylopyranosyl-(1→3)]-O-β-d-glucopyr...

journal_title：Phytochemistry

authors： Pérez AJ,Simonet AM,Calle JM,Pecio Ł,Guerra JO,Stochmal A,Macías FA

更新日期：2014-09-01 00:00:00

abstract：:Coumarins exhibit many biological activities and are the main specialised metabolites of Peucedanum praeruptorum Dunn, an important plant used in traditional Chinese medicine. In preliminary studies, we cloned several genes involved in coumarin biosynthesis in P. praeruptorum, such as 4-coumarate: CoA ligase (4CL), p-...

journal_title：Phytochemistry

authors： Sui Z,Luo J,Yao R,Huang C,Zhao Y,Kong L

更新日期：2019-02-01 00:00:00

abstract：:The paper describes the amino acid sequence of a 26 kDa basic subunit of 13S globulin of common buckwheat (Fagopyrum esculentum Moench). The protein has 93 and 75% sequence homology with 11S globulin of Coffea arabica and beta subunit of 11S globulin of Cucurbita pepo respectively. The subunit has the "globally conser...

journal_title：Phytochemistry

authors： Bharali S,Chrungoo NK

更新日期：2003-05-01 00:00:00

abstract：:Passiflora morifolia, which under natural conditions contains cyanohydrin glucosides linamarin, lotaustralin and epilotaustralin, converted cyclopentanecarbonitrile, 2-cyclopentenecarbonitrile and 3-methylbutanenitrile into the corresponding cyanohydrin glucosides. Turnera angustifolia, which normally produces glucosi...

journal_title：Phytochemistry

authors： Jaroszewski JW,Rasmussen AB,Rasmussen HB,Olsen CE,Jørgensen LB

更新日期：1996-06-01 00:00:00

abstract：:Schizolobium parahyba seed chymotrypsin inhibitor (SPC) is a protein with M(r) of 20,000 and four half-cystine residues and no free thiol group. SPC is stable at temperatures up to 75 degrees at pH 7 but gradually loses activity when kept at 95 degrees for 1 hr and total inactivation occurs after 5 hr. Amino acid anal...

journal_title：Phytochemistry

authors： Souza EM,Mizuta K,Sampaio MU,Sampaio CA

更新日期：1995-06-01 00:00:00

abstract：:Reinvestigation of the fermentation broth and mycelium of the coprophilous fungus Guanomyces polythrix, grown in static conditions, led to the isolation of several phytotoxic compounds, including two new naphthopyranone derivatives, namely (2S, 3R)-5-hydroxy-6,8-dimethoxy-2,3-dimethyl-2,3-dihydro-4H-naphtho[2,3-b]-pyr...

journal_title：Phytochemistry

authors： Macías M,Gamboa A,Ulloa M,Toscano RA,Mata R

更新日期：2001-11-01 00:00:00

abstract：:Eleven oleanane-type triterpenoid saponins, foegraecumosides A-K, and eight known ones, were isolated from the aerial parts of Lysimachia foenum-graecum. Their structures were elucidated by spectroscopic data analyses and chemical methods. All isolated saponins were evaluated for their cytotoxicity against four human ...

journal_title：Phytochemistry

authors： Dai LM,Huang RZ,Zhang B,Hua J,Wang HS,Liang D

更新日期：2017-04-01 00:00:00

abstract：:The chemical study on the heartwoods extract of Ventilago harmandiana (Rhamnaceae) resulted in the isolation of ten previously undescribed pyranonaphthoquinones (ventilanones A-J), an undescribed anthraquinone (ventilanone K), together with eight known anthraquinone derivatives. Their structures were elucidated by ext...

journal_title：Phytochemistry

authors： Panthong K,Hongthong S,Kuhakarn C,Piyachaturawat P,Suksen K,Panthong A,Chiranthanut N,Kongsaeree P,Prabpai S,Nuntasaen N,Reutrakul V

更新日期：2020-01-01 00:00:00

abstract：:Two bitter stigmastane derivatives, vernoguinosterol (1) and vernoguinoside (2), have been isolated from the stem bark of Vernonia guineensis and their structures eludicated using spectroscopic methods. The new compounds exhibit trypanocidal activity. ...

journal_title：Phytochemistry

authors： Tchinda AT,Tsopmo A,Tane P,Ayafor JF,Connolly JD,Sterner O

更新日期：2002-02-01 00:00:00

abstract：:A catechol oxidase from lemon balm (Melissa officinalis) moCO which only catalyzes the oxidation of catechols to quinones without hydroxylating tyrosine was purified. The molecular mass of the M. officinalis enzyme of 39,370 Da was obtained by MALDI mass spectrometry and the isoelectric point was determined to be 3.4....

journal_title：Phytochemistry

authors： Rompel A,Büldt-Karentzopoulos K,Molitor C,Krebs B

更新日期：2012-09-01 00:00:00

abstract：:The lipid extract of the temperate red alga Rhodymenia pertusa has yielded four eicosanoid metabolites, three of which are new natural products. Using principally NMR and MS techniques, their structures were deduced as 5R,6S-dihydroxy-7(E),9(E),11(Z),14(Z)-eicosatetraenoic acid (5R,6S-diHETE), 5R*,6S*-dihydroxy-7(E),9...

journal_title：Phytochemistry

authors： Jiang ZD,Ketchum SO,Gerwick WH

更新日期：2000-01-01 00:00:00

abstract：:To date, the many examples reporting that fungal pathogens can efficiently detoxify phytoalexins provide strong evidence that the pathogenicity and/or virulence of some fungi is linked to their ability to detoxify their hosts' phytoalexins. The pathways used by plant pathogenic fungi to metabolize and detoxify phytoal...

journal_title：Phytochemistry

authors： Pedras MS,Ahiahonu PW

更新日期：2005-02-01 00:00:00

abstract：:In plants, it has been proposed that hexacoordinate (class 1) non-symbiotic Hbs (nsHb-1) function in vivo as peroxidases. However, little is known about peroxidase activity of nsHb-1. We evaluated the peroxidase activity of rice recombinant Hb1 (a nsHb-1) by using the guaiacol/H2O2 system at pH 6.0 and compared it to ...

journal_title：Phytochemistry

authors： Violante-Mota F,Tellechea E,Moran JF,Sarath G,Arredondo-Peter R

更新日期：2010-01-01 00:00:00

abstract：:The seeds of 36 pigeonpea [Cajanus cajan (L) Millsp.] cultivars, resistant and susceptible to pests and pathogens and 17 of its wild relatives were analysed for inhibitors of trypsin, chymotrypsin, and insect gut proteinases to identify potential inhibitors of insect (Helicoverpa armigera) gut enzymes. Proteinase inhi...

journal_title：Phytochemistry

authors： Chougule NP,Hivrale VK,Chhabda PJ,Giri AP,Kachole MS

更新日期：2003-10-01 00:00:00

abstract：:[(3)H](+)-delta-Cadinene and its 8-hydroxy derivative, prepared from (1RS)-[1-(3)H]FPP by the action of one and two recombinant enzymes, respectively, were infiltrated into cotyledons of bacterial blight-resistant cotton plants as they biosynthesized sesquiterpene phytoalexins in response to infection by Xanthomonas c...

journal_title：Phytochemistry

authors： Wang YH,Davila-Huerta G,Essenberg M

更新日期：2003-09-01 00:00:00

abstract：:Four flavonol glycosides isolated from non-flowering leafy shoots of Iberis saxatilis (Brassicaceae) were characterised by spectroscopic and chemical methods as saxatilisins A-D, the 3-O-β-D-glucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)[β-D-glucopyranosyl-(1→2)-α-L-rhamnopyranosyl-(1→6)]-β-D-glucopyranoside, 3-O-β-D-...

journal_title：Phytochemistry

authors： Prescott TA,Kite GC,Porter EA,Veitch NC

更新日期：2013-04-01 00:00:00